1.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2.Department of Macromolecular Science and Engineering, School of Engineering, Case Western Reserve University, Cleveland, OH 44106, USA
3.School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710062, China
4.Luminous! Center of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798, Singapore
DG Ma, Email: mdg1014@ciac.ac.cn
纸质出版日期:2016-06,
网络出版日期:2016-11-05,
收稿日期:2015-06-23,
修回日期:2015-10-21,
录用日期:2015-11-04
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Organic semiconductor heterojunctions: electrode-independent charge injectors for high-performance organic light-emitting diodes[J]. LSA, 2016,5(2).
Chen, Y. H. et al. Organic semiconductor heterojunctions: electrode-independent charge injectors for high-performance organic light-emitting diodes. Light: Science & Applications, 5, e16042 (2016).
Organic semiconductor heterojunctions: electrode-independent charge injectors for high-performance organic light-emitting diodes[J]. LSA, 2016,5(2). DOI: 10.1038/lsa.2016.42.
Chen, Y. H. et al. Organic semiconductor heterojunctions: electrode-independent charge injectors for high-performance organic light-emitting diodes. Light: Science & Applications, 5, e16042 (2016). DOI: 10.1038/lsa.2016.42.
Organic light-emitting diodes (OLEDs) are driven by injected charges from an anode and a cathode. The low and high work function metals are necessary for the effective injection of electrons and holes
respectively. Here
we introduce a fully novel design concept using organic semiconductor heterojunctions (OSHJs) as the charge injectors for achieving highly efficient OLEDs
regardless of the work functions of the electrodes. In contrast to traditional injected charges from the electrodes
the injected charges originate from the OSHJs. The device performance was shown to be significantly improved in efficiency and stability compared to conventional OLEDs. Attractively
the OLEDs based on OSHJs as charge injectors still exhibited an impressive performance when the low work function Al was replaced by air- and chemistry-stable high work function metals
such as Au
Ag
and Cu
as the cathode contact
which has been suggested to be difficult in conventional OLEDs. This concept challenges the conventional design approach for the injection of charges and allows for the realization of practical applications of OLEDs with respect to high efficiency
selectable electrodes
and a long lifetime.
charge injectionOLEDsorganic semiconductor heterojunctions
Arkhipov VI, Emelianova EV, Tak YH, Bässler H. Charge injection into light-emitting diodes: theory and experiment.J Appl Phys1998;84: 848–856..
Brutting W, Adachi C.Physics of Organic Semiconductors. 2 edn. Weinheim: Wiley-VCH Verlag GmbH&Co. KGaA; 2012.
Murdey RJ, Salaneck WR. Charge injection barrier heights across multilayer organic thin films.Jpn J Appl Phys2005;44: 3751–3756..
Wang ZB, Helander MG, Greiner MT, Qiu J, Lu ZH. Analysis of charge-injection characteristics at electrode-organic interfaces: case study of transition-metal oxides.Phys Rev B2009;80: 235325..
Lee ST, Gao ZQ, Hung LS. Metal diffusion from electrodes in organic light-emitting diodes.Appl Phys Lett1999;75: 1404–1406..
Parker ID, Cao Y, Yang CY. Lifetime and degradation effects in polymer light-emitting diodes.J Appl Phys1999;85: 2441–2447..
Ma H, Yip HL, Huang F, Jen AKY. Interface engineering for organic electronics.Adv Funct Mater2010;20: 1371–1388..
Lee BR, Jung ED, Park JS, Nam YS, Min SHet al. Highly efficient inverted polymer light-emitting diodes using surface modifications of ZnO layer.Nat Commun2014;5: 4840..
Mason MG, Tang CW, Hung LS, Raychaudhuri P, Madathil Jet al. Interfacial chemistry of Alq3 and LiF with reactive metals.J Appl Phys2001;89: 2756–2765..
Walzer K, Maennig B, Pfeiffer M, Leo K. Highly efficient organic devices based on electrically doped transport layers.Chem Rev2007;107: 1233–1271..
Choudhury KR, Yoon JH, So F. LiF as an n-dopant in tris(8-hydroxyquinoline) aluminum thin films.Adv Mater2008;20: 1456–1461..
Pfeiffer M, Leo K, Zhou X, Huang JS, Hofmann Met al. Doped organic semiconductors: physics and application in light emitting diodes.Org Electron2003;4: 89–103..
Tong SW, Lee CS, Lifshitz Y, Gao DQ, Lee ST. Conducting fluorocarbon coatings for organic light-emitting diodes.Appl Phys Lett2004;84: 4032–4034..
Helander MG, Wang ZB, Qiu J, Greiner MT, Puzzo DPet al. Chlorinated indium tin oxide electrodes with high work function for organic device compatibility.Science2011;332: 944–947..
