
1.Optoelectronic Division—Engineering Department, University of Sannio, 82100 Benevento, Italy
2.National Research Council, Institute for Macromolecular Studies (ISMAC-CNR), 20133 Milano, Italy
3.ENEA, Portici Research Center, 80055 Portici, Italy
A Cusano, Email: a.cusano@unisannio.it
Published:2017-06,
Published Online:08 September 2016,
Received:14 March 2016,
Revised:06 September 2016,
Accepted:06 September 2016
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Pisco, M. et al. Nanosphere lithography for optical fiber tip nanoprobes. Light: Science & Applications, 6, e16229 (2017).
Pisco, M. et al. Nanosphere lithography for optical fiber tip nanoprobes. Light: Science & Applications, 6, e16229 (2017). DOI: 10.1038/lsa.2016.229.
This paper reports a simple and economical method for the fabrication of nanopatterned optical fiber nanotips. The proposed patterning approach relies on the use of the nanosphere lithography of the optical fiber end facet. Polystyrene (PS) nanospheres are initially self-assembled in a hexagonal array on the surface of water. The created pattern is then transferred onto an optical fiber tip (OFT). The PS monolayer colloidal crystal on the OFT is the basic building block that is used to obtain different periodic structures by applying further treatment to the fiber
such as metal coating
nanosphere size reduction and sphere removal. Ordered dielectric and metallo-dielectric sphere arrays
metallic nanoisland arrays and hole-patterned metallic films with feature sizes down to the submicron scale are achievable using this approach. Furthermore
the sizes and shapes of these periodic structures can be tailored by altering the fabrication conditions. The results indicate that the proposed self-assembly approach is a valuable route for the development of highly repeatable metallo-dielectric periodic patterns on OFTs with a high degree of order and low fabrication cost. The method can be easily extended to simultaneously produce multiple fibers
opening a new route to the development of fiber-optic nanoprobes. Finally
we demonstrate the effective application of the patterned OFTs as surface-enhanced Raman spectroscopy nanoprobes.
lab-on-fibernanosphere lithographySERS probes
Kostovski G, Stoddart PR, Mitchell A. The optical fiber tip: an inherently light-coupled microscopic platform for micro- and nanotechnologies.Adv Mater2014;26: 3798–3820..
Pisco M, Quero G, Iadicicco A, Giordano M, Galeotti Fet al. Lab on fiber by using the breath figure technique. In: Cusano A, Consales M, Crescitelli A, Ricciardi A, editors.Lab-on-Fiber Technology. Switzerland: Springer International Publishing; 2015, p233–250..
Ricciardi A, Crescitelli A, Vaiano P, Quero G, Consales Met al. Lab-on-fiber technology: a new vision for chemical and biological sensing.Analyst2015;140: 8068–8079..
Consales M, Ricciardi A, Crescitelli A, Esposito E, Cutolo Aet al. Lab-on-fiber technology: toward multifunctional optical nanoprobes.ACS Nano2012;6: 3163–3170..
Lin YB, Zou Y, Lindquist RG. A reflection-based localized surface plasmon resonance fiber-optic probe for biochemical sensing.Biomed Opt Express2011;2: 478–484..
Sanders M, Lin YB, Wei JJ, Bono T, Lindquist RG. An enhanced LSPR fiber-optic nanoprobe for ultrasensitive detection of protein biomarkers.Biosens Bioelectron2014;61: 95–101..
Micco A, Ricciardi A, Pisco M, La Ferrara V, Cusano A. Optical fiber tip templating using direct focused ion beam milling.Sci Rep2015;5: 15935..
Dhawan A, Gerhold M, Madison A, Fowlkes J, Russell PEet al. Fabrication of nanodot plasmonic waveguide structures using FIB milling and electron beam-induced deposition.Scanning2009;31: 139–146..
Dhawan A, Gerhold MD, Muth JF. Plasmonic structures based on subwavelength apertures for chemical and biological sensing applications.IEEE Sens J2008;8: 942–950..
Jia PP, Yang J. Integration of large-area metallic nanohole arrays with multimode optical fibers for surface plasmon resonance sensing.Appl Phys Lett2013;102: 243107..
Whitesides GM, Grzybowski B. Self-assembly at all scales.Science2002;295: 2418–2421..
Mullen KI, Carron KT. Surface-enhanced Raman spectroscopy with abrasively modified fiber optic probes.Anal Chem1991;63: 2196–2199..
Andrade GFS, Fan MK, Brolo AG. Multilayer silver nanoparticles-modified optical fiber tip for high performance SERS remote sensing.Biosens Bioelectron2010;25: 2270–2275..
Viets C, Hill W. Comparison of fibre-optic SERS sensors with differently prepared tips.Sens Actuat B Chem1998;51: 92–99..
Stoddart PR, White PA, Mazzolini A. Chemical sensors based on nanoparticle arrays.Proc SPIE2002;4934: 61–69..
Yap FL, Thoniyot P, Krishnan S, Krishnamoorthy S. Nanoparticle cluster arrays for high-performance SERS through directed self-assembly on flat substrates and on optical fibers.ACS Nano2012;6: 2056–2070..
Pisco M, Galeotti F, Quero G, Iadicicco A, Giordano Met al. Miniaturized sensing probes based on metallic dielectric crystals self-assembled on optical fiber tips.ACS Photonics2014;1: 917–927..
