Laboratory of Advanced Materials, College of Smart Materials and Future Energy, Department of Chemistry, New Cornerstone Science Laboratory, State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, China
Luminescent nanothermometry based on thermally coupled levels (TCLs) has emerged as a powerful tool for non-invasive temperature sensing
but it still lacks sufficient theoretical guidelines. To address this issue
a theoretical framework for Boltzmann luminescent nanothermometry has been established
which quantitatively defines the temperature window for establishing thermal equilibrium in TCLs
establishes a practical criterion for stable thermal coupling of TCLs
and enables predictive material design of temperature sensitivity. Based on this framework
a high sensitivity of 6.17% K
-1
is achieved
providing a theoretical basis for the rational design of high-precision nanothermometers.
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references
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