Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity

Lucia Di Virgilio; Jaco J. Geuchies; Heejae Kim; Keno Krewer; Hai Wang; Maksim Grechko; Mischa Bonn

doi:10.1038/s41377-023-01232-0

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Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity

Original Articles

- Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity
- Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity
- LSA 2023年12卷第9期页码：1749-1756
- Affiliations：
  
  1.Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany
  2.Pohang University of Science and Technology, Department of Physics, 37673 Pohang, Korea
- Author bio：
  
  Maksim Grechko (grechko@mpip-mainz.mpg.de)
  Mischa Bonn (bonn@mpip-mainz.mpg.de)
- Funds：
- DOI：10.1038/s41377-023-01232-0
  中图分类号：
- 纸质出版日期：2023-09-30，
  
  网络出版日期：2023-07-26，
  
  收稿日期：2023-01-09，
  
  修回日期：2023-07-10，
  
  录用日期：2023-07-14
- Accepted：
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Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity[J]. LSA, 2023,12(9):1749-1756.

Di Virgilio, L. et al. Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity. Light: Science & Applications, 12, 1749-1756 (2023).
Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity[J]. LSA, 2023,12(9):1749-1756. DOI： 10.1038/s41377-023-01232-0.

Di Virgilio, L. et al. Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity. Light: Science & Applications, 12, 1749-1756 (2023). DOI： 10.1038/s41377-023-01232-0.

摘要

Abstract

Optical cavities

resonant with vibrational or electronic transitions of material within the cavity

enable control of light-matter interaction. Previous studies have reported cavity-induced modifications of chemical reactivity

fluorescence

phase behavior

and charge transport. Here

we explore the effect of resonant cavity-phonon coupling on the transient photoconductivity in a hybrid organic-inorganic perovskite. To this end

we measure the ultrafast photoconductivity response of perovskite in a tunable Fabry–Pérot terahertz cavity

designed to be transparent for optical excitation. The terahertz-cavity field-phonon interaction causes apparent Rabi splitting between the perovskite phonon mode and the cavity mode. We explore whether the cavity-phonon interaction affects the material's electron-phonon interaction by determining the charge-carrier mobility through photoconductivity. Despite the apparent hybridization of cavity and phonon modes

we show that the perovskite properties in both ground (phonon response) and excited (photoconductive response) states remain unaffected by the tunable light-matter interaction. Yet the response of the integral perovskite-terahertz optical cavity system depends critically on the interaction strength of the cavity with the phonon: the transient terahertz response to optical excitation can be increased up to threefold by tuning the cavity-perovskite interaction strength. These results enable tunable switches and frequency-controlled induced transparency devices.

关键词

Keywords

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