Tunnelling of electrons via the neighboring atom

Ming Zhu; Jihong Tong; Xiwang Liu; Weifeng Yang; Xiaochun Gong; Wenyu Jiang; Peifen Lu; Hui Li; Xiaohong Song; Jian Wu

doi:10.1038/s41377-023-01373-2

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Tunnelling of electrons via the neighboring atom

Article

- Tunnelling of electrons via the neighboring atom
- Tunnelling of electrons via the neighboring atom
- LSA 2024年13卷第1期页码：127-134
- Affiliations：
- Author bio：
  
  dwfyang@hainanu.edu.cn
- Funds：
  
  National Natural Science Foundation of China (National Science Foundation of China)
- DOI：10.1038/s41377-023-01373-2
  中图分类号：
- 收稿日期：2023-07-11，
  
  修回日期：2023-12-12，
  
  录用日期：2023-12-22，
  
  网络出版日期：2024-01-16，
  
  纸质出版日期：2024-12
- Accepted：
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Tunnelling of electrons via the neighboring atom[J]. LSA, 2024,13(1):127-134.

Ming Zhu, Jihong Tong, Xiwang Liu, et al. Tunnelling of electrons via the neighboring atom[J]. Light: science & applications, 2024, 13(1): 127-134.
Tunnelling of electrons via the neighboring atom[J]. LSA, 2024,13(1):127-134. DOI： 10.1038/s41377-023-01373-2.

Ming Zhu, Jihong Tong, Xiwang Liu, et al. Tunnelling of electrons via the neighboring atom[J]. Light: science & applications, 2024, 13(1): 127-134. DOI： 10.1038/s41377-023-01373-2.

摘要

Abstract

As compared to the intuitive process that the electron emits straight to the continuum from its parent ion

there is an alternative route that the electron may transfer to and be trapped by a neighboring ionic core before the eventual release. Here

we demonstrate that electron tunnelling via the neighboring atomic core is a pronounced process in light-induced tunnelling ionization of molecules by absorbing multiple near-infrared photons. We devised a site-resolved tunnelling experiment using an Ar-Kr

ion as a prototype system to track the electron tunnelling dynamics from the Ar atom towards the neighboring Kr

by monitoring its transverse momentum distribution

which is temporally captured into the resonant excited states of the Ar-Kr

before its eventual releasing. The influence of the Coulomb potential of neighboring ionic cores promises new insights into the understanding and controlling of tunnelling dynamics in complex molecules or environment.

A van der Waals complex with an internuclear distance of 0.39 nm is designed as a prototype system to track electron tunneling via neighboring atoms within a sub-nanometer scale.

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references

Y. Cha , C.J. Murray , J.P. Klinman , Hydrogen tunneling in enzyme reactions . Science 243 , 1325 - 1330 ( 1989 ). http://doi.org/10.1126/science.2646716 http://doi.org/10.1126/science.2646716

K.M. Doll , B.R. Bender , R.G. Finke , The first experimental test of the hypothesis that enzymes have evolved to enhance hydrogen tunneling . J. Am. Chem. Soc. 125 , 10877 - 10884 ( 2003 ). http://doi.org/10.1021/ja030120h http://doi.org/10.1021/ja030120h

P. Ball , Enzymes: by chance, or by design? . Nature 431 , 396 - 398 ( 2004 ). http://doi.org/10.1038/431396a http://doi.org/10.1038/431396a

P.O. Löwdin , Proton tunneling in DNA and its biological implications . Rev. Mod. Phys. 35 , 724 - 732 ( 1963 ). http://doi.org/10.1103/RevModPhys.35.724 http://doi.org/10.1103/RevModPhys.35.724

J. McFadden , J. Al-Khalili , A quantum mechanical model of adaptive mutation . Biosystems 50 , 203 - 211 ( 1999 ). http://doi.org/10.1016/S0303-2647(99)00004-0 http://doi.org/10.1016/S0303-2647(99)00004-0

A. Godbeer , J.S. Al-Khalili , P.D. Stevenson , Modelling proton tunnelling in the adenine–thymine base pair . Phys. Chem. Chem. Phys. 17 , 13034 - 13044 ( 2015 ). http://doi.org/10.1039/C5CP00472A http://doi.org/10.1039/C5CP00472A

