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1.School of Physical Science and Technology, State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China
2.Hubei Key Laboratory of Energy Storage and Power Battery, School of Optoelectronic Engineering, School of New Energy, Hubei University of Automotive Technology, Shiyan 442002, China
3.Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Institute of Materials and Clean Energy, Shandong Normal University, Jinan 250014, China
4.School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China
Sheng Cao (caosheng@gxu.edu.cn)
Jialong Zhao (zhaojl@gxu.edu.cn)
Bingsuo Zou (zoubs@gxu.edu.cn)
Received:12 May 2025,
Revised:2025-08-17,
Accepted:18 August 2025,
Published Online:22 September 2025,
Published:30 November 2025
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Song, Y. S. et al. Efficient deep-blue LEDs based on colloidal CsPbBr3 nanoplatelets meeting the Rec.2020 standard. Light: Science & Applications, 14, 3602-3611 (2025).
Song, Y. S. et al. Efficient deep-blue LEDs based on colloidal CsPbBr3 nanoplatelets meeting the Rec.2020 standard. Light: Science & Applications, 14, 3602-3611 (2025). DOI: 10.1038/s41377-025-02019-1.
Colloidally quantum-confined CsPbBr
3
nanoplatelets (NPLs) exhibit narrow emission linewidths and thickness-tunable photoluminescence
making them ideal candidates for deep-blue perovskite light-emitting diodes (PeLEDs). However
the weak surface coordination of conventional long-chain ligands (
e.g
.
oleylamine and oleic acid) leads to face-to-face stacking of the NPLs
resulting in undesirable emission redshifts in their PeLEDs. Herein
we report an efficient deep-blue PeLED based on colloidal CsPbBr
3
NPLs that meet the Rec.2020 color standard
enabled by an acid-assisted ligand passivation strategy. Surface chemical analysis reveals that hydrobromic acid facilitates proton-assisted stripping of the long-chain ligands
followed by the formation of stable Pb-S-P coordination bonds with thio-tributylphosphine
which exhibits a high adsorption energy (E
ads
= -1.13 eV). This approach significantly improves surface defect passivation
yielding a photoluminescence quantum yield of 96% and a narrow 13 nm full-width-at-half-maximum deep-blue emission. Enhanced exciton recombination and reduced defect state density are evidenced by a prolonged photoluminescence lifetime and slower absorption bleach recovery kinetics. The resulting PeLEDs achieve rec
ord-breaking performance among CsPbBr
3
NPL-based systems
with a maximum external quantum efficiency of 6.81% at 461 nm
a peak luminance of 143 cd m
-2
and the CIE color coordinates (CIE-y = 0.046) that comply with Rec.2020 standards. This work presents an effective strategy for developing efficient and stable deep-blue perovskite emitters
demonstrating significant potential for the commercialization of perovskite nanomaterials in next-generation ultra-high-definition displays.
Liu, X. K. et al. Metal halide perovskites for light-emitting diodes. Nat. Mater. 20 , 10–21 (2021)..
Zhang, D. Q. et al. Large-scale planar and spherical light-emitting diodes based on arrays of perovskite quantum wires. Nat. Photonics 16 , 284–290 (2022)..
Lv, X. Y. et al. TOP-Zn steric hindrance effect enables ultra-uniform CsPbX 3 quantum dots for wide-color gamut displays. Adv. Mater. 37 , 2409308 (2025)..
Kong, L. M. et al. Fabrication of red-emitting perovskite LEDs by stabilizing their octahedral structur e. Nature 631 , 73–79 (2024)..
Lin, K. B. et al. Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent. Nature 562 , 245–248 (2018)..
Cao, Y. B. et al. High-efficiency, flexible and large-area red/green/blue all-inorganic metal halide perovskite quantum wires-based light-emitting diodes. Nat. Commun. 14 , 4611 (2023)..
Soneira, R. M. Display color gamuts: NTSC to Rec. 2020. Inf. Disp. 32 , 26–31 (2016)..
Karlsson, M. et al. Mixed halide perovskites for spectrally stable and high-efficiency blue light-emitting diodes. Nat. Commun. 12 , 361 (2021)..
Yuan, S. et al. Efficient blue electroluminescence from reduced-dimensional perovskites. Nat. Photonics 18 , 425–431 (2024)..
