Nonlinear memristive computational spectrometer

Xin Li; Jie Wang; Feilong Yu; Jin Chen; Xiaoshuang Chen; Wei Lu; Guanhai Li

doi:10.1038/s41377-024-01703-y

Go to Nature Website

Your Location：

Home >

Browse articles >

Nonlinear memristive computational spectrometer

Article

- Nonlinear memristive computational spectrometer
- Light: Science & Applications Vol. 14, Issue 1, (2025)
- Affiliations：
- Author bio：
  
  gghli0120@mail.sitp.ac.cn
- Funds：
- DOI：10.1038/s41377-024-01703-y
  CLC：
- Received：30 May 2024，
  
  Revised：09 October 2024，
  
  Accepted：2024-11-05，
  
  Published Online：14 January 2025，
- Accepted：
Scan QR Code
Xin Li, Jie Wang, Feilong Yu, et al. Nonlinear memristive computational spectrometer[J]. Light: science & applications, 2025, 14(1).
DOI：

Xin Li, Jie Wang, Feilong Yu, et al. Nonlinear memristive computational spectrometer[J]. Light: science & applications, 2025, 14(1). DOI： 10.1038/s41377-024-01703-y.

摘要

Abstract

In the domain of spectroscopy

miniaturization efforts often face significant challenges

particularly in achieving high spectral resolution and precise construction. Here

we introduce a computational spectrometer powered by a nonlinear photonic memristor with a WSe

homojunction. This approach overcomes traditional limitations

such as constrained Fermi level tunability

persistent dark current

and limited photoresponse dimensionality through dynamic energy band modulation driven by palladium (Pd) ion migration. The critical role of Pd ion migration is thoroughly supported by first-principles calculations

numerical simulations

and experimental verification

demonstrating its effectiveness in enhancing device performance. Additionally

we integrate this dynamic modulation with a specialized nonlinear neural network tailored to address the memristor’s inherent nonlinear photoresponse. This combination enables our spectrometer to achieve an exceptional peak wavelength accuracy of 0.18 nm and a spectral resolution of 2 nm within the 630–640 nm range. This development marks a significant advancement in the creation of compact

high-efficiency spectroscopic instruments and offers a versatile platform for applications across diverse material systems.

关键词

Keywords

references

C.P. Bacon , Y. Mattley , R. Defrece , Miniature spectroscopic instrumentation: applications to biology and chemistry . Rev. Sci. Instrum. 75 , 1 - 16 ( 2004 ). http://doi.org/10.1063/1.1633025 http://doi.org/10.1063/1.1633025

R.F. Wolffenbuttel , State-of-the-art in integrated optical microspectrometers . IEEE Trans. Instrum. Meas. 53 , 197 - 202 ( 2004 ). http://doi.org/10.1109/TIM.2003.821490 http://doi.org/10.1109/TIM.2003.821490

Z.Y. Yang et al. , Miniaturization of optical spectrometers . Science 371 , abe0722 ( 2021 ). http://doi.org/10.1126/science.abe0722 http://doi.org/10.1126/science.abe0722

Ebermann, M. et al. Tunable MEMS Fabry-Pérot filters for infrared microspectrometers: a review. Proceedings of SPIE 9760, MOEMS and Miniaturized Systems XV. San Francisco, California, United States: SPIE, 2016, 97600H.

R.A. Crocombe , Portable spectroscopy . Appl. Spectrosc. 72 , 1701 - 1751 ( 2018 ). http://doi.org/10.1177/0003702818809719 http://doi.org/10.1177/0003702818809719

C.H. Yao et al. , Integrated reconstructive spectrometer with programmable photonic circuits . Nat. Commun. 14 ,( 2023 ). http://doi.org/10.1038/s41467-023-42197-3 http://doi.org/10.1038/s41467-023-42197-3

C.C. Chen , H.G. Gu , S.Y. Liu , Ultra-simplified diffraction-based computational spectrometer . Light Sci. Appl. 13 , 9 ( 2024 ). http://doi.org/10.1038/s41377-023-01355-4 http://doi.org/10.1038/s41377-023-01355-4

M.J. Grotevent et al. , Integrated photodetectors for compact Fourier-transform waveguide spectrometers . Nat. Photonics 17 , 59 - 64 ( 2023 ). http://doi.org/10.1038/s41566-022-01088-7 http://doi.org/10.1038/s41566-022-01088-7

A. Li et al. , Advances in cost-effective integrated spectrometers . Light Sci. Appl. 11 , 174 ( 2022 ). http://doi.org/10.1038/s41377-022-00853-1 http://doi.org/10.1038/s41377-022-00853-1

R.X. Wang et al. , Compact multi-foci metalens spectrometer . Light Sci. Appl. 12 , 103 ( 2023 ). http://doi.org/10.1038/s41377-023-01148-9 http://doi.org/10.1038/s41377-023-01148-9

T.A. Kwa , R.F. Wolffenbuttel , Integrated grating/detector array fabricated in silicon using micromachining techniques . Sens. Actuators A: Phys. 31 , 259 - 266 ( 1992 ). http://doi.org/10.1016/0924-4247(92)80114-I http://doi.org/10.1016/0924-4247(92)80114-I