X. Zhu et al. , Heavy N + ion transfer in doubly charged N 2 Ar van der Waals cluster . Nat. Commun. 11 ,( 2020 ). http://doi.org/10.1038/s41467-020-16749-w http://doi.org/10.1038/s41467-020-16749-w

L. Turin , A spectroscopic mechanism for primary olfactory reception . Chem. Senses 21 , 773 - 791 ( 1996 ). http://doi.org/10.1093/chemse/21.6.773 http://doi.org/10.1093/chemse/21.6.773

P.M. Kraus , M. Zürch , S.K. Cushing , D.M. Neumark , S.R. Leone , The ultrafast X-ray spectroscopic revolution in chemical dynamics . Nat. Rev. Chem. 2 , 82 - 94 ( 2018 ). http://doi.org/10.1038/s41570-018-0008-8 http://doi.org/10.1038/s41570-018-0008-8

D. Polli et al. , Conical intersection dynamics of the primary photoisomerization event in vision . Nature 467 , 440 - 443 ( 2010 ). http://doi.org/10.1038/nature09346 http://doi.org/10.1038/nature09346

A.M. Perelomov , V.S. Popov , M.V. Terent’ev , Ionization of atoms in an alternating electric field . Sov. Phys. JETP 23 , 924 - 934 ( 1966 ).

P. Agostini , F. Fabre , G. Mainfray , G. Petite , N.K. Rahman , Free-free transitions following six-photon ionization of xenon atoms . Phys. Rev. Lett. 42 , 1127 - 1130 ( 1979 ). http://doi.org/10.1103/PhysRevLett.42.1127 http://doi.org/10.1103/PhysRevLett.42.1127

T. Zuo , A.D. Bandrauk , Charge-resonance-enhanced ionization of diatomic molecular ions by intense lasers . Phys. Rev. A 52 , R2511 - R2514 ( 1995 ). http://doi.org/10.1103/PhysRevA.52.R2511 http://doi.org/10.1103/PhysRevA.52.R2511

P. Eckle et al. , Attosecond ionization and tunneling delay time measurements in helium . Science 322 , 1525 - 1529 ( 2008 ). http://doi.org/10.1126/science.1163439 http://doi.org/10.1126/science.1163439

Y. Huismans et al. , Time-resolved holography with photoelectrons . Science 331 , 61 - 64 ( 2011 ). http://doi.org/10.1126/science.1198450 http://doi.org/10.1126/science.1198450

J. Wu et al. , Probing the tunnelling site of electrons in strong field enhanced ionization of molecules . Nat. Commun. 3 ,( 2012 ). http://doi.org/10.1038/ncomms2130 http://doi.org/10.1038/ncomms2130

X. Gong et al. , Strong-field dissociative double ionization of acetylene . Phys. Rev. Lett. 112 , 243001 ( 2014 ). http://doi.org/10.1103/PhysRevLett.112.243001 http://doi.org/10.1103/PhysRevLett.112.243001

M. Drescher et al. , Time-resolved atomic inner-shell spectroscopy . Nature 419 , 803 - 807 ( 2002 ). http://doi.org/10.1038/nature01143 http://doi.org/10.1038/nature01143

M. Uiberacker et al. , Attosecond real-time observation of electron tunnelling in atoms . Nature 446 , 627 - 632 ( 2007 ). http://doi.org/10.1038/nature05648 http://doi.org/10.1038/nature05648

M. Ossiander et al. , Absolute timing of the photoelectric effect . Nature 561 , 374 - 377 ( 2018 ). http://doi.org/10.1038/s41586-018-0503-6 http://doi.org/10.1038/s41586-018-0503-6

L.R. Liu et al. , Building one molecule from a reservoir of two atoms . Science 360 , 900 - 903 ( 2018 ). http://doi.org/10.1126/science.aar7797 http://doi.org/10.1126/science.aar7797

R. Ramos , D. Spierings , I. Racicot , A.M. Steinberg , Measurement of the time spent by a tunnelling atom within the barrier region . Nature 583 , 529 - 532 ( 2020 ). http://doi.org/10.1038/s41586-020-2490-7 http://doi.org/10.1038/s41586-020-2490-7

