1.Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
2.National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China
3.National Center for Nanoscience and Technology, Beijing 100190, China
Li Song, Email: song2012@ustc.edu.cn
Sishen Xie, Email: ssxie@aphy.iphy.ac.cn
纸质出版日期:2015-09,
网络出版日期:2015-04-09,
收稿日期:2014-11-08,
修回日期:2015-04-01,
录用日期:2015-04-02
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Optical visualization and polarized light absorption of the single-wall carbon nanotube to verify intrinsic thermal applications[J]. LSA, 2015,4(3).
Zhang, X. et al. Optical visualization and polarized light absorption of the single-wall carbon nanotube to verify intrinsic thermal applications. Light: Science & Applications, 4, e318 (2015).
Optical visualization and polarized light absorption of the single-wall carbon nanotube to verify intrinsic thermal applications[J]. LSA, 2015,4(3). DOI: 10.1038/lsa.2015.91.
Zhang, X. et al. Optical visualization and polarized light absorption of the single-wall carbon nanotube to verify intrinsic thermal applications. Light: Science & Applications, 4, e318 (2015). DOI: 10.1038/lsa.2015.91.
The predicted extraordinary properties of carbon nanotubes (CNTs) from theoretical calculations have great potential for many applications. However
reliable experimental determination of intrinsic properties at the single-tube level is currently a matter of concern
and many challenges remain because of the unhandled and nanoscale size of individual nanotubes. Here
we demonstrated a prototype to detect the intrinsic thermal conductivity of the single-wall carbon nanotube (SWCNT) and verify the significant non-resonant optical absorption behavior on tiny nanotubes by integrating the nanotube and ice into a new core-shell design. In particular
a reversible optical visualization method based on the individual suspended ultra-long SWCNT was first developed by wrapping a nanotube with ice in the cryogenic air environment. The light-induced thermal effect on the hybrid core-shell structure was used to melt the ice shell
which subsequently acted as a temperature sensor to verify the intrinsic thermal conductivity of the core-like nanotube. More interestingly
we successfully determined for the first time the thermal response phenomenon of the tiny absorption cross section in SWCNT in the vertical-polarization configuration and the significant non-resonant absorption behavior in the parallel-polarization configuration. These investigations will provide a better understanding for the unique optical behaviors of CNT and enable the detection of intrinsic properties of various one-dimensional nanostructures such as nanotubes
nanowires
and nanoribbons.
carbon nanotubeoptical visualizationpolarized laserresonant absorption
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