1.Moscow Center for Advanced Studies, Kulakova str. 20, Moscow 123592, Russia
2.Emerging Technologies Research Center, XPANCEO, Internet City, Emmay Tower, Dubai, United Arab Emirates
3.Donostia International Physics Center (DIPC), Donostia/San-Sebastián 20018, Spain
4.Institute of Materials, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland
5.Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia
6.Laboratory of Advanced Functional Materials, Yerevan State University, Yerevan 0025, Armenia
7.National Graphene Institute (NGI), University of Manchester, Manchester M13 9PL, UK
8.Department of Materials Science and Engineering, National University of Singapore, Singapore 03-09 EA, Singapore
9.Institute for Functional Intelligent Materials, National University of Singapore, 117544 Singapore, Singapore
Kostya S. Novoselov (kostya@nus.edu.sg)
收稿日期:2023-09-20,
修回日期:2024-01-22,
录用日期:2024-02-01,
网络出版日期:2024-03-08,
纸质出版日期:2024-04-30
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Exploring van der Waals materials with high anisotropy: geometrical and optical approaches[J]. LSA, 2024,13(4):645-653.
Slavich, A. S. et al. Exploring van der Waals materials with high anisotropy: geometrical and optical approaches. Light: Science & Applications, 13, 645-653 (2024).
Exploring van der Waals materials with high anisotropy: geometrical and optical approaches[J]. LSA, 2024,13(4):645-653. DOI: 10.1038/s41377-024-01407-3.
Slavich, A. S. et al. Exploring van der Waals materials with high anisotropy: geometrical and optical approaches. Light: Science & Applications, 13, 645-653 (2024). DOI: 10.1038/s41377-024-01407-3.
The emergence of van der Waals (vdW) materials resulted in the discovery of their high optical
mechanical
and electronic anisotropic properties
immediately enabling countless novel phenomena and applications. Such success inspired an intensive search for the highest possible anisotropic properties among vdW materials. Furthermore
the identification of the most promising among the huge family of vdW materials is a challenging quest requiring innovative approaches. Here
we suggest an easy-to-use method for such a survey based on the crystallographic geometrical perspective of vdW materials followed by their optical characterization. Using our approach
we found As
2
S
3
as a highly anisotropic vdW material. It demonstrates high in-plane optical anisotropy that is ~20% larger than for rutile and over two times as large as calcite
high refractive index
and transparency in the visible range
overcoming the century-long record set by rutile. Given these benefits
As
2
S
3
opens a pathway towards next-generation nanophotonics as demonstrated by an ultrathin true zero-order quarter-wave plate that combines classical and the Fabry–Pérot optical phase accumulations. Hence
our approach provides an effective and easy-to-use method to find vdW materials with the utmost anisotropic properties.
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