M.F. Kling et al. , Control of electron localization in molecular dissociation . Science 312 , 246 - 248 ( 2006 ). http://doi.org/10.1126/science.1126259 http://doi.org/10.1126/science.1126259

P.M. Kraus et al. , Measurement and laser control of attosecond charge migration in ionized iodoacetylene . Science 350 , 790 - 795 ( 2015 ). http://doi.org/10.1126/science.aab2160 http://doi.org/10.1126/science.aab2160

L.S. Cederbaum , J. Zobeley , F. Tarantelli , Giant intermolecular decay and fragmentation of clusters . Phys. Rev. Lett. 79 , 4778 - 4781 ( 1997 ). http://doi.org/10.1103/PhysRevLett.79.4778 http://doi.org/10.1103/PhysRevLett.79.4778

F. Trinter et al. , Resonant Auger decay driving intermolecular Coulombic decay in molecular dimers . Nature 505 , 664 - 666 ( 2014 ). http://doi.org/10.1038/nature12927 http://doi.org/10.1038/nature12927

V. Stumpf , N.V. Kryzhevoi , K. Gokhberg , L.S. Cederbaum , Enhanced one-photon double ionization of atoms and molecules in an environment of different species . Phys. Rev. Lett. 112 , 193001 ( 2014 ). http://doi.org/10.1103/PhysRevLett.112.193001 http://doi.org/10.1103/PhysRevLett.112.193001

R.A. Aziz , A. Van Dalen , An improved potential for Ar–Kr. The . J. Chem. Phys. 78 , 2413 - 2418 ( 1983 ). http://doi.org/10.1063/1.445043 http://doi.org/10.1063/1.445043

T.P. Haley , S.M. Cybulski , Ground state potential energy curves for He–Kr, Ne–Kr, Ar–Kr, and Kr 2 : coupled-cluster calculations and comparison with experiment. The . J. Chem. Phys. 119 , 5487 - 5496 ( 2003 ). http://doi.org/10.1063/1.1600434 http://doi.org/10.1063/1.1600434

J. Tong et al. , Probing resonant photoionization time delay by self-referenced molecular attoclock . Phys. Rev. Lett. 129 , 173201 ( 2022 ). http://doi.org/10.1103/PhysRevLett.129.173201 http://doi.org/10.1103/PhysRevLett.129.173201

V S. Popruzhenko , D. Bauer , Strong field approximation for systems with Coulomb interaction . J. Mod. Opt. 55 , 2573 - 2589 ( 2008 ). http://doi.org/10.1080/09500340802161881 http://doi.org/10.1080/09500340802161881

T.M. Yan , S.V. Popruzhenko , M.J. Vrakking , D. Bauer , Low-energy structures in strong field ionization revealed by quantum orbits . Phys. Rev. Lett. 105 , 253002 ( 2010 ). http://doi.org/10.1103/PhysRevLett.105.253002 http://doi.org/10.1103/PhysRevLett.105.253002

M. Lewenstein , P. Balcou , M.Y. Ivanov , A. L'Huillier , P.B. Corkum , Theory of high-harmonic generation by low-frequency laser fields . Phys. Rev. A 49 , 2117 - 2132 ( 1994 ). http://doi.org/10.1103/PhysRevA.49.2117 http://doi.org/10.1103/PhysRevA.49.2117

X. Liu et al. , Deep learning for Feynman’s path integral in strong-field time-dependent dynamics . Phys. Rev. Lett. 124 , 113202 ( 2020 ). http://doi.org/10.1103/PhysRevLett.124.113202 http://doi.org/10.1103/PhysRevLett.124.113202

X. Song et al. , Attosecond time delay of retrapped resonant ionization . Phys. Rev. Lett. 121 , 103201 ( 2018 ). http://doi.org/10.1103/PhysRevLett.121.103201 http://doi.org/10.1103/PhysRevLett.121.103201

Landau, L. D., & Lifshitz, E. M. Quantum mechanics: non-relativistic theory 3 , 250 (2013).

