1.Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150080, China
2.Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou 450018, China
3.Research Center of Analysis and Measurement, Harbin Institute of Technology, Harbin 150080, China
4.School of Energy Science & Engineering, Harbin Institute of Technology, Harbin 150080, China
Zicheng Song (songzc@hit.edu.cn)
Zhibo Zhang (zhangzhibo_hit@163.com)
Tianyu Wang (tianyu_wang@hit.edu.cn)
Jiaqi Zhu (zhujq@hit.edu.cn)
Published:31 October 2024,
Published Online:30 August 2024,
Received:14 February 2024,
Revised:15 June 2024,
Accepted:17 July 2024
Scan QR Code
Zhang, R. C. et al. Multispectral smart window: Dynamic light modulation and electromagnetic microwave shielding. Light: Science & Applications, 13, 2331-2341 (2024).
Zhang, R. C. et al. Multispectral smart window: Dynamic light modulation and electromagnetic microwave shielding. Light: Science & Applications, 13, 2331-2341 (2024). DOI: 10.1038/s41377-024-01541-y.
A novel multispectral smart window has been proposed
which features dynamic modulation of light transmittance and effective shielding against electromagnetic microwave radiation. This design integrates liquid crystal dynamic scattering and dye doping techniques
enabling the dual regulation of transmittance and scattering within a single-layer smart window. Additionally
the precise control of conductive film thickness ensures the attainment of robust microwave signal shielding. We present a theoretical model for ion movement in the presence of an alternating electric field
along with a novel approach to manipulate negative dielectric constant. The proposed model successfully enables a rapid transition between light transparent
absorbing and haze states
with an optimum drive frequency adjustable to approximately 300 Hz. Furthermore
the resistive design of the conductive layer effectively mitigates microwave radiation within the 2−18 GHz range. These findings offer an innovative perspective for future advancements in environmental construction.
Zhang, R. C. et al. Advanced liquid crystal-based switchable optical devices for light protection applications: principles and strategies.Light Sci. Appl.12, 11 (2023)..
Abbasi, H., Antunes, M.&Velasco, J. I. Recent advances in carbon-based polymer nanocomposites for electromagnetic interference shielding.Prog. Mater. Sci.103, 319–373 (2019)..
Granqvist, C. G. et al. Recent advances in electrochromics for smart windows applications.Sol. Energy63, 199–216 (1998)..
Deng, B. et al. An ultrafast, energy-efficient electrochromic and thermochromic device for smart windows.Adv. Mater.35, 2302685 (2023)..
Zhao, Q. et al. Printing of WO3/ITO nanocomposite electrochromic smart windows.Sol. Energy Mater. Sol. Cells194, 95–102 (2019)..
Zhang, S. L. et al. Amorphous and porous tungsten oxide films for fast-switching dual-band electrochromic smart windows.Adv. Opt. Mater.11, 2202115 (2023)..
Ghosh, A.&Norton, B. Durability of switching behaviour after outdoor exposure for a suspended particle device switchable glazing.Sol. Energy Mater. Sol. Cells163, 178–184 (2017)..
Ghosh, A., Norton, B.&Duffy, A. First outdoor characterisation of a PV powered suspended particle device switchable glazing.Sol. Energy Mater. Sol. Cells157, 1–9 (2016)..
Yu, B. H. et al. Light shutter using dye-doped cholesteric liquid crystals with polymer network structure.J. Inf. Disp.18, 13–17 (2017)..
Liang, X. et al. A temperature and electric field-responsive flexible smart film with full broadband optical modulation.Mater. Horiz.4, 878–884 (2017)..
He, Z. M. et al. Silicon nanostructure-doped polymer/nematic liquid crystal composites for low voltage-driven smart windows.Nanotechnology33, 085205 (2022)..
Katariya-Jain, A.&Deshmukh, R. R. Effects of dye doping on electro-optical, thermo-electro-optical and dielectric properties of polymer dispersed liquid crystal films.J. Phys. Chem. Solids160, 110363 (2022)..
Liang, X. et al. A roll-to-roll process for multi-responsive soft-matter composite films containing CsxWO3nanorods for energy-efficient smart window applications.Nanoscale Horiz.2, 319–325 (2017)..
