Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors

Byoungchoo Park; Soo Hong Yun; Chan Youn Cho; Young Chan Kim; Jung Chul Shin; Hong Goo Jeon; Yoon Ho Huh; Inchan Hwang; Ku Youn Baik; Young In Lee; Han Sup Uhm; Guang Sup Cho; Eun Ha Choi

doi:10.1038/lsa.2014.103

Go to Nature Website

Your Location：

Home >

Browse articles >

Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors

Original Articles

- Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors
- Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors
- LSA 2014年3卷第4期
- Affiliations：
  
  1.Department of Electrical and Biological Physics, Kwangwoon University, Seoul 139-701, Republic of Korea
  2.Department of Electronic Materials Engineering, Kwangwoon University, Seoul 139-701, Rep
- Author bio：
  
  Professor B Park, Department of Electrical and Biological Physics, Kwangwoon University, Wolgye-Dong, Nowon-gu, Seoul 139-701, Republic of Korea Email: bcpark@kw.ac.kr
- Funds：
- DOI：10.1038/lsa.2014.103
  中图分类号：
- 纸质出版日期：2014-12，
  
  网络出版日期：2014-12-05，
  
  收稿日期：2014-03-26，
  
  修回日期：2014-09-13，
  
  录用日期：2014-09-15
- Accepted：
Scan QR Code
Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors[J]. LSA, 2014,3(4).

Park, B. et al. Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors. Light: Science & Applications, 3, e222 (2014).
Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors[J]. LSA, 2014,3(4). DOI： 10.1038/lsa.2014.103.

Park, B. et al. Surface plasmon excitation in semitransparent inverted polymer photovoltaic devices and their applications as label-free optical sensors. Light: Science & Applications, 3, e222 (2014). DOI： 10.1038/lsa.2014.103.

摘要

Abstract

Herein

we report on surface plasmon (SP)-sensitive semitransparent inverted polymer photovoltaic (PV) devices that are based on multilayered material systems consisting of poly(3-hexylthiophene): fullerene-derivative bulk-heterojunction PV layers and thin gold or silver a

nodes. We demonstrate that these PV devices allow the simultaneous generation of both electrical power and SPs on their anodes for photoexcitation just above the optical absorption edge of the PV layers

resulting not only in attenuated total reflection

but also in attenuated photocurrent generation (APG) under the SP resonance (SPR) condition. Moreover

we also confirm that the biomolecular interaction of biotin–streptavidin on the PV devices can be precisely detected

via

apparent SPR angle shifts in the APG spectra

even without the need for complex attenuated total reflection configurations. We highlight our view that APG measurements made using these PV devices show great potential for the development of future generations of compact and highly sensitive SPR-based optical sensors.

关键词

Keywords

attenuated total reflectionoptical sensorsphotocurrent generationpolymer photovoltaic devicessurface plasmon

references

Ritchie RH. Plasma losses by fast electrons in thin films.Phys Rev1957;106: 874–881..

Ritchie RH, Arakawa ET, Cowan JJ, Hamm RN. Surface-plasmon resonance effect in grating diffraction.Phys Rev Lett1968;21: 1530–1533..

Otto A. Excitation of nonradiative surface plasma waves in silver by the method of frustrated total reflection.Z Phys1968;216: 398–410..

Kretschmann E. Die bestimmung optischer konstanten von metallen durch anregung von oberflächenplasmaschwingungen.Z Phys1971;241: 313–324..

Raether H.Excitation of Plasmons and Interband Transitions by Electrons. Berlin: Springer; 1980.

Knoll W. Interfaces and thin films as seen by bound electromagnetic waves.Annu Rev Phys Chem1998;49: 569–638..

Polman A. Plasmonics applied.Science2008;322: 868–869..

Lindquist NC, Nagpal P, McPeak KM, Norris DJ, Oh SH. Engineering metallic nanostructures for plasmonics and nanophotonics.Rep Prog Phys2012;75: 036501..

Fang Z, Zhu X. Plasmonics in nanostructures.Adv Mater2013;25: 3840–3856..

Otte MA, Sepúlveda B, Ni W, Juste JP, Liz-Marzán LMet al. Identification of the optimal spectral region for plasmonic and nanoplasmonic sensing.ACS Nano2010;4: 349–357..

Brolo AG. Plasmonics for future biosensors.Nat Photon2012;6: 709–713..

Stuart HR, Hall DG. Absorption enhancement in silicon-on-insulator waveguides using metal island films.Appl Phys Lett1996;69: 2327–2329..

Schaadt DM, Feng B, Yu ET. Enhanced semiconductor optical absorptionviasurface plasmon excitation in metal nanoparticles.Appl Phys Lett2005;86: 063106..

Su YH, Ke YF, Cai SL, Yao QY. Surface plasmon resonance of layer-by-layer gold nanoparticles induced photoelectric current in environmentally-friendly plasmon-sensitized solar cell.Light Sci Appl2012;1: e14; doi: 10.1038/lsa.2012.14..

Polman A, Atwater HA. Photonic design principles for ultrahigh-efficiency photovoltaics.Nat Mater2012;11: 174–177..

Hayashi S, Kozaru K, Yamamoto K. Enhancement of photoelectric conversion efficiency by surface plasmon excitation: a test with an organic solar cell.Solid State Commun1991;79: 763–767..

Westphalen M, Kreibig U, Rostalski J, Lüth H, Meissner D. Metal cluster enhanced organic solar cells.Sol Energy Mater Sol Cells2000;61: 97–105..