T. Brabec , M.Y. Ivanov , P.B. Corkum , Coulomb focusing in intense field atomic processes . Phys. Rev. A 54 , R2551 - R2554 ( 1996 ). http://doi.org/10.1103/PhysRevA.54.R2551 http://doi.org/10.1103/PhysRevA.54.R2551

D. Shafir et al. , Trajectory-resolved coulomb focusing in tunnel ionization of atoms with intense, elliptically polarized laser pulses . Phys. Rev. Lett. 111 , 023005 ( 2013 ). http://doi.org/10.1103/PhysRevLett.111.023005 http://doi.org/10.1103/PhysRevLett.111.023005

M. Li et al. , Subcycle dynamics of coulomb asymmetry in strong elliptical laser fields . Phys. Rev. Lett. 111 , 023006 ( 2013 ). http://doi.org/10.1103/PhysRevLett.111.023006 http://doi.org/10.1103/PhysRevLett.111.023006

S.A. Kelvich , W. Becker , S.P. Goreslavski , Coulomb focusing and defocusing in above-threshold-ionization spectra produced by strong mid-IR laser pulses . Phys. Rev. A 93 , 033411 ( 2016 ). http://doi.org/10.1103/PhysRevA.93.033411 http://doi.org/10.1103/PhysRevA.93.033411

U.S. Sainadh et al. , Attosecond angular streaking and tunnelling time in atomic hydrogen . Nature 568 , 75 - 77 ( 2019 ). http://doi.org/10.1038/s41586-019-1028-3 http://doi.org/10.1038/s41586-019-1028-3

L. Torlina et al. , Interpreting attoclock measurements of tunnelling times . Nat. Phys. 11 , 503 - 508 ( 2015 ). http://doi.org/10.1038/nphys3340 http://doi.org/10.1038/nphys3340

H.C. Ni , U. Saalmann , J.M. Rost , Tunneling ionization time resolved by backpropagation . Phys. Rev. Lett. 117 , 023002 ( 2016 ). http://doi.org/10.1103/PhysRevLett.117.023002 http://doi.org/10.1103/PhysRevLett.117.023002

K.L. Liu , I. Barth , Identifying the tunneling site in strong-field ionization of H 2 + . Phys. Rev. Lett. 119 , 243204 ( 2017 ). http://doi.org/10.1103/PhysRevLett.119.243204 http://doi.org/10.1103/PhysRevLett.119.243204

S. Eckart et al. , Ultrafast preparation and detection of ring currents in single atoms . Nat. Phys. 14 , 701 - 704 ( 2018 ). http://doi.org/10.1038/s41567-018-0080-5 http://doi.org/10.1038/s41567-018-0080-5

M. Meckel et al. , Signatures of the continuum electron phase in molecular strong-field photoelectron holography . Nat. Phys. 10 , 594 - 600 ( 2014 ). http://doi.org/10.1038/nphys3010 http://doi.org/10.1038/nphys3010

X. Gong et al. , Energy-resolved ultrashort delays of photoelectron emission clocked by orthogonal two-color laser fields . Phys. Rev. Lett. 118 , 143203 ( 2017 ). http://doi.org/10.1103/PhysRevLett.118.143203 http://doi.org/10.1103/PhysRevLett.118.143203

S. Ghimire , D.A. Reis , High-harmonic generation from solids . Nat. Phys. 15 , 10 - 16 ( 2019 ). http://doi.org/10.1038/s41567-018-0315-5 http://doi.org/10.1038/s41567-018-0315-5

R. Dörner et al. , Cold target recoil ion momentum spectroscopy: a ‘momentum microscope’ to view atomic collision dynamics . Phys. Rep. 330 , 95 - 192 ( 2000 ). http://doi.org/10.1016/S0370-1573(99)00109-X http://doi.org/10.1016/S0370-1573(99)00109-X

O. Jagutzki et al. , Multiple hit readout of a microchannel plate detector with a three-layer delay-line anode . IEEE Trans. Nucl. Sci. 49 , 2477 - 2483 ( 2002 ). http://doi.org/10.1109/TNS.2002.803889 http://doi.org/10.1109/TNS.2002.803889

J. Ullrich et al. , Recoil-ion and electron momentum spectroscopy: reaction-microscopes . Rep. Prog. Phys. 66 , 1463 - 1545 ( 2003 ). http://doi.org/10.1088/0034-4885/66/9/203 http://doi.org/10.1088/0034-4885/66/9/203

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