Excitation-wavelength-dependent persistent luminescence from single-component nonstoichiometric CaGa<sub>x</sub>O<sub>4</sub>:Bi for dynamic anti-counterfeiting

Bo-Mei Liu; Yue Lin; Yingchun Liu; Bibo Lou; Chong-Geng Ma; Hui Zhang; Jing Wang

doi:10.1038/s41377-024-01635-7

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Excitation-wavelength-dependent persistent luminescence from single-component nonstoichiometric CaGa_xO₄:Bi for dynamic anti-counterfeiting

Original Articles

- Excitation-wavelength-dependent persistent luminescence from single-component nonstoichiometric CaGa_xO₄:Bi for dynamic anti-counterfeiting
- Light: Science & Applications Vol. 13, Issue 12, Pages: 3064-3075(2024)
- Affiliations：
  
  1.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, China
  2.Ministry of Education Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry, Sun Yat-sen University, Guangzhou, China
  3.Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center, Jieyang, China
  4.School of Optoelectronic Engineering & CQUPT-BUL Innovation Institute, Chongqing University of Posts and Telecommunications, Chongqing, China
  5.Nanchang Research Institute, Sun Yat-sen University, Nanchang, Jiangxi, China
- Author bio：
  
  Bo-Mei Liu (liubomei@gdut.edu.cn)
  Chong-Geng Ma (cgma.ustc@gmail.com)
  Jing Wang (ceswj@mail.sysu.edu.cn)
- Funds：
- DOI：10.1038/s41377-024-01635-7
  CLC：
- Published：31 December 2024，
  
  Published Online：10 October 2024，
  
  Received：30 May 2024，
  
  Revised：27 August 2024，
  
  Accepted：11 September 2024
- Accepted：
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Liu, B. M. et al. Excitation-wavelength-dependent persistent luminescence from single-component nonstoichiometric CaGa_xO₄:Bi for dynamic anti-counterfeiting. Light: Science & Applications, 13, 3064-3075 (2024).
DOI：

Liu, B. M. et al. Excitation-wavelength-dependent persistent luminescence from single-component nonstoichiometric CaGa_xO₄:Bi for dynamic anti-counterfeiting. Light: Science & Applications, 13, 3064-3075 (2024). DOI： 10.1038/s41377-024-01635-7.

摘要

Abstract

Materials capable of dynamic persistent luminescence (PersL) within the visible sp

ectrum are highly sought after for applications in display

biosensing

and information security. However

PersL materials with eye-detectable and excitation-wavelength-dependent characteristics are rarely achieved. Herein

a nonstoichiometric compound CaGa

:Bi (

2) is present

which demonstrates ultra-long

color-tunable PersL. The persistent emission wavelength can be tuned by varying the excitation wavelength

enabling dynamic color modulation from the green to the orange region within the visible spectrum. Theoretical calculations

in conjunction with experimental observations

are utilized to elucidate the thermodynamic charge transitions of various defect states

thereby providing insights into the relationship between Bi

emitters

traps

and multicolored PersL. Furthermore

the utility of color-tunable PersL materials and flexible devices is showcased for use in visual sensing of invisible ultraviolet light

multicolor display

information encryption

and anti-counterfeiting. These discoveries create new opportunities to develop smart photoelectric materials with dynamically controlled PersL for various applications.

关键词

Keywords

references

Shen, Y. et al. Stimulus-responsive polymer materials toward multi-mode and multi-level information anti-counterfeiting: recent advances and future challenges.Chem. Soc. Rev.53, 606–623 (2024)..

Leem, J. W. et al. Edible matrix code with photogenic silk proteins.ACS Cent. Sci.8, 513–526 (2022)..

Ji, X. F. et al. Encoding, reading, and transforming information using multifluorescent supramolecular polymeric hydrogels.Adv. Mater.30, 1705480 (2018)..

Guo, D. et al. Excitation-wavelength-dependent fluorescent organohydrogel for dynamic information anti-counterfeiting.Chin. Chem. Lett.34, 108347 (2023)..

Abdollahi, A. et al. Photoluminescent and chromic nanomaterials for anticounterfeiting technologies: recent advances and future challenges.ACS Nano14, 14417–14492 (2020)..

Liu, B. M. et al. A High-efficiency blue-LED-excitable NIR-Ⅱ-emitting MgO:Cr3+,Ni2+phosphor for future broadband light source toward multifunctional NIR spectroscopy applications.Chem. Eng. J.452, 139313 (2023)..

Zheng, T. C. et al. Mn2+and Sb3+codoped Cs2ZnCl4metal halide with excitation-wavelength-dependent emission for fluorescence anticounterfeiting.Inorg. Chem.62, 17352–17361 (2023)..

Shi, Y. R. et al. Variable halide perovskites: diversification of anti-counterfeiting applications.Mater. Chem. Front.7, 6085–6106 (2023)..

