Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy

Quan Sun; Kosei Ueno; Han Yu; Atsushi Kubo; Yasutaka Matsuo; Hiroaki Misawa

doi:10.1038/lsa.2013.74

Go to Nature Website

Your Location：

Home >

Browse articles >

Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy

Original Articles

- Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy
- Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy
- LSA 2013年2卷第3-4期
- Affiliations：
  
  1.Research Institute for Electronic Science, Hokkaido University, Sapporo 001-0021, Japan
  2.Creative Research Institution, Hokkaido University, Sapporo 001-0021, Japan
  3.PRESTO, Japan Science and Technology Agency, Kawaguchi 332-0012, Japan
  4.Institute of Physics, University of Tsukuba, Tsukuba 305-8571, Japan
- Author bio：
  
  Professor H Misawa, Research Institute for Electronic Science, Hokkaido University, Sapporo 001-0021, Japan E-mail: misawa@es.hokudai.ac.jp
- Funds：
- DOI：10.1038/lsa.2013.74
  中图分类号：
- 纸质出版日期：2013-12，
  
  网络出版日期：2013-12-20，
  
  收稿日期：2013-03-11，
  
  修回日期：2013-06-12，
  
  录用日期：2013-08-16
- Accepted：
Scan QR Code
Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy[J]. LSA, 2013,2(3-4).

Sun, Q. et al. Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy. Light: Science & Applications, 2, e118 (2013).
Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy[J]. LSA, 2013,2(3-4). DOI： 10.1038/lsa.2013.74.

Sun, Q. et al. Direct imaging of the near field and dynamics of surface plasmon resonance on gold nanostructures using photoemission electron microscopy. Light: Science & Applications, 2, e118 (2013). DOI： 10.1038/lsa.2013.74.

摘要

Abstract

Localized surface plasmon resonance (LSPR) can be supported by metallic nanoparticles and engineered nanostructures. An understanding of the spatially resolved near-field properties and dynamics of LSPR is important

but remains experimentally challenging. We report experimental studies toward this aim using photoemission electron microscopy (PEEM) with high spatial resolution of sub-10 nm. Various engineered gold nanostructure arrays (such as rods

nanodisk-like particles and dimers) are investigated

via

PEEM using near-infrared (NIR) femtosecond laser pulses as the excitation source. When the LSPR wavelengths overlap the spectrum of the femtosecond pulses

the LSPR is efficiently excited and promotes multiphoton photoemission

which is correlated with the local intensity of the metallic nanoparticles in the near field. Thus

the local field distribution of the LSPR on different Au nanostructures can be directly explored and discussed using the PEEM images. In addition

the dynamics of the LSPR is studied by combining interferometric time-resolved pump-probe technique and PEEM. Detailed information on the oscillation and dephasing of the LSPR field can be obtained. The results identify PEEM as a powerful

tool for accessing the near-field mapping and dynamic properties of plasmonic nanostructures.

关键词

Keywords

femtosecond laserlocal field enhancementnear-field imagingphotoemission electron microscopysurface plasmon resonance

references

Jain PK, Huang XH, El-Sayed IH, El-Sayed MA. Noble metals on the nanoscale: optical and photothermal properties and some applications in imaging, sensing, biology, and medicine.Accounts Chem Res2008;41: 1578–1586..

Giannini V, Fernandez-Dominguez AI, Sonnefraud Y, Roschuk T, Fernandez-Garcia Ret al. Controlling light localization and light–matter interactions with nanoplasmonics.Small2010;6: 2498–2507..

Schuller JA, Barnard ES, Cai WS, Jun YC, White JSet al. Plasmonics for extreme light concentration and manipulation.Nat Mater2010;9: 193–204..

Watanabe K, Menzel D, Nilius N, Freund HJ. Photochemistry on metal nanoparticles.Chem Rev2006;106: 4301–4320..

Chen C, Hutchison JA, Clemente F, Kox R, Uji-I Het al. Direct evidence of high spatial localization of hot spots in surface-enhanced Raman scattering.Angew Chem Int Ed2009;48: 9932–9935..

Yokota Y, Ueno K, Misawa H. Highly controlled surface-enhanced raman scattering chips using nanoengineered gold blocks.Small2011;7: 252–258..

Alvarez-Puebla RA, Agarwal A, Manna P, Khanal BP, Aldeanueva-Potel Pet al. Gold nanorods 3D-supercrystals as surface enhanced Raman scattering spectroscopy substrates for the rapid detection of scrambled prions.Proc Natl Acad Sci USA2011;108: 8157–8161..

