Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal

Hao Suo; Nan Wang; Yu Zhang; Xin Zhang; Jinmeng Xiang; Xiaojia Wang; Guansheng Xing; Dongxu Guo; Jiwen Chang; Yu Wang; Panlai Li; Zhijun Wang; Yuhai Zhang; Bing Chen; Shuzhou Li; Chongfeng Guo; Feng Wang

doi:10.1038/s41377-024-01689-7

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Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal

Original Articles

- Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal
- Light: Science & Applications Vol. 14, Issue 1, Pages: 186-196(2025)
- Affiliations：
  
  1.Hebei Key Laboratory of Optic-electronic Information and Materials, College of Physics Science & Technology, Hebei University, Baoding 071002, China
  2.Department of Materials Science and Engineering, City University of Hong Kong, Kowloon 999077 Hong Kong SAR, China
  3.State Key Laboratory of Photon-Technology in Western China Energy, Institute of Photonics & PhotonTechnology, Northwest University, Xi'an 710127, China
  4.Institute for Advanced Interdisciplinary Research, University of Jinan, Jinan, Shandong 250022, China
  5.College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing 210023, China
  6.School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore
- Author bio：
  
  Hao Suo (suo@hbu.edu.cn)
  Chongfeng Guo (guocf@nwu.edu.cn)
  Feng Wang (fwang24@cityu.edu.hk)
- Funds：
- DOI：10.1038/s41377-024-01689-7
  CLC：
- Published：31 January 2025，
  
  Published Online：02 January 2025，
  
  Received：11 September 2024，
  
  Revised：12 November 2024，
  
  Accepted：2024-11-12
- Accepted：
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Suo, H. et al. Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal. Light: Science & Applications, 14, 186-196 (2025).
DOI：

Suo, H. et al. Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal. Light: Science & Applications, 14, 186-196 (2025). DOI： 10.1038/s41377-024-01689-7.

摘要

Abstract

Low-dimensional lead-free metal halide perovskites are highly attractive for cutting-edge optoelectronic applications. Herein

we report a class of scandium-based double perovskite crystals comprising antimony dopants that can generate multiexcitonic emissions in the ultraviolet

blue

and yellow spectral regions. Owing to the zero-dimensional nature of the crystal lattice that minimizes energy crosstalk

different excitonic states in the crystals can be selectively excited by ultraviolet light

X-ray irradiation

and mechanical action

enabling dynamic control of steady/transient-state spectral features by modulating the excitation modes. Remarkably

the transparent crystal exhibits highly efficient white photoluminescence (quantum yield > 97%)

X-ray excited blue emission with long afterglow (duration > 9 h)

and high-brightness self-reproducible violet-blue mechanoluminescence. These findings reveal the exceptional capability of low-dimensional perovskite crystals for integrating various excitonic luminescence

offering exciting opportunities for multi-level data encryption and all-in-one authentication technologies.

关键词

Keywords

references

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