Kato K, Tsuruta H, Ebe T, Shinbo K, Kaneko Fet al. Enhancement of optical absorption and photocurrents in solar cells of merocyanine Langmuir–Blodgett films utilizing surface plasmon excitations.Mater Sci Eng C2002;22: 251–256..

Yamagishi K, Inoue J, Yamashita M. Surface plasmon resonance in organic photovoltaic cells with silver or gold electrodes.Mol Cryst Liq Cryst2006;462: 83–90..

Mapel JK, Singh M, Baldo MA, Celebi K. Plasmonic excitation of organic double heterostructure solar cells.Appl Phys Lett2007;90: 121102..

Sariciftci NS, Smilowitz L, Heeger AJ, Wudl F. Photoinduced electron transfer from a conducting polymer to buckminsterfullerene.Science1992;258: 1474–1476..

Yu G, Gao J, Hummelen JC, Wudl F, Heeger AJ. Polymer photovoltaic cells: enhanced efficienciesviaa network of internal donor-acceptor heterojunctions.Science1995;270: 1789–1791..

Liang Y, Xu Z, Xia J, Tsai ST, Wu Yet al. For the bright future—bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%.Adv Mater2010;22: E135–E138..

You J, Dou L, Yoshimura K, Kato T, Ohya Ket al. A polymer tandem solar cell with 10.6% power conversion efficiency.Nat Commun2013;4: 1446..

Dennler G, Forberich K, Scharber MC, Brabec CJ, Tomiš Iet al. Angle dependence of external and internal quantum efficiencies in bulk-heterojunction organic solar cells.J Appl Phys2007;102: 054516..

Şahin Y, Alem S, de Bettignies R, Nunzi JM. Development of air stable polymer solar cells using an inverted gold on top anode structure.Thin Solid Films2005;476: 340–343..

Li G, Chu CW, Shrotriya V, Huang J, Yang Y. Efficient inverted polymer solar cells.Appl Phys Lett2006;88: 253503..

Small CE, Chen S, Subbiah J, Amb CM, Tsang SWet al. High-efficiency inverted dithienogermole–thienopyrrolodione-based polymer solar cells.Nat Photon2012;6: 115–120..

He Z, Zhong C, Su S, Xu M, Wu Het al. Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure.Nat Photon2012;6: 591–595..

Park B, Shin JC, Cho CY. Water-processable electron-collecting layers of a hybrid poly(ethylene oxide): caesium carbonate composite for flexible inverted polymer solar cells.Sol Energy Mater Sol Cells2013;108: 1–8..

Tao C, Ruan S, Zhang X, Xie G, Shen Let al. Performance improvement of inverted polymer solar cells with different top electrodes by introducing a MoO3 buffer layer.Appl Phys Lett2008;93: 193307..

Tvingstedt K, Persson NK, Inganäs O, Rahachou A, Zozoulenko IV. Surface plasmon increase absorption in polymer photovoltaic cells.Appl Phys Lett2007;91: 113514..

Chang YC, Chou FY, Yeh PH, Chen HW, Chang SHet al. Effects of surface plasmon resonant scattering on the power conversion efficiency of organic thin-film solar cells.J Vac Sci Technol B2007;25: 1899–1902..

Gan Q, Bartoli FJ, Kafafi ZH. Plasmonic-enhanced organic photovoltaics: breaking the 10% efficiency barrier.Adv Mater2013;25: 2385–2396..

Stratakis E, Kymakis E. Nanoparticle-based plasmonic organic photovoltaic devices.Mater Today2013;16: 133–146..

Kao CS, Chen FC, Liao CW, Huang MH, Hsu CS. Plasmonic-enhanced performance for polymer solar cells prepared with inverted structures.Appl Phys Lett2012;101: 193902..

Li X, Choy WC, Huo L, Xie F, Sha WEet al. Dual plasmonic nanostructures for high performance inverted organic solar cells.Adv Mater2012;24: 3046–3052..

Xu P, Shen L, Meng F, Zhang J, Xie Wet al. The role of Ag nanoparticles in inverted polymer solar cells: surface plasmon resonance and backscattering centers.Appl Phys Lett2013;102: 123301..

Yee KS. Numerical solutions of initial boundary value problems involving maxwell's equations in isotropic media.IEEE Trans Antenn Propag1966;14: 302–307..

FDTD Solutions. Vancouver: Lumerical Solutions Inc.

Woollam JA, Johs BD, Herzinger CM, Hilfiker JN, Synowicki RAet al. Overview of variable-angle spectroscopic ellipsometry (VASE): Ⅰ. Basic theory and typical applications.Proc SPIE1999;CR72: 3–28..

Johs BD, Woollam JA, Herzinger CM, Hilfiker JN, Synowicki RA et al. Overview of variable-angle spectroscopic ellipsometry (VASE): Ⅱ. Advanced applications.Proc SPIE1999;CR72: 29–58..

Bull HB. Adsorption of bovine serum albumin on glass.Biochim Biophys Acta1956;19: 464–471..

Riboh JC, Haes AJ, McFarland AD, Yonzon CR, Van Duyne RP. A nanoscale optical biosensor: real-time immunoassay in physiological buffer enabled by improved nanoparticle adhesion.J Phys Chem B2003;107: 1772–1780..

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Plasmon-assisted optical trapping and anti-trapping

Coupling of plasmonic nanopore pairs: facing dipoles attract each other

A digitally generated ultrafine optical frequency comb for spectral measurements with 0.01-pm resolution and 0.7-µs response time