Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions

Chao Xie; Peng You; Zhike Liu; Li Li; Feng Yan

doi:10.1038/lsa.2017.23

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Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions

Original Articles

- Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions
- Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions
- LSA 2017年6卷第3期
- Affiliations：
  
  1.Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong 999077, China
  2.Institute of Textiles and Clothing, The Hong Kong Polytechnic University, Hong Kong 999077, China
- Author bio：
  
  F Yan, Email: apafyan@polyu.edu.hk
- Funds：
- DOI：10.1038/lsa.2017.23
  中图分类号：
- 纸质出版日期：2017-09，
  
  网络出版日期：2017-02-22，
  
  收稿日期：2016-08-11，
  
  修回日期：2017-02-08，
  
  录用日期：2017-02-13
- Accepted：
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Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions[J]. LSA, 2017,6(3).

Xie, C. et al. Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions. Light: Science & Applications, 6, e17023 (2017).
Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions[J]. LSA, 2017,6(3). DOI： 10.1038/lsa.2017.23.

Xie, C. et al. Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions. Light: Science & Applications, 6, e17023 (2017). DOI： 10.1038/lsa.2017.23.

摘要

Abstract

Organolead halide perovskites have emerged as the most promising materials for various optoelectronic devices

especially solar cells

because of their excellent optoelectronic properties. Here

we present the first report of low-voltage high-gain phototransistors based on perovskite/organic-semiconductor vertical heterojunctions

which show ultrahigh responsivities of ~10

A W

–1

and specific detectivities of ~10

Jones in a broadband region from the ultraviolet to the near infrared. The high sensitivity of the devices is attributed to a pronounced photogating effect that is mainly due to the long carrier lifetimes and strong light absorption in the perovskite material. In addition

flexible perovskite photodetectors have been successfully prepared via a solution process and show high sensitivity as well as excellent flexibility and bending durability. The high performance and facile solution-based fabrication of the perovskite/organic-semiconductor phototransistors indicate their promise for potential application for ultrasensitive broadband photodetection.

关键词

Keywords

broadbandflexibleorganic semiconductorperovskitephotodetector

references

Gong X, Tong MH, Xia YJ, Cai WZ, Moon JSet al. High-detectivity polymer photodetectors with spectral response from 300 nm to 1450 nm.Science2009;325: 1665–1667..

Arnold MS, Zimmerman JD, Renshaw CK, Xu X, Lunt RRet al. Broad spectral response using carbon nanotube/organic semiconductor/C60photodetectors.Nano Lett2009;9: 3354–3358..

Konstantatos G, Sargent EH. Nanostructured materials for photon detection.Nat Nanotechnol2010;5: 391–400..

Li JH, Niu LY, Zheng ZJ, Yan F. Photosensitive graphene transistors.Adv Mater2014;26: 5239–5273..

Soci C, Zhang A, Xiang B, Dayeh SA, Aplin DPRet al. ZnO nanowire UV photodetectors with high internal gain.Nano Lett2007;7: 1003–1009..

Sze SM, Ng KK.Physics of Semiconductor Devices,(3rd edn. )Hoboken: John Wiley&Sons, Inc.; 2006..

Konstantatos G, Howard I, Fischer A, Hoogland S, Clifford Jet al. Ultrasensitive solution-cast quantum dot photodetectors.Nature2006;442: 180–183..

Guo FW, Yang B, Yuan YB, Xiao ZG, Dong QFet al. A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection.Nat Nanotechnol2012;7: 798–802..

Xia FN, Mueller T, Lin YM, Valdes-Garcia A, Avouris P. Ultrafast graphene photodetector.Nat Nanotechnol2009;4: 839–843..

Liu C-H, Chang Y-C, Norris TB, Zhong ZH. Graphene photodetectors with ultra-broadband and high responsivity at room temperature.Nat Nanotechnol2014;9: 273–278..

Lopez-Sanchez O, Lembke D, Kayci M, Radenovic A, Kis A. Ultrasensitive photodetectors based on monolayer MoS2.Nat Nanotechnol2013;8: 497–501..

Duan XD, Wang C, Shaw JC, Cheng R, Chen Yet al. Lateral epitaxial growth of two-dimensional layered semiconductor heterojunctions.Nat Nanotechnol2014;9: 1024–1030..

Konstantatos G, Badioli M, Gaudreau L, Osmond J, Bernechea Met al. Hybrid graphene–quantum dot phototransistors with ultrahigh gain.Nat Nanotechnol2012;7: 363–368..

Sun ZH, Liu ZK, Li JH, Tai GA, Lau S-Pet al. Infrared photodetectors based on CVD-grown graphene and PbS quantum dots with ultrahigh responsivity.Adv Mater2012;24: 5878–5883..

Roy K, Padmanabhan M, Goswami S, Sai TP, Ramalingam Get al. Graphene–MoS2hybrid structures for multifunctional photoresponsive memory devices.Nat Nanotechnol2013;8: 826–830..

Yang Y, da Costa RC, Fuchter MJ, Campbell AJ. Circularly polarized light detection by a chiral organic semiconductor transistor.Nat Photonics2013;7: 634–638..

Baeg KJ, Binda M, Natali D, Caironi M, Noh YY. Organic light detectors: photodiodes and phototransistors.Adv Mater2013;25: 4267–4295..

Burschka J, Pellet N, Moon S-J, Humphry-Baker R, Gao Pet al. Sequential deposition as a route to high-performance perovskite-sensitized solar cells.Nature2013;499: 316–320..

Liu MZ, Johnston MB, Snaith HJ. Efficient planar heterojunction perovskite solar cells by vapour deposition.Nature2013;501: 395–398..

Kim H-S, Lee C-R, Im J-H, Lee K-B, Moehl Tet al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%.Sci Rep2012;2: 591..

Jeng JY, Chiang YF, Lee MH, Peng SR, Guo TFet al. CH3NH3PbI3perovskite/fullerene planar-heterojunction hybrid solar cells.Adv Mater2013;25: 3727–3732..

Kazim S, Nazeeruddin MK, Grätzel M, Ahmad S. Perovskite as light harvester: a game changer in photovoltaics.Angew Chemie - Int Ed2014;53: 2812–2824..

Stranks SD, Eperon GE, Grancini G, Menelaou C, Alcocer MJPet al. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber.Science2013;342: 341–344..

Shi D, Adinolfi V, Comin R, Yuan MJ, Alarousu Eet al. Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals.Science2015;347: 519–522..

Dong QF, Fang YJ, Shao YC, Mulligan P, Qiu Jet al. Electron-hole diffusion lengths> 175 μm in solution-grown3NH3PbI3single crystals.Science2015;347: 967–970..

Tan Z-K, Moghaddam RS, Lai ML, Docampo P, Higler Ret al. Bright light-emitting diodes based on organometal halide perovskite.Nat Nanotechnol2014;9: 687–692..

Zhu HM, Fu YP, Meng F, Wu XX, Gong ZZet al. Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors.Nat Mater2015;14: 636–642..

Yakunin S, Sytnyk M, Kriegner D, Shrestha S, Richter Met al. Detection of X-ray photons by solution-processed lead halide perovskites.Nat Photonics2015;9: 444–449..

Zhou HP, Chen Q, Li G, Luo S, Song T-Bet al. Interface engineering of highly efficient perovskite solar cells.Science2014;345: 542–546..

Yang WS, Noh JH, Jeon NJ, Kim YC, Ryu Set al. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange.Science2015;348: 1234–1237..

Hu X, Zhang XD, Liang L, Bao J, Li Set al. High-Performance flexible broadband photodetector based on organolead halide perovskite.Adv Funct Mater2014;24: 7373–7380..

Xia HR, Li J, Sun WT, Peng LM. Organohalide lead perovskite based photodetectors with much enhanced performance.Chem Commun2014;50: 13695–13697..

Dou LT, Yang Y, You JB, Hong ZR, Chang W-Het al. Solution-processed hybrid perovskite photodetectors with high detectivity.Nat Commun2014;5: 5404..

Dong R, Fang YJ, Chae J, Dai J, Xiao ZGet al. High-gain and low-driving-voltage photodetectors based on organolead triiodide perovskites.Adv Mater2015;27: 1912–1918..

Lee Y, Kwon J, Hwang E, Ra CH, Yoo WJet al. High-performance perovskite-graphene hybrid photodetector.Adv Mater2015;27: 41–46..

Li F, Ma C, Wang H, Hu WJ, Yu WLet al. Ambipolar solution-processed hybrid perovskite phototransistors.Nat Commun2015;6: 8238..

Fang YJ, Dong QF, Shao YC, Yuan YB, Huang JS. Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination.Nat Photonics2015;9: 679–686..

Lin QQ, Armin A, Burn PL, Meredith P. Filterless narrowband visible photodetectors.Nat Photonics2015;9: 687–694..

Xu WT, Cho H, Kim YH, Kim YT, Wolf Cet al. Organometal halide perovskite artificial synapses.Adv Mater2016;28: 5916–5922..

Grancini G, Srimath Kandada AR, Frost JM, Barker AJ, De Bastiani Met al. Role of microstructure in the electron–hole interaction of hybrid lead halide perovskites.Nat Photonics2015;9: 695–701..

Green MA, Ho-Baillie A, Snaith HJ. The emergence of perovskite solar cells.Nat Photonics2014;8: 506–514..

Shao DL, Gao J, Chow P, Sun HT, Xin GQet al. Organic-inorganic heterointerfaces for ultrasensitive detection of ultraviolet light.Nano Lett2015;15: 3787–3792..

Liu X, Gu LL, Zhang QP, Wu JY, Long YZet al. All-printable band-edge modulated ZnO nanowire photodetectors with ultra-high detectivity.Nat Commun2014;5: 4007..

Kim CO, Kim S, Shin DH, Kang SS, Kim JMet al. High photoresponsivity in an all-graphene p-n vertical junction photodetector.Nat Commun2014;5: 3249..

You P, Liu ZK, Tai QD, Liu SH, Yan F. Efficient semitransparent perovskite solar cells with graphene electrodes.Adv Mater2015;27: 3632–3638..

Jung HS, Park NG. Perovskite solar cells: from materials to devices.Small2015;11: 10–25..

Zhang WJ, Chuu C-P, Huang J-K, Chen C-H, Tsai M-Let al. Ultrahigh-gain photodetectors based on atomically thin graphene-MoS2heterostructures.Sci Rep2014;4: 3826..

Xing GC, Mathews N, Sun SY, Lim SS, Lam YMet al. Long-range balanced electron- and hole-transport lengths in organic-inorganic CH3NH3PbI3.Science2013;342: 344–347..

deQuilettes DW, Vorpahl SM, Stranks SD, Nagaoka H, Eperon GEet al. Impact of microstructure on local carrier lifetime in perovskite solar cells.Science2015;348: 683–686..

Li JH, Sun ZH, Yan F. Solution processable low-voltage organic thin film transistors with high-krelaxor ferroelectric polymer as gate insulator.Adv Mater2012;24: 88–93..

Yan F, Li JH, Mok SM. Highly photosensitive thin film transistors based on a composite of poly(3-hexylthiophene) and titania nanoparticles.J Appl Phys2009;106: 074501..

Song YM, Xie YZ, Malyarchuk V, Xiao JL, Jung Iet al. Digital cameras with designs inspired by the arthropod eye.Nature2013;497: 95–99..

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