Hutchison JA, Centeno SP, Odaka H, Fukumura H, Hofkens Jet al. Subdiffraction limited, remote excitation of surface enhanced Raman scattering.Nano Lett2009;9: 995–1001..

Nusz GJ, Curry AC, Marinakos SM, Wax A, Chilkoti A. Rational selection of gold nanorod geometry for label-free plasmonic biosensors.ACS Nano2009;3: 795–806..

Lee KL, Chih MJ, Shi X, Ueno K, Misawa Het al. Improving surface plasmon detection in gold nanostructures using a multi-polarization spectral integration method.Adv Mater2012;24: 253–259..

Wu BT, Ueno K, Yokota Y, Sun K, Zeng HPet al. Enhancement of a two-photon-induced reaction in solution using light-harvesting gold nanodimer structures.J Phys Chem Lett2012;3: 1443–1447..

Tsuboi Y, Shimizu R, Shoji T, Kitamura N. Near-infrared continuous-wave light driving a two-photon photochromic reaction with the assistance of localized surface plasmon.J Am Chem Soc2009;131: 12623–12627..

Nishijima Y, Ueno K, Yokota Y, Murakoshi K, Misawa H. Plasmon-assisted photocurrent generation from visible to near-infrared wavelength using a Au-nanorods/TiO2electrode.J Phys Chem Lett2010;1: 2031–2036..

Sugawa K, Akiyama T, Kawazumi H, Yamada S. Plasmon-enhanced photocurrent generation from self-assembled monolayers of phthalocyanine by using gold nanoparticle films.Langmuir2009;25: 3887–3893..

Su YH, Ke YF, Cai SL, Yao QY. Surface plasmon resonance of layer-by-layer gold nanoparticles induced photoelectric current in environmentally-friendly plasmon-sensitized solar cell.Light Sci Appl2012;1: e14..

Grubisic A, Ringe E, Cobley CM, Xia YN, Marks LDet al. Plasmonic near-electric field enhancement effects in ultrafast photoelectron emission: correlated spatial and laser polarization microscopy studies of individual Ag nanocubes.Nano Lett2012;12: 4823–4829..

Schweikhard V, Grubisic A, Baker TA, Thomann I, Nesbitt DJ. Polarization-dependent scanning photoionization microscopy: ultrafast plasmon-mediated electron ejection dynamics in single Au nanorods.ACS Nano2011;5: 3724–3735..

Imura K, Nagahara T, Okamoto H. Near-field optical imaging of plasmon modes in gold nanorods.J Chem Phys2005;122: 154701..

Imura K, Ueno K, Misawa H, Okamoto H. Anomalous light transmission from plasmonic-capped nanoapertures.Nano Lett2011;11: 960–965..

Rang M, Jones AC, Zhou F, Li ZY, Wiley BJet al. Optical near-field mapping of plasmonic nanoprisms.Nano Lett2008;8: 3357–3363..

Tanaka Y, Ishiguro H, Fujiwara H, Yokota Y, Ueno Ket al. Direct imaging of nanogap-mode plasmon-resonant fields.Opt Express2011;19: 7726–7733..

Ueno K, Juodkazis S, Mizeikis V, Sasaki K, Misawa H. Clusters of closely spaced gold nanoparticles as a source of two-photon photoluminescence at visible wavelengths.Adv Mater2008;20: 26–30..

Imura K, Okamoto H, Hossain MK, Kitajima M. Visualization of localized intense optical fields in single gold-nanoparticle assemblies and ultrasensitive Raman active sites.Nano Lett2006;6: 2173–2176..

Geldhauser T, Kolloch A, Murazawa N, Ueno K, Boneberg Jet al. Quantitative measurement of the near-field enhancement of nanostructures by two-photon polymerization.Langmuir2012;28: 9041–9046..

Ueno K, Juodkazis S, Shibuya T, Yokota Y, Mizeikis Vet al. Nanoparticle plasmon-assisted two-photon polymerization induced by incoherent excitation source.J Am Chem Soc2008;130: 6928–6929..

Leiderer P, Bartels C, Konig-Birk J, Mosbacher M, Boneberg J. Imaging optical near-fields of nanostructures.Appl Phys Lett2004;85: 5370–5372..

Nedyalkov NN, Takada H, Obara M. Nanostructuring of silicon surface by femtosecond laser pulse mediated with enhanced near-field of gold nanoparticles.Appl Phys A2006;85: 163–168..

Eversole D, Luk'yanchuk B, Ben-Yakar A. Plasmonic laser nanoablation of silicon by the scattering of femtosecond pulses near gold nanospheres.Appl Phys A2007;89: 283–291..

