Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

Surendra B. Anantharaman; Jason Lynch; Christopher E. Stevens; Christopher Munley; Chentao Li; Jin Hou; Hao Zhang; Andrew Torma; Thomas Darlington; Francis Coen; Kevin Li; Arka Majumdar; P. James Schuck; Aditya Mohite; Hayk Harutyunyan; Joshua R. Hendrickson; Deep Jariwala

doi:10.1038/s41377-023-01334-9

Your Location：

Home >

Browse articles >

Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

Article

- Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites
- Light: Science & Applications Vol. 13, Issue 1, Pages: 13-22(2024)
- Affiliations：
- Author bio：
  
  asba@iitm.ac.in
  tdmj@seas.upenn.edu
- Funds：
- DOI：10.1038/s41377-023-01334-9
  CLC：
- Received：12 March 2023，
  
  Revised：25 October 2023，
  
  Accepted：2023-11-10，
  
  Published Online：01 January 2024，
  
  Published：2024-12
- Accepted：
Scan QR Code
Surendra B. Anantharaman, Jason Lynch, Christopher E. Stevens, et al. Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites[J]. Light: science & applications, 2024, 13(1): 13-22.
DOI：

Surendra B. Anantharaman, Jason Lynch, Christopher E. Stevens, et al. Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites[J]. Light: science & applications, 2024, 13(1): 13-22. DOI： 10.1038/s41377-023-01334-9.

摘要

Abstract

Excitons

bound electron–hole pairs

in two-dimensional hybrid organic inorganic perovskites (2D HOIPs) are capable of forming hybrid light-matter states known as exciton-polaritons (E–Ps) when the excitonic medium is confined in an optical cavity. In the case of 2D HOIPs

they can self-hybridize into E–Ps at specific thicknesses of the HOIP crystals that form a resonant optical cavity with the excitons. However

the fundamental properties of these self-hybridized E–Ps in 2D HOIPs

including their role in ultrafast energy and/or charge transfer at interfaces

remain unclear. Here

we demonstrate that >0.5 µm thick 2D HOIP crystals on Au substrates are capable of supporting multiple-orders of self-hybridized E–P modes. These E–Ps have high Q factors (>100) and modulate the optical dispersion for the crystal to enhance sub-gap absorption and emission. Through varying excitation energy and ultrafast measurements

we also confirm energy transfer from higher energy E–Ps to lower energy E–Ps. Finally

we also demonstrate that E–Ps are capable of charge transport and transfer at interfaces. Our findings provide new insights into charge and energy transfer in E–Ps opening new opportunities towards their manipulation for polaritonic devices.

Self-hybridized exciton–polaritons are shown to enable sub-bandgap absorption and emission in 2D perovskites. The energy absorbed by the perovskites are also found to transfer to few-layer graphene in a heterostructure.

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=70078632&type=

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=70078632&type=small

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=70078632&type=middle

关键词

Keywords

references

H. Dong et al. , Metal Halide Perovskite for next-generation optoelectronics: progresses and prospects . eLight 3 , 1 - 16 ( 2023 ). http://doi.org/10.1186/s43593-022-00033-z http://doi.org/10.1186/s43593-022-00033-z

H. Min et al. , Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes . Nature 598 , 444 - 450 ( 2021 ). http://doi.org/10.1038/s41586-021-03964-8 http://doi.org/10.1038/s41586-021-03964-8

Z.L. Hu et al. , Compact layer free mixed-cation lead mixed-halide perovskite solar cells . Chem. Commun. 54 , 2623 - 2626 ( 2018 ). http://doi.org/10.1039/C7CC06183H http://doi.org/10.1039/C7CC06183H

H. Li et al. , Revealing the output power potential of bifacial monolithic all-perovskite tandem solar cells . eLight 2 , 1 - 10 ( 2022 ). http://doi.org/10.1186/s43593-022-00028-w http://doi.org/10.1186/s43593-022-00028-w

J.J. Luo et al. , Efficient and stable emission of warm-white light from lead-free halide double perovskites . Nature 563 , 541 - 545 ( 2018 ). http://doi.org/10.1038/s41586-018-0691-0 http://doi.org/10.1038/s41586-018-0691-0

