320-fold luminescence enhancement of [Ru(dpp)<sub>3</sub>]Cl<sub>2</sub> dispersed on PMMA opal photonic crystals and highly improved oxygen sensing performance

Pingwei Zhou; Donglei Zhou; Li Tao; Yongsheng Zhu; Wen Xu; Sai Xu; Shaobo Cui; Lin Xu; Hongwei Song

doi:10.1038/lsa.2014.90

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320-fold luminescence enhancement of [Ru(dpp)₃]Cl₂ dispersed on PMMA opal photonic crystals and highly improved oxygen sensing performance

Original Articles

- 320-fold luminescence enhancement of [Ru(dpp)₃]Cl₂ dispersed on PMMA opal photonic crystals and highly improved oxygen sensing performance
- Light: Science & Applications Vol. 3, Issue 4, (2014)
- Affiliations：
  
  1.State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, China
  2.College of Physics, Jilin University, Changchun 130012, China
- Author bio：
  
  Professor HW Song, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, ChinaE-mail: songhw@jlu.edu.cn
- Funds：
- DOI：10.1038/lsa.2014.90
  CLC：
- Published：2014-12，
  
  Published Online：10 October 2014，
  
  Received：18 April 2014，
  
  Revised：21 July 2014，
  
  Accepted：22 July 2014
- Accepted：
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Zhou, P. W. et al. 320-fold luminescence enhancement of [Ru(dpp)₃]Cl₂ dispersed on PMMA opal photonic crystals and highly improved oxygen sensing performance. Light: Science & Applications, 3, e209 (2014).
DOI：

Zhou, P. W. et al. 320-fold luminescence enhancement of [Ru(dpp)₃]Cl₂ dispersed on PMMA opal photonic crystals and highly improved oxygen sensing performance. Light: Science & Applications, 3, e209 (2014). DOI： 10.1038/lsa.2014.90.

摘要

Abstract

Ru complexes ([Ru(dpp)

]

) were spin coated on poly(methyl methacrylate) (PMMA) opal photonic crystals (PhCs)

and a ~320-fold luminescence enhancement was observed compared to that on glass

which is the largest luminescence enhancement of dye molecules by the modulation of three-dimensional (3D) PhCs reported until now. The enhancement mechanism was carefully examined and it was shown that the luminescence of [Ru(dpp)

]

depended on the molecule concentration and temperature. It can be concluded that the suppressed non-radiative relaxation among the molecules and the field enhancement both contribute significantly to the luminescence enhancement. The PMMA PhC/Ru complex composites were then tested for their intracellular oxygen sensing and cell imaging properties; these composites effectively improved the limit of detection (LOD) and the brightness of the cell images.

关键词

Keywords

cell imagingfluorescence enhancementoxygen sensingphotonic crystals

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⁰

320-fold luminescence enhancement of [Ru(dpp)3]Cl2 dispersed on PMMA opal photonic crystals and highly improved oxygen sensing performance

DOI：10.1038/lsa.2014.90

摘要

Abstract

关键词

Keywords

references

320-fold luminescence enhancement of [Ru(dpp)₃]Cl₂ dispersed on PMMA opal photonic crystals and highly improved oxygen sensing performance