Pisco M, Galeotti F, Quero G, Grisci G, Micco Aet al. Nanosphere lithography for advanced all fiber Sers probes.Proc SPIE2016;9916: 99161S..
Ye XZ, Qi LM. Two-dimensionally patterned nanostructures based on monolayer colloidal crystals: controllable fabrication, assembly, and applications.Nano Today2011;6: 608–631..
Moon GD, Lee TI, Kim B, Chae G, Kim Jet al. Assembled monolayers of hydrophilic particles on water surfaces.ACS Nano2011;5: 8600–8612..
Ho CC, Chen PY, Lin KH, Juan WT, Lee WL. Fabrication of monolayer of polymer/nanospheres hybrid at a water-air interface.ACS Appl Mater Interfaces2011;3: 204–208..
Yu J, Yan QF, Shen DZ. Co-self-assembly of binary colloidal crystals at the air-water interface.ACS Appl Mater Interfaces2010;2: 1922–1926..
Dai ZF, Li Y, Duan GT, Jia LC, Cai WP. Phase diagram, design of monolayer binary colloidal crystals, and their fabrication based on ethanol-assisted self-assembly at the air/water interface.ACS Nano2012;6: 6706–6716..
Kitaev V, Ozin GA. Self-assembled surface patterns of binary colloidal crystals.Adv Mater2003;15: 75–78..
Wang LK, Wan Y, Li YQ, Cai ZY, Li HLet al. Binary colloidal crystals fabricated with a horizontal deposition method.Langmuir2009;25: 6753–6759..
Zhou ZC, Yan QF, Li Q, Zhao XS. Fabrication of binary colloidal crystals and non-close-packed structures by a sequential self-assembly method.Langmuir2007;23: 1473–1477..
Haynes CL, van Duyne RP. Nanosphere lithography: a versatile nanofabrication tool for studies of size-dependent nanoparticle optics.J Phys Chem B2001;105: 5599–5611..
Pisco M, Galeotti F, Grisci G, Quero G, Cusano A. Self-assembled periodic patterns on the optical fiber tip by microsphere arrays.Proc SPIE2015;9634: 96341N..
Muldarisnur M, Marlow F. Opal films made by the capillary deposition method: crystal orientation and defects.J Phys Chem C2011;115: 414–418..
Hoogenboom JP, Derks D, Vergeer P, van Blaaderen A. Stacking faults in colloidal crystals grown by sedimentation.J Chem Phys2002;117: 11320–11328..
Jiang P, McFarland MJ. Large-scale fabrication of wafer-size colloidal crystals, macroporous polymers and nanocomposites by spin-coating.J Am Chem Soc2004;126: 13778–13786..
Ariga K, Yamauchi Y, Mori T, Hill JP. 25th anniversary article: what can be done with the langmuir-blodgett method? Recent developments and its critical role in materials science.Adv Mater2013;25: 6477–6512..
Akinoglu EM, Morfa AJ, Giersig M. Understanding anisotropic plasma etching of two-dimensional polystyrene opals for advanced materials fabrication.Langmuir2014;30: 12354–12361..
Schneider CA, Rasband WS, Eliceiri KW. NIH Image to ImageJ: 25 years of image analysis.Nat Methods2012;9: 671–675..
Homola J. Surface plasmon resonance sensors for detection of chemical and biological species.Chem Rev2008;108: 462–493..
Stewart ME, Anderton CR, Thompson LB, Maria J, Gray SKet al. Nanostructured plasmonic sensors.Chem Rev2008;108: 494–521..
Smythe EJ, Dickey MD, Bao JM, Whitesides GM, Capasso F. Optical antenna arrays on a fiber facet forin situsurface-enhanced Raman scattering detection.Nano Lett2009;9: 1132–1138..
Kahraman M, Daggumati P, Kurtulus O, Seker E, Wachsmann-Hogiu S. Fabrication and characterization of flexible and tunable plasmonic nanostructures.Sci Rep2013;3: 3396..
Liu CY, Wang SY, Chen G, Xu SP, Jia Qet al. A surface-enhanced Raman scattering (SERS)-active optical fiber sensor based on a three-dimensional sensing layer.Sens Biosensing Res2014;1: 8–14..
Meng W, Hu F, Jiang XH, Lu LD. Preparation of silver colloids with improved uniformity and stable surface-enhanced Raman scattering.Nanoscale Res Lett2015;10: 34..
Ouyang L, Zhu LH, Jiang JZ, Tang HQ. A surface-enhanced Raman scattering method for detection of trace glutathione on the basis of immobilized silver nanoparticles and crystal violet probe.Anal Chim Acta2014;816: 41–49..
Bouvrée A, D'Orlando A, Makiabadi T, Martin S, Louarn Get al. Nanostructured and nanopatterned gold surfaces: application to the surface-enhanced Raman spectroscopy.Gold Bull2013;46: 283–290..
Kudelski A. Raman studies of rhodamine 6G and crystal violet sub-monolayers on electrochemically roughened silver substrates: do dye molecules adsorb preferentially on highly SERS-active sites?Chem Phys Lett2005;414: 271–275..
Angeloni L, Smulevich G, Marzocchi MP. Resonance Raman spectrum of crystal violet.J Raman Spectrosc1979;8: 305–310..
Le Ru EC, Etchegoin PG. Quantifying SERS enhancements.MRS Bull2013;38: 631–640..
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