Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors

Xile Han; Hai Zhong; Kaiwei Li; Xiaobin Xue; Wen Wu; Nan Hu; Xihong Lu; Jiaqiang Huang; Gaozhi Xiao; Yaohua Mai; Tuan Guo

doi:10.1038/s41377-023-01346-5

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Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors

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- Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors
- Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors
- LSA 2024年13卷第1期页码：153-166
- Affiliations：
- Author bio：
  
  hseejhuang@ust.hk
  jgeorge.xiao@nrc-cnrc.gc.ca
  kyaohuamai@jnu.edu.cn
  mtuanguo@jnu.edu.cn
- Funds：
  
  The National Natural Science Foundation of China (No. 62035006, No. U2033204); The Guangdong Outstanding Scientific Innovation Foundation (No. 2019TX05X383); The Program of Marine Economy Development Special Fund under Department of Natural Resources of Guangdong Province (No. GDNRC [2023]23);National Natural Science Foundation of China (No. 52207230); Guangzhou Municipal Science and Technology Project (No. 2023A03J0003 and No. 2023A03J0103)
- DOI：10.1038/s41377-023-01346-5
  中图分类号：
- 收稿日期：2023-08-19，
  
  修回日期：2023-10-24，
  
  录用日期：2023-11-27，
  
  网络出版日期：2024-01-22，
  
  纸质出版日期：2024-12
- Accepted：
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Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors[J]. LSA, 2024,13(1):153-166.

Xile Han, Hai Zhong, Kaiwei Li, et al. Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors[J]. Light: science & applications, 2024, 13(1): 153-166.
Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors[J]. LSA, 2024,13(1):153-166. DOI： 10.1038/s41377-023-01346-5.

Xile Han, Hai Zhong, Kaiwei Li, et al. Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors[J]. Light: science & applications, 2024, 13(1): 153-166. DOI： 10.1038/s41377-023-01346-5.

摘要

Abstract

Lithium (Li) dendrite growth significantly deteriorates the performance and shortens the operation life of lithium metal batteries. Capturing the intricate dynamics of surface localized and rapid mass transport at the electrolyte–electrode interface of lithium metal is essential for the understanding of the dendrite growth process

and the evaluation of the solutions mitigating the dendrite growth issue. Here we demonstrate an approach based on an ultrasensitive tilted fiber Bragg grating (TFBG) sensor which is inserted close to the electrode surface in a working lithium metal battery

without disturbing its operation. Thanks to the superfine optical resonances of the TFBG

in situ and rapid monitoring of mass transport kinetics and lithium dendrite growth at the nanoscale interface of lithium anodes have been achieved. Reliable correlations between the performance of different natural/artificial solid electrolyte interphases (SEIs) and the time-resolved optical responses have been observed and quantified

enabling us to link the nanoscale ion and SEI behavior with the macroscopic battery performance. This new

operando

tool will provide additional capabilities for parametrization of the batteries’ electrochemistry and help identify the optimal interphases of lithium metal batteries to enhance battery performance and its safety.

Operando monitoring of mass transport kinetics and lithium dendrite growth in lithium metal batteries and parametrization of the batteries’ electrochemistry and safety have been achieved using optical fiber sensors.

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