1.School of Optoelectronic Science and Engineering & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006, China
2.National University of Singapore Suzhou Research Institute, Dushu Lake Science and Education Innovation District, Suzhou 215123, China
Zhenwei Ren (zhwren@suda.edu.cn)
Yu Chen (chenyu_ny@suda.edu.cn)
Published:30 November 2024,
Published Online:26 September 2024,
Received:12 June 2024,
Revised:27 July 2024,
Accepted:22 August 2024
Scan QR Code
Luo, C. Z. et al. Ultrahigh-resolution, high-fidelity quantum dot pixels patterned by dielectric electrophoretic deposition. Light: Science & Applications, 13, 2745-2755 (2024).
Luo, C. Z. et al. Ultrahigh-resolution, high-fidelity quantum dot pixels patterned by dielectric electrophoretic deposition. Light: Science & Applications, 13, 2745-2755 (2024). DOI: 10.1038/s41377-024-01601-3.
The high pixel resolution is emerging as one of the key parameters for the next-generation displays. Despite the development of various quantum dot (QD) patterning techniques
achieving ultrahigh-resolution (
>
10
000 pixels per inch (PPI)) and high-fidelity QD patterns is still a tough challenge that needs to be addressed urgently. Here
we propose a novel and effective approach of orthogonal electric field-induced template-assisted dielectric electrophoretic deposition to successfully achieve one of the highest pixel resoluti
ons of 23090 (PPI) with a high fidelity of up to 99%. Meanwhile
the proposed strategy is compatible with the preparation of QD pixels based on perovskite CsPbBr
3
and conventional CdSe QDs
exhibiting a wide applicability for QD pixel fabrication. Notably
we further demonstrate the great value of our approach to achieve efficiently electroluminescent QD pixels with a peak external quantum efficiency of 16.5%. Consequently
this work provides a general approach for realizing ultrahigh-resolution and high-fidelity patterns based on various QDs and a novel method for fabricating QD-patterned devices with high performance.
Hassan, Y. et al. Ligand-engineered bandgap stability in mixed-halide perovskite LEDs.Nature591, 72–77 (2021)..
Coe, S. et al. Electroluminescence from single monolayers of nanocrystals in molecular organic devices.Nature420, 800–803 (2002)..
Colvin, V. L., Schlamp, M. C.&Alivisatos, A. P. Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer.Nature370, 354–357 (1994)..
Yang, X. L. et al. Efficient green light-emitting diodes based on quasi-two-dimensional composition and phase engineered perovskite with surface passivation.Nat. Commun.9, 570 (2018)..
Huang, P. et al. Nonlocal interaction enhanced biexciton emission in large CsPbBr3nanocrystals.eLight3, 10 (2023)..
Dong, H. et al. Metal halide perovskite for next-generation optoelectronics: progresses and prospects.eLight3, 3 (2023)..
Joo, W. J. et al. Metasurface-driven OLED displays beyond 10, 000 pixels per inch.Science370, 459–463 (2020)..
Bae, J. et al. Quantum dot-integrated gan light-emitting diodes with resolution beyond the retinal limit.Nat. Commun.13, 1862 (2022)..
Xiao, P. W. et al. Surface passivation of intensely luminescent all-inorganic nanocrystals and their direct optical patterning.Nat. Commun.14, 49 (2023)..
Yang, J. et al. High-resolution patterning of colloidal quantum dots via non-destructive, light-driven ligand crosslinking.Nat. Commun.11, 2874 (2020)..
Shi, L. F. et al. In situ inkjet printing strategy for fabricating perovskite quantum dot patterns.Adv. Funct. Mater.29, 1903648 (2019)..
Keum, H. et al. Photoresist contact patterning of quantum dot films.ACS Nano12, 10024–10031 (2018)..
Liu, D. et al. Direct optical patterning of perovskite nanocrystals with ligand cross-linkers.Sci. Adv.8, eabm8433 (2022)..
Wei, C. T. et al. A universal ternary-solvent-ink strategy toward efficient inkjet-printed perovskite quantum dot light-emitting diodes.Adv. Mater.34, 2107798 (2022)..
Shi, S. C. et al. In situ inkjet printing patterned lead halide perovskite quantum dot color conversion films by using cheap and eco-friendly aqueous inks.Small Methods5, 2000889 (2021)..
Bai, W. H. et al. Microscale perovskite quantum dot light-emitting diodes (micro-PeLEDs) for full-color displays.Adv. Opt. Mater.10, 2200087 (2022)..
Li, Z. J. et al. Mass transfer printing of metal-halide perovskite films and nanostructures.Adv. Mater.34, 2203529 (2022)..
