Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

Surendra B. Anantharaman; Jason Lynch; Christopher E. Stevens; Christopher Munley; Chentao Li; Jin Hou; Hao Zhang; Andrew Torma; Thomas Darlington; Francis Coen; Kevin Li; Arka Majumdar; P. James Schuck; Aditya Mohite; Hayk Harutyunyan; Joshua R. Hendrickson; Deep Jariwala

doi:10.1038/s41377-023-01334-9

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Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

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- Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites
- Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites
- LSA 2024年13卷第1期页码：13-22
- Affiliations：
- Author bio：
  
  asba@iitm.ac.in
  tdmj@seas.upenn.edu
- Funds：
  
  United States Department of Defense | United States Army | U.S. Army Research, Development and Engineering Command | Army Research Laboratory (U.S. Army Research Laboratory);United States Department of Defense | United States Air Force | AFMC | Air Force Office of Scientific Research (AF Office of Scientific Research);National Science Foundation (NSF);Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation);United States Department of Defense | United States Air Force | AFMC | Air Force Research Laboratory (AFRL);DOE | SC | Basic Energy Sciences (BES)
- DOI：10.1038/s41377-023-01334-9
  中图分类号：
- 收稿日期：2023-03-12，
  
  修回日期：2023-10-25，
  
  录用日期：2023-11-10，
  
  网络出版日期：2024-01-01，
  
  纸质出版日期：2024-12
- Accepted：
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Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites[J]. LSA, 2024,13(1):13-22.

Surendra B. Anantharaman, Jason Lynch, Christopher E. Stevens, et al. Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites[J]. Light: science & applications, 2024, 13(1): 13-22.
Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites[J]. LSA, 2024,13(1):13-22. DOI： 10.1038/s41377-023-01334-9.

Surendra B. Anantharaman, Jason Lynch, Christopher E. Stevens, et al. Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites[J]. Light: science & applications, 2024, 13(1): 13-22. DOI： 10.1038/s41377-023-01334-9.

摘要

Abstract

Excitons

bound electron–hole pairs

in two-dimensional hybrid organic inorganic perovskites (2D HOIPs) are capable of forming hybrid light-matter states known as exciton-polaritons (E–Ps) when the excitonic medium is confined in an optical cavity. In the case of 2D HOIPs

they can self-hybridize into E–Ps at specific thicknesses of the HOIP crystals that form a resonant optical cavity with the excitons. However

the fundamental properties of these self-hybridized E–Ps in 2D HOIPs

including their role in ultrafast energy and/or charge transfer at interfaces

remain unclear. Here

we demonstrate that >0.5 µm thick 2D HOIP crystals on Au substrates are capable of supporting multiple-orders of self-hybridized E–P modes. These E–Ps have high Q factors (>100) and modulate the optical dispersion for the crystal to enhance sub-gap absorption and emission. Through varying excitation energy and ultrafast measurements

we also confirm energy transfer from higher energy E–Ps to lower energy E–Ps. Finally

we also demonstrate that E–Ps are capable of charge transport and transfer at interfaces. Our findings provide new insights into charge and energy transfer in E–Ps opening new opportunities towards their manipulation for polaritonic devices.

Self-hybridized exciton–polaritons are shown to enable sub-bandgap absorption and emission in 2D perovskites. The energy absorbed by the perovskites are also found to transfer to few-layer graphene in a heterostructure.

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references

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