Zheng, X. P. et al. Chlorine vacancy passivation in mixed halide perovskite quantum dots by organic pseudohalides enables efficient Rec. 2020 blue light-emitting diodes. ACS Energy Lett. 5 , 793–798 (2020)..
Gao, L. et al. High efficiency pure blue perovskite quantum dot light-emitting diodes based on formamidinium manipulating carrier dynamics and electron state filling. Light Sci. Appl. 11 , 346 (2022)..
Yuan, S. et al. Efficient and spectrally stable blue perovskite light-emitting diodes employing a cationic π-conjugated polymer. Adv. Mater. 33 , 2103640 (2021)..
Li, Z. C. et al. Modulation of recombination zone position for quasi-two-dimensional blue perovskite light-emitting diodes with efficiency exceeding 5. Nat. Commun. 10 , 1027 (2019)..
Liu, A. Q. et al. Optimizing perovskite surfaces to enhance post-treatment for efficient blue mixed-halide perovskite light-emitting diodes. Adv. Mater. 37 , 2414788 (2025)..
Ren, Z. W. et al. High-performance blue perovskite light-emitting diodes enabled by efficient energy transfer between coupled quasi-2D perovskite layers. Adv. Mater. 33 , 2005570 (2021)..
Lee, J. W. & Park, N. G. Quasi-two-dimensional perovskite light emitting diodes for bright future. Light Sci. Appl. 10 , 86 (2021)..
Liu, S. C. et al. Zwitterions narrow distribution of perovskite quantum wells for blue light-emitting diodes with efficiency exceeding 15%. Adv. Mater. 35 , 2208078 (2023)..
Xing, J. et al. Color-stable highly luminescent sky-blue perovskite light-emitting diodes. Nat. Commun. 9 , 3541 (2018)..
Alahbakhshi, M. et al. Highly efficient quasi 2D blue perovskite electroluminescence leveraging a dual ligand composition. Adv. Funct. Mater. 33 , 2214315 (2023)..
Qi, H. et al. Homogenizing energy landscape for efficient and spectrally stable blue perovskite light-emitting diodes. Adv. Mater. 36 , 2409319 (2024)..
Chu, Z. M. & You, J. B. Blue light-emitting diodes based on pure bromide perovskites. Adv. Mater. 37 , 2409867 (2025)..
Otero-Martínez, C. et al. Colloidal metal-halide perovskite nanoplatelets: thickness-controlled synthesis, properties, and application in light-emitting diodes. Adv. Mater. 34 , 2107105 (2022)..
Jang, K. Y. et al. Efficient deep-blue light-emitting diodes through decoupling of colloidal perovskite quantum dots. Adv. Mater. 36 , 2404856 (2024)..
Liu, H. et al. Organic semiconducting ligands passivated CsPbBr 3 nanoplatelets for blue light-emitting diodes. ACS Energy Lett. 8 , 4259–4266 (2023)..
Wang, L. et al. Efficient, color-stable, pure-blue light-emitting diodes based on aromatic ligand-engineered perovskite nanoplatelets. Nano Lett. 24 , 7004–7011 (2024)..
Lin, H. et al. Bi-functional chelating ligand enables ultra-stable blue emissive CsPbBr 3 nanoplatelets film. Adv. Optical Mater. 12 , 2400214 (2024)..
Liang, J. Y. et al. Highly stable deep-blue emitting CsPbBr 3 nanoplatelets with modified zwitterionic surface passivation. Chem. Eng. J. 495 , 153337 (2024)..
Shamsi, J. et al. Stable hexylphosphonate-capped blue-emitting quantum-confined CsPbBr 3 nanoplatelets. ACS Energy Lett. 5 , 1900–1907 (2020)..
Huang, Q. Q. et al. Enh ancing crystal integrity and structural rigidity of CsPbBr 3 nanoplatelets to achieve a narrow color-saturated blue emission. Light Sci. Appl. 13 , 111 (2024)..
Liu, H. et al. Efficient and stable blue light emitting diodes based on CsPbBr 3 nanoplatelets with surface passivation by a multifunctional organic sulfate. Adv. Energy Mater. 13 , 2201605 (2022)..
Song, Y. S. et al. Decyl disulfide surface treatment improved photoluminescence quantum yield and stability of blue-emitting CsPbBr 3 nanoplatelets. Mater. Res. Bull. 164 , 112257 (2023)..