Xie, W. W. et al. Anti-Kasha triplet energy transfer and excitation wavelength dependent persistent luminescence from host-guest doping systems.Nat. Commun.14, 8098 (2023)..

Xiao, G. W. et al. CO2-responsive tunable persistent luminescence in a hydrogen-bond organized two-component ionic crystal.Chem. Commun.59, 10113–10116 (2023)..

Wang, Z. et al. White light and color‐tuning long persistent luminescence from metal halide based metal‐organic frameworks.Adv. Funct. Mater.33, 2300021 (2023)..

Xu, J.&Tanabe, S. Persistent luminescence instead of phosphorescence: history, mechanism, and perspective.J. Lumin.205, 581–620 (2019)..

Kuang, Q. Q. et al. Recent advances in the anti-counterfeiting applications of long persistent phosphors.Phys. Chem. Chem. Phys.25, 17759–17768 (2023)..

Shi, C. et al. Multiresponsive luminescence materials: richer color than chameleon materials.Adv. Optical Mater.8, 2000007 (2020)..

Pei, P. X. et al. An advanced tunable multimodal luminescent La4GeO8: Eu2+, Er3+phosphor for multicolor anticounterfeiting.Adv. Funct. Mater.31, 2102479 (2021)..

Gu, L. et al. Colour-tunable ultra-long organic phosphorescence of a single-component molecular crystal.Nat. Photonics13, 406–411 (2019)..

Man, Z. W. et al. Host surface-induced excitation wavelength-dependent organic afterglow.J. Am. Chem. Soc.145, 13392–13399 (2023)..

Zong, S. Y. et al. Time-dependent and excitation-dependent afterglow color evolution from the assembly of dual carbon dots in zeolite.Nano Lett.24, 1859–1866 (2024)..

Shi, W. Y. et al. Time-dependent phosphorescence color of carbon dots in binary salt matrices through activations by structural confinement and defects for dynamic information encryption.Angew. Chem. Int. Ed.62, e202303063 (2023)..

Wang, Z. et al. Reversible acid-base long persistent luminescence switch based on amino-functionalized metal-organic frameworks.Inorg. Chem.63, 1188–1196 (2024)..

Liu, C. M. et al. Excitation wavelength dependent luminescence of LuNbO4: Pr3+—influences of intervalence charge transfer and host sensitization.J. Phys. Chem. C120, 26044–26053 (2016)..

Wang, Z. H. et al. Color-tunable polymeric long-persistent luminescence based on polyphosphazenes.Adv. Mater.32, 1907355 (2020)..

Fu, P. Y. et al. One/two-photon-excited ESIPT-attributed coordination polymers with wide temperature range and color-tunable long persistent luminescence.Angew. Chem. Int. Ed.62, e202309172 (2023)..

Chen, K. Y. et al. A facile strategy for achieving polymeric afterglow materials with wide color‐tunability and persistent near‐infrared luminescence.Adv. Funct. Mater.34, 2312883 (2024)..

Xiao, F. M. et al. Guest-host doped strategy for constructing ultralong-lifetime near-infrared organic phosphorescence materials for bioimaging.Nat. Commun.13, 186 (2022)..

Shi, C. et al. Excitation wavelength-dependent dual-mode luminescence emission for dynamic multicolor anticounterfeiting.ACS Appl. Mater. Interfaces11, 18548–18554 (2019)..

Li, X. et al. Color-tunable persistent luminescence phosphor for multimode dynamic anti-counterfeiting.Mater. Today Chem.30, 101594 (2023)..

Gao, D. L. et al. Quintuple-mode dynamic anti-counterfeiting using multi-mode persistent phosphors.J. Mater. Chem. C9, 16634–16644 (2021)..

Jiang, T. et al. Multistimuli‐responsive display materials to encrypt differentiated information in bright and dark fields.Adv. Funct. Mater.29, 1906068 (2019)..

Wang, L. P. et al. Engineering trap distribution to achieve multicolor persistent and photostimulated luminescence from ultraviolet to near-infrared Ⅱ.Matter6, 4261–4273 (2023)..

Awater, R. H. P.&Dorenbos, P. Towards a general concentration quenching model of Bi3+luminescence.J. Lumin.188, 487–489 (2017)..

Lou, B. B. et al. Understanding the defect levels and photoluminescence in a series of bismuth-doped perovskite oxides: first-principles study.Phys. Rev. B104, 115101 (2021)..

Bessière, A. et al. Storage of visible light for long-lasting phosphorescence in chromium-doped zinc gallate.Chem. Mater.26, 1365–1373 (2014)..

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Excitation-wavelength-dependent persistent luminescence from single-component nonstoichiometric CaGaxO4:Bi for dynamic anti-counterfeiting

DOI：10.1038/s41377-024-01635-7

摘要

Abstract

关键词

Keywords

references

Excitation-wavelength-dependent persistent luminescence from single-component nonstoichiometric CaGa_xO₄:Bi for dynamic anti-counterfeiting