Elschner A, Bruder F, Heuer HW, Jonas F, Karbach Aet al. PEDT/PSS for efficient hole-injection in hybrid organic light-emitting diodes.Synth Met2000;111–112: 139–143..
Qiao XF, Chen JS, Li XL, Ma DG. Observation of hole hopping via dopant in MoOx-doped organic semiconductors: mechanism analysis and application for high performance organic light-emitting devices.J Appl Phys2010;107: 104505..
So F, Kondakov D. Degradation mechanisms in small-molecule and polymer organic light-emitting diodes.Adv Mater2010;22: 3762–3777..
Kanno H, Holmes RJ, Sun Y, Kena-Cohen S, Forrest SR. White stacked electrophosphorescent organic light-emitting devices employing MoO3as a charge-generation layer.Adv Mater2006;18: 339–342..
Liao LS, Klubek KP, Tang CW. High-efficiency tandem organic light-emitting diodes.Appl Phys Lett2004;84: 167–169..
Guo FW, Ma DG. White organic light-emitting diodes based on tandem structures.Appl Phys Lett2005;87: 173510..
Liao LS, Klubek KP. Power efficiency improvement in a tandem organic light-emitting diode.Appl Phys Lett2008;92: 223311..
Leem DS, Lee JH, Kim JJ, Kang JW. Highly efficient tandemp-i-norganic light-emitting diodes adopting a low temperature evaporated rhenium oxide interconnecting layer.Appl Phys Lett2008;93: 103304..
Chen YH, Chen JS, Ma DG, Yan DH, Wang LXet al. High power efficiency tandem organic light-emitting diodes based on bulk heterojunction organic bipolar charge generation layer.Appl Phys Lett2011;98: 243309..
Chen YH, Tian HK, Geng YH, Chen JS, Ma DGet al. Organic heterojunctions as a charge generation layer in tandem organic light-emitting diodes: the effect of interfacial energy level and charge carrier mobility.J Mater Chem2011;21: 15332–15336..
Chen YH, Chen JS, Ma DG, Yan DH, Wang LX. Effect of organic bulk heterojunction as charge generation layer on the performance of tandem organic light-emitting diodes.J Appl Phys2011;110: 074504..
Chen YH, Ma DG. Organic semiconductor heterojunctions as charge generation layers and their application in tandem organic light-emitting diodes for high power efficiency.J Mater Chem2012;22: 18718–18734..
Chen YH, Wang Q, Chen JS, Ma DG, Yan DHet al. Organic semiconductor heterojunction as charge generation layer in tandem organic light-emitting diodes for high power efficiency.Org Electron2012;13: 1121–1128..
Kang SJ, Yi Y, Kim CY, Cho K, Seo JHet al. Ambipolar organic thin-film transistors using C60/pentacene structure: characterization of electronic structure and device property.Appl Phys Lett2005;87: 233502..
Kang SJ, Yi Y, Kim CY, Cho SW, Noh Met al. Energy level diagrams of C60/pentacene/Au and pentacene/C60/Au.Synth Met2006;156: 32–37..
Verlaak S, Beljionne D, Cheyns D, Rolin C, Linares Met al. Electronic structure and geminate pair energetics at organic-organic interfaces: the case of pentacene/C60heterojunctions.Adv Funct Mater2009;19: 3809–3814..
Park B, Paoprasert P, Gopalan P, Kuech TF, Evans PG. Dynamics of photoinduced charge transfer between pentacene and a C60-terminated self-assembled monolayer.Appl Phys Lett2009;94: 073302..
Reineke S, Lindner F, Schwartz G, Seidler N, Walzer Ket al. White organic light-emitting diodes with fluorescent tube efficiency.Nature2009;459: 234–238..
Yoo S, Domercq B, Kippelen B. Efficient thin-film organic solar cells based on pentacene/C60heterojunctions.Appl Phys Lett2004;85: 5427–5429..
Anderson RL. Germanium-gallium arsenide heterojunctions [letter to the editor].IBM J Res Dev1960;4: 283–287..
Yan DH, Wang HB, Du BX.Introduction to Organic Semiconductor Heterojunctions. Weinheim: Wiley-VCH Verlag GmbH&Co. KGaA; 2010.
Liu XL, Wang CG, Wang CC, Irfan I, Gao YL. Interfacial electronic structures of buffer-modified pentacene/C60-based charge generation layer.Org Electron2015;17: 325–333..
Sun QJ, Dong GF, Li D, Duan L, Wang LDet al. Dark current and photovoltage models on the formation of depletion region in C60/NPB organic heterojunctions.Org Electron2012;13: 3276–3283..
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