Su, S. J. et al. Stable and highly efficient blue-emitting CsPbBr 3 perovskite nanomaterials via kinetic-controlled growth. Chem. Eng. J. 419 , 129612 (2021)..
Yin, W. K. et al. Multidentate ligand polyethylenimine enables bright color-saturated blue light-emitting diodes based on CsPbBr 3 nanoplatelets. ACS Energy Lett. 6 , 477–484 (2021)..
Wang, Y. K. et al. Long-range order enabled stability in quantum dot light-emitting diodes. Nature 629 , 586–591 (2024)..
Bi, C. H. et al. Perovskite quantum dots with ultralow trap density by acid etching-driven ligand exchange for high luminance and stable pure-blue light-emitting diodes. Adv. Mater. 33 , 2006722 (2021)..
Krieg, F. et al. Colloidal CsPbX 3 (X = Cl, Br, I) nanocrystals 2.0: zwitterionic capping ligands for improved durability and stability. ACS Energy Lett. 3 , 641–646 (2018)..
Dang, Z. Y. et al. Temperature-driven transformation of CsPbBr 3 nanoplatelets into mosaic nanotiles in solution through self-assembly. Nano Lett. 20 , 1808–1818 (2020)..
Pan, A.Z. et al. Insight into the ligand-mediated synthesis of colloidal CsPbBr 3 perovskite nanocrystals: the role of organic acid, base, and cesium precursors. ACS Nano 10 , 7943–7954 (2016)..
Yin, W. X. et al. Overcoming the ambient manufacturability-performance bottleneck in perovskite nanocrystal emitters for efficient light-emitting diodes. Angew. Chem. Int. Ed. 62 , e202303462 (2023)..
Liu, Z. K. et al. Ligand mediated transformation of cesium lead bromide perovskite nanocrystals to lead depleted Cs 4 PbBr 6 nanocry stals. J. Am. Chem. Soc. 139 , 5309–5312 (2017)..
Wu, W. B. et al. Photo-induced thiol coupling and C–H activation using nanocrystalline lead-halide perovskite catalysts. Catal. Sci. Technol. 8 , 4257–4263 (2018)..
Wu, Y. et al. In situ passivation of PbBr 6 4– octahedra toward blue luminescent CsPbBr 3 nanoplatelets with near 100% absolute quantum yield. ACS Energy Lett. 3 , 2030–2037 (2018)..
Zhang, W. et al. Ultrasmooth organic-inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells. Nat. Commun. 6 , 6142 (2015)..
Jiang, Y. Z. et al. Synthesis-on-substrate of quantum dot solids. Nature 612 , 679–684 (2022)..
Price, M. B. et al. Hot-carrier cooling and photoinduced refractive index changes in organic–inorganic lead halide perovskites. Nat. Commun. 6 , 8420 (2015)..
Ding, P. B. et al. Strongly confined and spectrally tunable CsPbBr 3 quantum dots for deep blue QD-LEDs. Adv. Optical Mater. 12 , 2302477 (2024)..
Lee, S. et al. Brightening deep-blue perovskite light-emitting diodes: a path to Rec. 2020. Sci. Adv. 10 , eadn8465 (2024)..
Zou, G. R. X. et al. Color-stable deep-blue perovskite light-emitting diodes based on organotrichlorosilane post-treatment. Adv. Funct. Mater. 31 , 2103219 (2021)..
Guo, Y. Y. et al. Lattice stabilized and emission tunable pure-bromide quasi-2D perovskite for air-processed blue light-emitting diodes. Adv. Sci. 12 , 2414499 (2025)..
Dong, J. C. et al. Deep-blue electroluminescence of perovskites with reduced dimensionality achieved by manipulating adsorption-energy differences. Angew. Chem. Int. Ed. 61 , e202210322 (2022)..
Dong, J. C. et al. Multivalent-effect immobilization of reduced-dimensional perovskites for efficient and spectrally stable deep-blue light-emitting diodes. Nat. Nanotechnol. 20 , 507–514 (2025)..
Wei, K. Y. et al. Managing edge states in reduced-dimensional perovskites for highly efficient deep-blue LEDs. Adv. Mater. 37 , 2412041 (20 25)..
Li, J. Q. et al. Efficient deep-blue (465 nm) perovskite quantum dot-based light-emitting diodes via triphenylamine derivative tailored hole transport engineering. Adv. Funct. Mater. 35 , 2412367 (2025)..
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