Y.H. Zhou et al. , Perovskite anion exchange: a microdynamics model and a polar adsorption strategy for precise control of luminescence color . Adv. Funct. Mater. 31 , 2106871 ( 2021 ). http://doi.org/10.1002/adfm.202106871 http://doi.org/10.1002/adfm.202106871

R. Wang et al. , Minimizing energy barrier in intermediate connection layer for monolithic tandem WPeLEDs with wide color gamut . Adv. Funct. Mater. 33 , 2215189 ( 2023 ). http://doi.org/10.1002/adfm.202215189 http://doi.org/10.1002/adfm.202215189

M.V. Kovalenko , L. Protesescu , M.I. Bodnarchuk , Properties and potential optoelectronic applications of lead halide perovskite nanocrystals . Science 358 , 745 - 750 ( 2017 ). http://doi.org/10.1126/science.aam7093 http://doi.org/10.1126/science.aam7093

A.K. Jena , A. Kulkarni , T. Miyasaka , Halide perovskite photovoltaics: background, status, and future prospects . Chem. Rev. 119 , 3036 - 3103 ( 2019 ). http://doi.org/10.1021/acs.chemrev.8b00539 http://doi.org/10.1021/acs.chemrev.8b00539

J.C. Blancon et al. , Semiconductor physics of organic–inorganic 2D halide perovskites . Nat. Nanotechnol. 2020 15:12 15 , 969 - 985 ( 2020 ).

E. Jokar et al. , Enhanced performance and stability of 3D/2D tin perovskite solar cells fabricated with a sequential solution deposition . ACS Energy Lett. 6 , 485 - 492 ( 2021 ). http://doi.org/10.1021/acsenergylett.0c02305 http://doi.org/10.1021/acsenergylett.0c02305

Z.P. Wang et al. , Efficient ambient-air-stable solar cells with 2D-3D heterostructured butylammonium-caesium-formamidinium lead halide perovskites . Nat. Energy 2 , 17135 ( 2017 ). http://doi.org/10.1038/nenergy.2017.135 http://doi.org/10.1038/nenergy.2017.135

S. Sidhik et al. , Deterministic fabrication of 3D/2D perovskite bilayer stacks for durable and efficient solar cells . Science 377 , 1425 - 1430 ( 2022 ). http://doi.org/10.1126/science.abq7652 http://doi.org/10.1126/science.abq7652

J. Chakkamalayath , N. Hiott , P.V. Kamat , How stable is the 2D/3D interface of metal halide perovskite under light and heat? . ACS Energy Lett. 8 , 169 - 171 ( 2023 ). http://doi.org/10.1021/acsenergylett.2c02408 http://doi.org/10.1021/acsenergylett.2c02408

J.S. Manser , J.A. Christians , P.V. Kamat , Intriguing optoelectronic properties of metal halide perovskites . Chem. Rev. 116 , 12956 - 13008 ( 2016 ). http://doi.org/10.1021/acs.chemrev.6b00136 http://doi.org/10.1021/acs.chemrev.6b00136

M.G. La-Placa et al. , Photoluminescence quantum yield exceeding 80% in low dimensional perovskite thin-films via passivation control . Chem. Commun. 53 , 8707 - 8710 ( 2017 ). http://doi.org/10.1039/C7CC04149G http://doi.org/10.1039/C7CC04149G

F. Liu et al. , Highly luminescent phase-stable CsPbI3 perovskite quantum dots achieving near 100% absolute photoluminescence quantum yield . ACS Nano 11 , 10373 - 10383 ( 2017 ). http://doi.org/10.1021/acsnano.7b05442 http://doi.org/10.1021/acsnano.7b05442

M.D. Smith , B.A. Connor , H.I. Karunadasa , Tuning the luminescence of layered halide perovskites . Chem. Rev. 119 , 3104 - 3139 ( 2019 ). http://doi.org/10.1021/acs.chemrev.8b00477 http://doi.org/10.1021/acs.chemrev.8b00477

Y. Li et al. , Author Correction: manipulating polariton condensates by Rashba-Dresselhaus coupling at room temperature . Nat. Commun. 13 , 4307 ( 2022 ). http://doi.org/10.1038/s41467-022-32032-6 http://doi.org/10.1038/s41467-022-32032-6