Liang, X. et al. Dual-band modulation of visible and near-infrared light transmittance in an all-solution-processed hybrid micro-nano composite film.ACS Appl. Mater. Interfaces9, 40810–40819 (2017)..
Kim, M. et al. Fabrication of microcapsules for dye-doped polymer-dispersed liquid crystal-based smart windows.ACS Appl. Mater. Interfaces7, 17904–17909 (2015)..
Hu, X. W. et al. Stable andscalable smart window based on polymer stabilized liquid crystals.J. Appl. Polym. Sci.137, 48917 (2020)..
Zhang, Z. B. et al. Visible and infrared optical modulation of PSLC smart films doped with ATO nanoparticles.Dalton Trans.50, 10033–10040 (2021)..
Ängskog, P. et al. Shielding effectiveness and HPM vulnerability of energy-saving windows and window panes.IEEE Trans. Electromagn. Compat.61, 870–877 (2019)..
Zhan, Y. Y. et al. Electrohydrodynamic instabilities for smart window applications.Liq. Cryst.47, 977–983 (2020)..
Konshina, E. A.&Shcherbinin, D. P. Study of dynamic light scattering in nematic liquid crystal and its optical, electrical and switching characteristics.Liq. Cryst.45, 292–302 (2018)..
Zhan, Y. Y. et al. Light-driven electrohydrodynamic instabilities in liquid crystals.Adv. Funct. Mater.28, 1707436 (2018)..
Huh, J. W. et al. Ion-doped liquid-crystal cell with low opaque-state specular transmittance based on electro-hydrodynamic effect.Dyes Pigments150, 16–20 (2018)..
Huh, J. W. et al. Tristate switching of a liquid-crystal cell among initial transparent, haze-free dark, and high-haze dark states.J. Mol. Liq.281, 81–85 (2019)..
Chen, C. W. et al. Normally transparent smart window based on electrically induced instability in dielectrically negative cholesteric liquid crystal.Opt. Mater. Express8, 691–697 (2018)..
Han, C. H.&Oh, S. W. A high-haze liquid crystal grating device with asymmetric anchoring energies.Displays81, 102581 (2024)..
Huh, J. W. et al. Filtering of yellow light in a liquid-crystal light shutter for higher color contrast and reduced glare.J. Mol. Liq.327, 114846 (2020)..
Li, C. C. et al. Versatile energy-saving smart glass based on tristable cholesteric liquid crystals.ACS Appl. Energy Mater.3, 7601–7609 (2020)..
Madhuri, P. L. et al. Cochleate-doped liquid crystal as switchable metamaterial window mediated by molecular orientation modified aggregation.Part. Part. Syst. Charact.37, 2000067 (2020)..
Abdulhalim, I. et al. Novel easy to fabricate liquid crystal composite with potential for electrically or thermally controlled transparency windows.Opt. Express27, 17387–17401 (2019)..
Madhuri, P. L. et al. Voltage controlled scattering from porous silicon Mie-particles in liquid crystals.J. Mol. Liq.281, 108–116 (2019)..
Ali, S. et al. Preparation of polyethylene and ethylene/methacrylic acid copolymer blend films with tunable surface properties through manipulating processing parameters during film blowing.Polymers11, 1565 (2019)..
Xia, Y. et al. High-efficiency and reliable smart photovoltaic windows enabled by multiresponsive liquid crystal composite films and semi-transparent perovskite solar cells.Adv. Energy Mater.9, 1900720 (2019)..
Huang, J. H. et al. Simultaneous achievement of high visible transmission and near-infrared heat shielding in flexible liquid crystal-based smart windows via electrode design.Sol. Energy188, 857–864 (2019)..
De Volder, M. F. L. et al. Carbon nanotubes: present and future commercial applications.Science339, 535–539 (2013)..
Song, W. L. et al. Ionic conductive gels for optically manipulatable microwave stealth structures.Adv. Sci.7, 1902162 (2020)..
Heilmeier, G. H., Zanoni, L. A.&Barton, L. A. Dynamic scattering: a new electrooptic effect in certain classes of nematic liquid crystals.Proc. IEEE56, 1162–1171 (1968)..
Ong, H. L. Electro-optical properties of guest-host nematic liquid-crystal displays.J. Appl. Phys.63, 1247–1249 (1988)..
Koide, N. The Liquid Crystal Display Story. (Tokyo: Springer, 2014).