Kwon, J. I. et al. Ultrahigh-resolution full-color perovskite nanocrystal patterning for ultrathin skin-attachable displays.Sci. Adv.8, eadd0697 (2022)..
Meng, T. T. et al. Ultrahigh-resolution quantum-dot light-emitting diodes.Nat. Photonics16, 297–303 (2022)..
Mei, W. H. et al. High-resolution, full-color quantum dot light-emitting diode display fabricated via photolithography approach.Nano Res.13, 2485–2491 (2020)..
Park, S. Y. et al. Patterning quantum dots via photolithography: a review.Adv. Mater.35, 2300546 (2023)..
Mao, C. M. et al. Ultra-high-resolution perovskite quantum dot light-emitting diodes.Adv. Opt. Mater.11, 2202058 (2023)..
Luo, C. Z. et al. High-resolution, highly transparent, and efficient quantum dot light-emitting diodes.Adv. Mater.35, 2303329 (2023)..
Zhao, J. Y. et al. Large-area patterning of full-color quantum dot arrays beyond 1000 pixels per inch by selective electrophoretic deposition.Nat. Commun.12, 4603 (2021)..
Yu, E. S. et al. Precise capture and dynamic relocation of nanoparticulate biomolecules through dielectrophoretic enhancement by vertical nanogap architectures.Nat. Commun.11, 2804 (2020)..
Masitas, R. A., Allen, S. L.&Zamborini, F. P. Size-dependent electrophoretic deposition of catalytic gold nanoparticles.J. Am. Chem. Soc.138, 15295–15298 (2016)..
Zhang, H. Y. et al. Direct assembly of large area nanoparticle arrays.ACS Nano12, 7529–7537 (2018)..
Zhang, Y. D. et al. Precise patterning of organic single crystals via capillary-assisted alternating-electric field.Small13, 1604261 (2017)..
Chinappi, M. et al. Analytical model for particle capture in nanopores elucidates competition among electrophoresis, electroosmosis, and dielectrophoresis.ACS Nano14, 15816–15828 (2020)..
Li, L. J. et al. Size-dependent performances in homogeneous, controllable, and large-area silicon wire array photocathode.J. Power Sources473, 228580 (2020)..
Zhang, P. P. et al. Direct in situ photolithography of perovskite quantum dots based on photocatalysis of lead bromide complexes.Nat. Commun.13, 6713 (2022)..
Minh, D. N. et al. Perovskite nanoparticle composite films by size exclusion lithography.Adv. Mater.30, 1802555 (2018)..
Yang, X. Y. et al. Towards micro-PeLED displays.Nat. Rev. Mater.8, 341–353 (2023)..
Lee, W. et al. High-resolution spin-on-patterning of perovskite thin films for a multiplexed image sensor array.Adv. Mater.29, 1702902 (2017)..
An, H. J., Kim, M. S.&Myoung, J. M. Strategy for the fabrication of perovskite-based green micro LED for ultra high-resolution displays by micro-molding process and surface passivation.Chem. Eng. J.453, 139927 (2023)..
Gao, H. J. et al. High-performance, high-resolution quantum dot light-emitting devices through photolithographic patterning.Org. Electron.108, 106609 (2022)..
Song, K. M. et al. Noninvasive and direct patterning of high-resolution full-color quantum dot arrays by programmed microwetting.ACS Nano16, 16598–16607 (2022)..
Cho, H. et al. Direct optical patterning of quantum dot light-emitting diodes via in situ ligand exchange.Adv. Mater.32, 2003805 (2020)..
Ko, J. et al. Ligand-assisted direct photolithography of perovskite nanocrystals encapsulated with multifunctional polymer ligands for stable, full-colored, high-resolution displays.Nano Lett.21, 2288–2295 (2021)..
Maeng, S. et al. Direct photocatalytic patterning of colloidal emissive nanomaterials.Sci. Adv.9, eadi6950 (2023)..
Zhang, H., Su, Q.&Chen, S. M. Suppressing förster resonance energy transfer in close-packed quantum-dot thin film: toward efficient quantum-dot light-emitting diodes with external quantum efficiency over 21.6%.Adv. Opt. Mater.8, 1902092 (2020)..
Chiba, T. et al. Anion-exchange red perovskite quantum dots with ammonium iodine salts for highly efficient light-emitting devices.Nat. Photonics12, 681–687 (2018)..
Tsai, H. et al. Bright and stable light-emitting diodes made with perovskite nanocrystals stabilized in metal–organic frameworks.Nat. Photonics15, 843–849 (2021)..
0
Views
0
Downloads
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution