Organic polaritonic light-emitting diodes with high luminance and color purity toward laser displays

Jianbo De; Ruiyang Zhao; Fan Yin; Chunling Gu; Teng Long; Han Huang; Xue Cao; Cunbin An; Bo Liao; Hongbing Fu; Qing Liao

doi:10.1038/s41377-024-01531-0

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Organic polaritonic light-emitting diodes with high luminance and color purity toward laser displays

Original Articles

- Organic polaritonic light-emitting diodes with high luminance and color purity toward laser displays
- Light: Science & Applications Vol. 13, Issue 9, Pages: 1956-1963(2024)
- Affiliations：
  
  1.Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, 100048 Beijing, China
  2.Beijing Special Engineering Design and Research Institute, 100028 Beijing, China
  3.Institute of Process Engineering, Chinese Academy of Sciences, 100190 Beijing, China
  4.Institute of Molecule Plus, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), 300072 Tianjin, China
  5.School of Materials Science and Engineering, Hunan University of Science and Technology, 411201 Xiangtan, Hunan, China
- Author bio：
  
  Hongbing Fu (hbfu@cnu.edu.cn)
  Qing Liao (liaoqing@cnu.edu.cn)
- Funds：
- DOI：10.1038/s41377-024-01531-0
  CLC：
- Received：07 March 2024，
  
  Revised：02 July 2024，
  
  Accepted：2024-07-15，
  
  Published Online：15 August 2024，
  
  Published：30 September 2024
- Accepted：
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De, J. B. et al. Organic polaritonic light-emitting diodes with high luminance and color purity toward laser displays. Light: Science & Applications, 13, 1956-1963 (2024).
DOI：

De, J. B. et al. Organic polaritonic light-emitting diodes with high luminance and color purity toward laser displays. Light: Science & Applications, 13, 1956-1963 (2024). DOI： 10.1038/s41377-024-01531-0.

摘要

Abstract

Achieving high-luminescence organic light-emitting devices (OLEDs) with narrowband emission and high color purity is important in various optoelectronic fields. Laser displays exhibit outstanding advantages in next-generation display technologies owing to their ultimate visual experience

but this remains a great challenge. Here

we develop a novel OLED based organic single crystals. By strongly coupling the organic exciton state to an optical microcavity

we obtain polariton electroluminescent (EL) emission from the polariton OLEDs (OPLEDs) with high luminance

narrow-band emission

high color purity

high polarization as well as excellent optically pumped polariton laser. Further

we evaluate the potential for electrically pumped polariton laser through theoretical analysis and provide possible solutions. This work provides a powerful strategy with a material–device combination that paves the way for electrically driven organic single-crystal-based polariton luminescent devices and possibly lasers.

关键词

Keywords

references

Kim, D. H. et al. High-efficiency electroluminescence and amplified spontaneous emission from a thermally activated delayed fluorescent near-infrared emitter. Nat. Photonics 12 , 98–104 (2018)..

Chan, C. Y. et al. Stable pure-blue hyperfluorescence organic light-emitting diodes with high-efficiency and narrow emission. Nat. Photonics 15 , 203–207 (2021)..

Chen, Y. et al. Approaching nearly 40% external quantum efficiency in organic light emitting diodes utilizing a green thermally activated delayed fluorescence emitter with an extended linear donor–acceptor–donor structure. Adv. Mater. 33 , 2103293 (2021)..

Jung, H. et al. Two-band optical gain and ultrabright electroluminescence from colloidal quantum dots at 1000 A cm −2 . Nat. Commun. 13 , 3734 (2022)..

Liu, Y. C. et al. All-organic thermally activated delayed fluorescence materials for organic light-emitting diodes. Nat. Rev. Mater. 3 , 18020 (2018)..

Zhao, W. J., He, Z. K. & Tang, B. Z. Room-temperature phosphorescence from organic aggregates. Nat. Rev. Mater. 5 , 869–885 (2020)..

Dong, H. Y. et al. Organic microcrystal vibronic lasers with full-spectrum tunable output beyond the Franck–Condon principle. Angew. Chem. Int. Ed. 57 , 3108–3112 (2018)..

Hestand, N. J. & Spano, F. C. Expanded theory of H- and J-molecular aggregates: the effects of vibronic coupling and intermolecular charge transfer. Chem. Rev. 118 , 7069–7163 (2018)..

Zang, C. X. et al. Top-emitting thermally activated delayed fluorescence organic light-emitting devices with weak light–matter coupling. Light Sci. Appl. 10 , 116 (2021)..