Z.R. Ji et al. , Spatially dispersive circular photogalvanic effect in a Weyl semimetal . Nat. Mater. 18 , 955 - 962 ( 2019 ). http://doi.org/10.1038/s41563-019-0421-5 http://doi.org/10.1038/s41563-019-0421-5

L. Stern et al. , Chip-scale atomic diffractive optical elements . Nat. Commun. 10 ,( 2019 ). http://doi.org/10.1038/s41467-019-11145-5 http://doi.org/10.1038/s41467-019-11145-5

J.D. Thompson et al. , Strong dispersive coupling of a high-finesse cavity to a micromechanical membrane . Nature 452 , 72 - 75 ( 2008 ). http://doi.org/10.1038/nature06715 http://doi.org/10.1038/nature06715

A. Roy et al. , Non-equilibrium spectral phase transitions in coupled nonlinear optical resonators . Nat. Phys. 19 , 427 - 434 ( 2023 ). http://doi.org/10.1038/s41567-022-01874-8 http://doi.org/10.1038/s41567-022-01874-8

Z. Wang et al. , Single-shot on-chip spectral sensors based on photonic crystal slabs . Nat. Commun. 10 ,( 2019 ). http://doi.org/10.1038/s41467-019-08994-5 http://doi.org/10.1038/s41467-019-08994-5

A. Tittl et al. , Imaging-based molecular barcoding with pixelated dielectric metasurfaces . Science 360 , 1105 - 1109 ( 2018 ). http://doi.org/10.1126/science.aas9768 http://doi.org/10.1126/science.aas9768

D.M. Kita et al. , High-performance and scalable on-chip digital Fourier transform spectroscopy . Nat. Commun. 9 ,( 2018 ). http://doi.org/10.1038/s41467-018-06773-2 http://doi.org/10.1038/s41467-018-06773-2

Z.G. Chen , M. Segev , Highlighting photonics: looking into the next decade . eLight 1 , 2 ( 2021 ). http://doi.org/10.1186/s43593-021-00002-y http://doi.org/10.1186/s43593-021-00002-y

C. Xu et al. , Quasicrystal metasurface for dual functionality of holography and diffraction generation . eLight 4 , 9 ( 2024 ). http://doi.org/10.1186/s43593-024-00065-7 http://doi.org/10.1186/s43593-024-00065-7

M. Manley , Near-infrared spectroscopy and hyperspectral imaging: non-destructive analysis of biological materials . Chem. Soc. Rev. 43 , 8200 - 8214 ( 2014 ). http://doi.org/10.1039/C4CS00062E http://doi.org/10.1039/C4CS00062E

A. Toulouse et al. , 3D-printed miniature spectrometer for the visible range with a 100 × 100 μm 2 footprint . Light.: Adv. Manuf. 2 , 20 - 30 ( 2021 ).

J.Y. Wang et al. , Single-pixel p-graded-n junction spectrometers . Nat. Commun. 15 ,( 2024 ). http://doi.org/10.1038/s41467-024-46066-5 http://doi.org/10.1038/s41467-024-46066-5

E. Ryckeboer et al. , Glucose sensing by waveguide-based absorption spectroscopy on a silicon chip . Biomed. Opt. Express 5 , 1636 - 1648 ( 2014 ). http://doi.org/10.1364/BOE.5.001636 http://doi.org/10.1364/BOE.5.001636

R.S. Cheng et al. , Broadband on-chip single-photon spectrometer . Nat. Commun. 10 ,( 2019 ). http://doi.org/10.1038/s41467-019-12149-x http://doi.org/10.1038/s41467-019-12149-x

Z.Y. Yang et al. , Single-nanowire spectrometers . Science 365 , 1017 - 1020 ( 2019 ). http://doi.org/10.1126/science.aax8814 http://doi.org/10.1126/science.aax8814

G. Wu et al. , Miniaturized spectrometer with intrinsic long-term image memory . Nat. Commun. 15 ,( 2024 ). http://doi.org/10.1038/s41467-024-44884-1 http://doi.org/10.1038/s41467-024-44884-1

S.F. Yuan et al. , A wavelength-scale black phosphorus spectrometer . Nat. Photonics 15 , 601 - 607 ( 2021 ). http://doi.org/10.1038/s41566-021-00787-x http://doi.org/10.1038/s41566-021-00787-x

W.J. Deng et al. , Electrically tunable two-dimensional heterojunctions for miniaturized near-infrared spectrometers . Nat. Commun. 13 ,( 2022 ). http://doi.org/10.1038/s41467-022-32306-z http://doi.org/10.1038/s41467-022-32306-z

S. Lee et al. , Programmable black phosphorus image sensor for broadband optoelectronic edge computing . Nat. Commun. 13 ,( 2022 ). http://doi.org/10.1038/s41467-022-29171-1 http://doi.org/10.1038/s41467-022-29171-1