R. Su et al. , Perovskite semiconductors for room-temperature exciton-polaritonics . Nat. Mater. 20 , 1315 - 1324 ( 2021 ). http://doi.org/10.1038/s41563-021-01035-x http://doi.org/10.1038/s41563-021-01035-x

V. Agranovich , H. Benisty , C. Weisbuch , Organic and inorganic quantum wells in a microcavity: Frenkel-Wannier-Mott excitons hybridization and energy transformation . Solid State Commun. 102 , 631 - 636 ( 1997 ). http://doi.org/10.1016/S0038-1098(96)00433-4 http://doi.org/10.1016/S0038-1098(96)00433-4

J. Wenus et al. , Hybrid organic-inorganic exciton-polaritons in a strongly coupled microcavity . Phys. Rev. B 74 , 235212 ( 2006 ). http://doi.org/10.1103/PhysRevB.74.235212 http://doi.org/10.1103/PhysRevB.74.235212

A. Fieramosca et al. , Two-dimensional hybrid perovskites sustaining strong polariton interactions at room temperature . Sci. Adv. 5 , eaav9967 ( 2019 ). http://doi.org/10.1126/sciadv.aav9967 http://doi.org/10.1126/sciadv.aav9967

J. Wang et al. , Room temperature coherently coupled exciton-polaritons in two-dimensional organic-inorganic perovskite . ACS Nano 12 , 8382 - 8389 ( 2018 ). http://doi.org/10.1021/acsnano.8b03737 http://doi.org/10.1021/acsnano.8b03737

T.T. Wang et al. , Electrically pumped polarized exciton-polaritons in a halide perovskite microcavity . Nano Lett. 22 , 5175 - 5181 ( 2022 ). http://doi.org/10.1021/acs.nanolett.2c00906 http://doi.org/10.1021/acs.nanolett.2c00906

P. Bouteyre et al. , Room-temperature cavity polaritons with 3D hybrid perovskite: toward large-surface polaritonic devices . ACS Photonics 6 , 1804 - 1811 ( 2019 ). http://doi.org/10.1021/acsphotonics.9b00625 http://doi.org/10.1021/acsphotonics.9b00625

J. Wang et al. , Spontaneously coherent orbital coupling of counterrotating exciton polaritons in annular perovskite microcavities . Light Sci. Appl. 10 , 45 ( 2021 ). http://doi.org/10.1038/s41377-021-00478-w http://doi.org/10.1038/s41377-021-00478-w

Q.Y. Shang et al. , Surface plasmon enhanced strong exciton-photon coupling in hybrid inorganic-organic perovskite nanowires . Nano Lett. 18 , 3335 - 3343 ( 2018 ). http://doi.org/10.1021/acs.nanolett.7b04847 http://doi.org/10.1021/acs.nanolett.7b04847

J.E. Park et al. , Polariton dynamics in two-dimensional ruddlesden-popper perovskites strongly coupled with plasmonic lattices . ACS Nano 16 , 3917 - 3925 ( 2022 ). http://doi.org/10.1021/acsnano.1c09296 http://doi.org/10.1021/acsnano.1c09296

N.H.M. Dang et al. , Tailoring dispersion of room-temperature exciton-polaritons with perovskite-based subwavelength metasurfaces . Nano Lett. 20 , 2113 - 2119 ( 2020 ). http://doi.org/10.1021/acs.nanolett.0c00125 http://doi.org/10.1021/acs.nanolett.0c00125

S.B. Anantharaman et al. , Self-hybridized polaritonic emission from layered perovskites . Nano Lett. 21 , 6245 - 6252 ( 2021 ). http://doi.org/10.1021/acs.nanolett.1c02058 http://doi.org/10.1021/acs.nanolett.1c02058

X.X. He et al. , Oriented growth of ultrathin single crystals of 2D ruddlesden-popper hybrid lead iodide perovskites for high-performance photodetectors . ACS Appl. Mater. Interfaces 11 , 15905 - 15912 ( 2019 ). http://doi.org/10.1021/acsami.9b01825 http://doi.org/10.1021/acsami.9b01825

C.C. Stoumpos et al. , Ruddlesden-popper hybrid lead iodide perovskite 2D homologous semiconductors . Chem. Mater. 28 , 2852 - 2867 ( 2016 ). http://doi.org/10.1021/acs.chemmater.6b00847 http://doi.org/10.1021/acs.chemmater.6b00847

L.L. Mao et al. , Hybrid Dion-Jacobson 2D lead iodide perovskites . J. Am. Chem. Soc. 140 , 3775 - 3783 ( 2018 ). http://doi.org/10.1021/jacs.8b00542 http://doi.org/10.1021/jacs.8b00542

B.K. Song et al. , Determination of dielectric functions and exciton oscillator strength of two-dimensional hybrid perovskites . ACS Mater. Lett. 3 , 148 - 159 ( 2021 ). http://doi.org/10.1021/acsmaterialslett.0c00505 http://doi.org/10.1021/acsmaterialslett.0c00505

Hou, J. et al. Synthesis of 2D perovskite crystals via progressive transformation of quantum well thickness. Nat. Synth . https://doi.org/10.1038/s44160-023-00422-3 10.1038/s44160-023-00422-3 (2023).

E.P. Booker et al. , Formation of long-lived color centers for broadband visible light emission in low-dimensional layered perovskites . J. Am. Chem. Soc. 139 , 18632 - 18639 ( 2017 ). http://doi.org/10.1021/jacs.7b10223 http://doi.org/10.1021/jacs.7b10223

H. Hu et al. , Observation of defect luminescence in 2D Dion–Jacobson perovskites . Adv. Opt. Mater. 9 , 2101423 ( 2021 ). http://doi.org/10.1002/adom.202101423 http://doi.org/10.1002/adom.202101423

J.C. Blancon et al. , Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites . Science 355 , 1288 - 1292 ( 2017 ). http://doi.org/10.1126/science.aal4211 http://doi.org/10.1126/science.aal4211

E.D. Kinigstein et al. , Edge states drive exciton dissociation in Ruddlesden-Popper lead halide perovskite thin Films . ACS Mater. Lett. 2 , 1360 - 1367 ( 2020 ). http://doi.org/10.1021/acsmaterialslett.0c00333 http://doi.org/10.1021/acsmaterialslett.0c00333

S. Kahmann , E.K. Tekelenburg , H. Duim , M.E. Kamminga , M.A. Loi , Extrinsic nature of the broad photoluminescence in lead iodide-based Ruddlesden–Popper perovskites . Nat. Communications 11 , 2344 ( 2020 ). http://doi.org/10.1038/s41467-020-15970-x http://doi.org/10.1038/s41467-020-15970-x

S. Kahmann et al. , The origin of broad emission in 〈100〉 two-dimensional perovskites: extrinsic vs intrinsic processes . ACS Energy Lett. 7 , 4232 - 4241 ( 2022 ). http://doi.org/10.1021/acsenergylett.2c02123 http://doi.org/10.1021/acsenergylett.2c02123

D.G. Lidzey et al. , Experimental study of light emission from strongly coupled organic semiconductor microcavities following nonresonant laser excitation . Phys. Rev. B 65 , 195312 ( 2002 ). http://doi.org/10.1103/PhysRevB.65.195312 http://doi.org/10.1103/PhysRevB.65.195312

A. Fieramosca et al. , Tunable out-of-plane excitons in 2D single-crystal perovskites . ACS Photonics 5 , 4179 - 4185 ( 2018 ). http://doi.org/10.1021/acsphotonics.8b00984 http://doi.org/10.1021/acsphotonics.8b00984

H. Tang et al. , Urbach tail of anatase TiO 2 . Phys. Rev. B 52 , 7771 - 7774 ( 1995 ). http://doi.org/10.1103/PhysRevB.52.7771 http://doi.org/10.1103/PhysRevB.52.7771

S.B. Anantharaman , K. Jo , D. Jariwala , Exciton-photonics: from fundamental science to applications . ACS Nano 15 , 12628 - 12654 ( 2021 ). http://doi.org/10.1021/acsnano.1c02204 http://doi.org/10.1021/acsnano.1c02204

L.A.A. Pettersson , L.S. Roman , O. Inganäs , Modeling photocurrent action spectra of photovoltaic devices based on organic thin films . J. Appl. Phys. 86 , 487 - 496 ( 1999 ). http://doi.org/10.1063/1.370757 http://doi.org/10.1063/1.370757

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

No data

Related Author

No data

Related Institution

No data

⁰