Park, I. S. et al. Achieving ultimate narrowband and ultrapure blue organic light-emitting diodes based on polycyclo-heteraborin multi-resonance delayed-fluorescence emitters. Adv. Mater. 34 , 2107951 (2022)..

Fardy, M. & Yang, P. D. Materials science—Lilliputian light sticks. Nature 451 , 408–409 (2008)..

Zou, Y. et al. High-performance narrowband pure-red OLEDs with external quantum efficiencies up to 36.1% and ultralow efficiency roll-off. Adv. Mater. 34 , 2201442 (2022)..

Lv, X. L. et al. Extending the π-skeleton of multi-resonance TADF materials towards high-efficiency narrowband deep-blue emission. Angew. Chem. Int. Ed. 61 , e202201588 (2022)..

Qiu, Y. T. et al. Narrowing the electroluminescence spectra of multiresonance emitters for high-performance blue OLEDs by a peripheral decoration strategy. ACS Appl. Mater. Interfaces 13 , 59035–59042 (2021)..

Mischok, A. et al. Highly efficient polaritonic light-emitting diodes with angle-independent narrowband emission. Nat. Photonics 17 , 393–400 (2023)..

Huang, Y. G. et al. Mini-LED, micro-LED and OLED displays: present status and future perspectives. Light Sci. Appl. 9 , 105 (2020)..

Qi, L. H. et al. Monolithic full-color active-matrix micro-LE D micro-display using InGaN/AlGaInP heterogeneous integration. Light Sci. Appl. 12 , 258 (2023)..

Weisbuch, C. et al. Observation of the coupled exciton-photon mode splitting in a semiconductor quantum microcavity. Phys. Rev. Lett. 69 , 3314–3317 (1992)..

Lidzey, D. G. et al. Room temperature polariton emission from strongly coupled organic semiconductor microcavities. Phys. Rev. Lett. 82 , 3316–3319 (1999)..

Kasprzak, J. et al. Bose–Einstein condensation of exciton polaritons. Nature 443 , 409–414 (2006)..

Amo, A. et al. Superfluidity of polaritons in semiconductor microcavities. Nat. Phys. 5 , 805–810 (2009)..

Sanvitto, D. & Kéna-Cohen, S. The road towards polaritonic devices. Nat. Mater. 15 , 1061–1073 (2016)..

Kéna-Cohen, S. & Forrest, S. R. Room-temperature polariton lasing in an organic single-crystal microcavity. Nat. Photonics 4 , 371–375 (2010)..

Lu, T. C. et al. Room temperature polariton lasing vs. photon lasing in a ZnO-based hybrid microcavity. Opt. Express 20 , 5530–5537 (2012)..

Ren, J. H. et al. Efficient bosonic condensation of exciton polaritons in an H-aggregate organic single-crystal microcavity. Nano Lett. 20 , 7550–7557 (2020)..

Chellappan, K. V., Erden, E. & Urey, H. Laser-based displays: a review. Appl. Opt. 49 , F79–F98 (2010)..

Zhao, J. Y. et al. Full-color laser displays based on organic printed microlaser arrays. Nat. Commun. 10 , 870 (2019)..

Graf, A. et al. Electrical pumping and tuning of exciton–polaritons in carbon nanotube microcavities. Nat. Mater. 16 , 911–917 (2017)..

Yin, F. et al. High-performance organic laser semiconductor enabling efficient light-emitting transistors and low-threshold microcavity lasers. Nano Lett. 22 , 5803–5809 (2022)..

Liu, D. et al. Organic laser molecule with high mobility, high photoluminescence quantum yield, and deep-blue lasing characteristics. J. Am. Chem. Soc. 142 , 6332–6339 (2020)..

Long, T. et al. Helical polariton lasing from topological valleys in an organic crystalline microcavity. Adv. Sci. 9 , 2203588 (2022)..

Kéna-Cohen, S., Davanço, M. & Forrest, S. R. Strong exciton-photon coupling in an organic single crystal microcavity. Phys. Rev. Lett. 101 , 116401 (2008)..

An, M. H. et al. Highly polarized emission from organic single-crystal light-emitting devices with a polarization ratio of 176. Optica 9 , 121 (2022)..

Wang, K. & Zhao, Y. S. Pursuing electrically pumped lasing with organic semiconductors. Chem 7 , 3221–3231 (2021)..

Slootsky, M., Zhang, Y. F. & Forrest, S. R. Temperature dependence of polariton lasing in a crystalline anthracene microcavity. Phys. Rev. B 86 , 045312 (2012)..

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