H. Zhou et al. , MOF/polymer-integrated multi-hotspot mid-infrared nanoantennas for sensitive detection of CO 2 gas . Nano-Micro Lett. 14 ,( 2022 ). http://doi.org/10.1007/s40820-022-00950-1 http://doi.org/10.1007/s40820-022-00950-1

G. Uddin et al. , Broadband miniaturized spectrometers with a van der Waals tunnel diode . Nat. Commun. 15 ,( 2024 ). http://doi.org/10.1038/s41467-024-44702-8 http://doi.org/10.1038/s41467-024-44702-8

H.H. Yoon et al. , Miniaturized spectrometers with a tunable van der Waals junction . Science 378 , 296 - 299 ( 2022 ). http://doi.org/10.1126/science.add8544 http://doi.org/10.1126/science.add8544

J. Bao , M.G. Bawendi , A colloidal quantum dot spectrometer . Nature 523 , 67 - 70 ( 2015 ). http://doi.org/10.1038/nature14576 http://doi.org/10.1038/nature14576

J.J. Meng , J.J. Cadusch , K.B. Crozier , Detector-only spectrometer based on structurally colored silicon nanowires and a reconstruction algorithm . Nano Lett. 20 , 320 - 328 ( 2020 ). http://doi.org/10.1021/acs.nanolett.9b03862 http://doi.org/10.1021/acs.nanolett.9b03862

Z.H. Zhang et al. , All-in-one two-dimensional retinomorphic hardware device for motion detection and recognition . Nat. Nanotechnol. 17 , 27 - 32 ( 2022 ). http://doi.org/10.1038/s41565-021-01003-1 http://doi.org/10.1038/s41565-021-01003-1

J.R. Yu et al. , Bioinspired mechano-pho tonic artificial synapse based on graphene/MoS 2 heterostructure . Sci. Adv. 7 ,( 2021 ). http://doi.org/10.1126/sciadv.abd9117 http://doi.org/10.1126/sciadv.abd9117

S. Seo et al. , Artificial optic-neural synapse for colored and color-mixed pattern recognition . Nat. Commun. 9 ,( 2018 ). http://doi.org/10.1038/s41467-018-07572-5 http://doi.org/10.1038/s41467-018-07572-5

L. Mennel et al. , Ultrafast machine vision with 2D material neural network image sensors . Nature 579 , 62 - 66 ( 2020 ). http://doi.org/10.1038/s41586-020-2038-x http://doi.org/10.1038/s41586-020-2038-x

F. Wang et al. , Fully depleted self-aligned heterosandwiched van der Waals photodetectors . Adv. Mater. 34 ,( 2022 ). http://doi.org/10.1002/adma.202203283 http://doi.org/10.1002/adma.202203283

C.Y. Wang et al. , Gate-tunable van der Waals heterostructure for reconfigurable neural network vision sensor . Sci. Adv. 6 ,( 2020 ). http://doi.org/10.1126/sciadv.aba6173 http://doi.org/10.1126/sciadv.aba6173

X. Fu et al. , Graphene/MoS 2− x O x /graphene photomemristor with tunable non-volatile responsivities for neuromorphic vision processing . Light Sci. Appl. 12 , 39 ( 2023 ). http://doi.org/10.1038/s41377-023-01079-5 http://doi.org/10.1038/s41377-023-01079-5

T.X. Li et al. , Reconfigurable, non-volatile neuromorphic photovoltaics . Nat. Nanotechnol. 18 , 1303 - 1310 ( 2023 ). http://doi.org/10.1038/s41565-023-01446-8 http://doi.org/10.1038/s41565-023-01446-8

H. Zhao et al. , Energy-efficient high-fidelity image reconstruction with memristor arrays for medical diagnosis . Nat. Commun. 14 ,( 2023 ). http://doi.org/10.1038/s41467-023-38021-7 http://doi.org/10.1038/s41467-023-38021-7

X. Tang et al. , Controlling sulfurization of 2D Mo 2 C crystal for Mo 2 C/MoS 2 -based memristor and artificial synapse . npj Flex. Electron. 6 ,( 2022 ). http://doi.org/10.1038/s41528-022-00227-y http://doi.org/10.1038/s41528-022-00227-y

S.M. Hus et al. , Observation of single-defect memristor in an MoS 2 atomic sheet . Nat. Nanotechnol. 16 , 58 - 62 ( 2021 ). http://doi.org/10.1038/s41565-020-00789-w http://doi.org/10.1038/s41565-020-00789-w

J. Lee et al. , Light-enhanced molecular polarity enabling multispectral color-cognitive memristor for neuromorphic visual system . Nat. Commun. 14 ,( 2023 ). http://doi.org/10.1038/s41467-023-41419-y http://doi.org/10.1038/s41467-023-41419-y

H. Wang , S.H. Chen , X.L. Chen , Room-temperature self-powered infrared spectrometer based on a single black phosphorus heterojunction diode . Nano Lett. 24 , 326 - 330 ( 2024 ). http://doi.org/10.1021/acs.nanolett.3c04044 http://doi.org/10.1021/acs.nanolett.3c04044

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

No data

Related Author

No data

Related Institution

No data

⁰