Kolloch A, Geldhauser T, Ueno K, Misawa H, Boneberg Jet al. Femtosecond and picosecond near-field ablation of gold nanotriangles: nanostructuring and nanomelting.Appl Phys A2011;104: 793–799..

Cinchetti M, Gloskovskii A, Nepjiko SA, Schonhense G, Rochholz Het al. Photoemission electron microscopy as a tool for the investigation of optical near fields.Phys Rev Lett2005;95: 047601..

Heringdorf FM, Chelaru LI, Mollenbeck S, Thien D, Hoegen MH. Femtosecond photoemission microscopy.Surf Sci2007;601: 4700–4705..

Kubo A, Onda K, Petek H, Sun ZJ, Jung YSet al. Femtosecond imaging of surface plasmon dynamics in a nanostructured silver film.Nano Lett2005;5: 1123–1127..

Melchior P, Bayer D, Schneider C, Fischer A, Rohmer Met al. Optical near-field interference in the excitation of a bowtie nanoantenna.Phys Rev B2011;83: 235407..

Schertz F, Schmelzeisen M, Mohammadi R, Kreiter M, Elmers HJet al. Near field of strongly coupled plasmons: uncovering dark modes.Nano Lett2012;12: 1885–1890..

Aeschlimann M, Brixner T, Fischer A, Kramer C, Melchior Pet al. Coherent two-dimensional nanoscopy.Science2011;333: 1723–1726..

Bauer E, Mundschau M, Swiech W, Telieps W. Surface studies by low-energy electron-microscopy (LEEM) and conventional UV photoemission electron-microscopy (PEEM).Ultramicroscopy1989;31: 49–57..

Vogel J, Kuch W, Bonfim M, Camarero J, Pennec Yet al. Time-resolved magnetic domain imaging by X-ray photoemission electron microscopy.Appl Phys Lett2003;82: 2299–2301..

Kubo A, Pontius N, Petek H. Femtosecond microscopy of surface plasmon polariton wave packet evolution at the silver/vacuum interface.Nano Lett2007;7: 470–475..

Zhang LX, Kubo A, Wang LM, Petek H, Seideman T. Imaging of surface plasmon polariton fields excited at a nanometer-scale slit.Phys Rev B2011;84: 245442..

Michaelson HB. Work function of elements and its periodicity.J Appl Phys1977;48: 4729–4733..

Schierbaum KD, Fischer S, Torquemada MC, deSegovia JL, Roman Eet al. The interaction of Pt with TiO2(110) surfaces: a comparative XPS, UPS, ISS, and ESD study.Surf Sci1996;345: 261–273..

Schneider CM, Schonhense G. Investigating surface magnetism by means of photoexcitation electron emission microscopy.Rep Prog Phys2002;65: R1785–R1839..

Buckanie NM, Gohre J, Zhou P, von der Linde D, Horn-von Hoegen Met al. Space charge effects in photoemission electron microscopy using amplified femtosecond laser pulses.J Phys Condens Matter2009;21: 314003..

Johnson PB, Christy RW. Optical constants of noble metals.Phys Rev B1972;6: 4370–4379..

Schertz F, Schmelzeisen M, Kreiter M, Elmers HJ, Schonhense G. Field emission of electrons generated by the near field of strongly coupled plasmons.Phys Rev Lett2012;108: 237602..

Bormann R, Gulde M, Weismann A, Yalunin SV, Ropers C. Tip-enhanced strong-field photoemission.Phys Rev Lett2010;105: 147601..

Kruger M, Schenk M, Forster M, Hommelhoff P. Attosecond physics in photoemission from a metal nanotip.J Phys B At Mol Opt2012;45: 074006..

Ward DR, Huser F, Pauly F, Cuevas JC, Natelson D. Optical rectification and field enhancement in a plasmonic nanogap.Nat Nanotechnol2010;5: 732–736..

Hao E, Schatz GC. Electromagnetic fields around silver nanoparticles and dimers.J Chem Phys2004;120: 357–366..

Acimovic SS, Kreuzer MP, Gonzalez MU, Quidant R. Plasmon near-field coupling in metal dimers as a step toward single-molecule sensing.ACS Nano2009;3: 1231–1237..

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Electrons dynamics control by shaping femtosecond laser pulses in micro/nanofabrication: modeling, method, measurement and application

Direct visualization of the complete evolution of femtosecond laser-induced surface structural dynamics of metals

Energy transfer in plasmonic photocatalytic composites

High-aspect 3D two-photon polymerization structuring with widened objective working range (WOW-2PP)

Conic hyperspectral dispersion mapping applied to semiconductor plasmonics