Belyaev, B. A., Drokin, N. A.&Maslennikov, A. N. Impedance spectroscopy investigation of liquid crystals doped with ionic surfactants.Phys. Solid State56, 1455–1462 (2014)..
Sima, W. X. et al. Improved model of activation energy absorption for different electrical breakdowns in semi-crystalline insulating polymers.J. Phys. D: Appl. Phys.51, 215301 (2018)..
Wang, L. et al. Stimuli-directed self-organized chiral superstructures for adaptive windows enabled by mesogen-functionalized graphene.Mater. Today20, 230–237 (2017)..
Yang, M. Y. et al. Bioinspired phototropic MXene-reinforced soft tubular actuators for omnidirectional light-tracking and adaptive photovoltaics.Adv. Funct. Mater.32, 2201884 (2022)..
Bisoyi, H. K.&Li, Q. Liquid crystals: versatile self-organized smart soft materials.Chem. Rev.122, 4887–4926 (2022)..
Xiong, J. H.&Wu, S. T. Planar liquid crystal polarization optics for augmented reality and virtual reality: from fundamentals to applications.eLight1, 3 (2021)..
Zheng, Z. G. et al. Three-dimensional control of the helical axis of a chiral nematic liquid crystal by light.Nature531, 352–356 (2016)..
Wang, L., Urbas, A. M.&Li, Q. Nature-inspired emerging chiral liquid crystal nanostructures: from molecular self-assembly to DNA mesophase and nanocolloids.Adv. Mater.32, 1801335 (2020)..
Zhang, X.et al. Liquid crystal-templated chiral nanomaterials: from chiral plasmonics to circularly polarized luminescence.Light Sci. Appl.11, 223 (2022)..
Gao, J. J. et al. Stimuli-responsive photonic actuators for integrated biomimetic and intelligent systems.Respons. Mater.1, e20230008 (2023)..
Lan, R. C. et al. Adaptive liquid crystal polymers based on dynamic bonds: from fundamentals to functionalities.Respons. Mater.2, e20230030 (2024)..
Lin, K. T. et al. Highly efficient flexible structured metasurface by roll-to-roll printing for diurnal radiative cooling.eLight3, 22 (2023)..
Zhang, X. et al. Three-dimensional electrochromic soft photonic crystals based on MXene-integrated blue phase liquid crystals for bioinspired visible and infrared camouflage.Angew. Chem. Int. Ed.61, e202211030 (2022)..
Yang, J. J. et al. Beyond the visible: bioinspired infrared adaptive materials.Adv. Mater.33, 2004754 (2021)..
Ma, S. S. et al. Responsive soft actuators with MXene nanomaterials.Respons. Mater.2, e20230026 (2024)..
Ni, Y. B. et al. Computational spectropolarimetry with a tunable liquid crystal metasurface.eLight2, 23 (2022)..
Wang, Z. Y. et al. Vectorial liquid-crystal holography.eLight4, 5 (2024)..
Kim, D. H. et al. Transparent and flexible film for shielding electromagnetic interference.Mater. Des.89, 703–707 (2016)..
Hosseini, E. et al. Filler-free conducting polymers as a new class of transparent electromagnetic interference shields.ACS Appl. Mater. Interfaces12, 28596–28606 (2020)..
Zhou, B. et al. Flexible MXene/silver nanowires-based transparent conductive film with electromagnetic interference shielding and electro-photo-thermal performances.ACS Appl. Mater. Interfaces12, 40859–40869 (2020)..
Hu, M. J. et al. Flexible transparent PES/silver nanowires/PET sandwich-structured film for high-efficiency electromagnetic interference shielding.Langmuir28, 7101–7106 (2012)..
Liang, X. W. et al. Room-temperature nanowelding of a silver nanowire network triggered by hydrogen chloride vapor for flexible transparent conductive films.ACS Appl. Mater. Interfaces9, 40857–40867 (2017)..
Zhang, H. L., Xia, Y.&Gai, J. G. Ultrathin active layer for transparent electromagnetic shielding window.ACS Omega3, 2765–2772 (2018)..
Cheng, C. M. et al. Study on shielding effectiveness of high transmittance coating film glasses against electromagnetic pulse.Technologies11, 175 (2023)..
0
Views
0
Downloads
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution