Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments

Xulong Lv; Yanjie Liang; Yi Zhang; Dongxun Chen; Xihui Shan; Xiao-jun Wang

doi:10.1038/s41377-024-01533-y

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Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments

Original Articles

- Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments
- Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments
- LSA 2024年13卷第11期页码：2634-2648
- Affiliations：
  
  1.Key Laboratory for Liquid-Solid Structure Evolution and Processing of Materials, Shandong University, Jinan 250061, China
  2.Department of Physics, Georgia Southern University, Statesboro, GA 30460, USA
- Author bio：
  
  Yanjie Liang (yanjie.liang@sdu.edu.cn)
  Xiao-Jun Wang (xwang@georgiasouthern.edu)
- Funds：
- DOI：10.1038/s41377-024-01533-y
  中图分类号：
- 收稿日期：2024-03-12，
  
  修回日期：2024-07-11，
  
  录用日期：2024-07-15，
  
  网络出版日期：2024-09-14，
  
  纸质出版日期：2024-11-30
- Accepted：
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Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments[J]. LSA, 2024,13(11):2634-2648.

Lv, X. L. et al. Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments. Light: Science & Applications, 13, 2634-2648 (2024).
Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments[J]. LSA, 2024,13(11):2634-2648. DOI： 10.1038/s41377-024-01533-y.

Lv, X. L. et al. Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments. Light: Science & Applications, 13, 2634-2648 (2024). DOI： 10.1038/s41377-024-01533-y.

摘要

Abstract

Extensive research has been conducted on visible-light and longer-wavelength infrared-light storage phosphors

which are utilized as promising rewritable memory media for optical information storage applications in dark environments. However

storage phosphors emitting in the deep ultraviolet spectral region (200–300 nm) are relatively lacking. Here

we report an appealing deep-trap ultraviolet storage phosphor

ScBO

:Bi

which exhibits an ultra-narrowband light emission centered at 299 nm with a full width at half maximum (FWHM) of 0.21

eV and excellent X-ray energy storage capabilities. When persistently stimulated by longer-wavelength white/NIR light or heated at elevated temperatures

ScBO

:Bi

phosphor exhibits intense and long-lasting ultraviolet luminescence due to the interplay between defect levels and external stimulus

while the natural decay in the dark at room temperature is extremely weak after X-ray irradiation. The impact of the spectral distribution and illuminance of ambient light and ambient temperature on ultraviolet light emission has been studied by comprehensive experimental and theoretical investigations

which elucidate that both O vacancy and Sc interstitial serve as deep electron traps for enhanced and prolonged ultraviolet luminescence upon continuous optical or thermal stimulation. Based on the unique spectral features and trap distribution in ScBO

:Bi

phosphor

controllable optical information read-out is demonstrated via external light or heat manipulation

highlighting the great potential of ScBO

:Bi

phosphor for advanced optical storage application in bright environments.

关键词

Keywords

references

Gu, M., Li, X. P. & Cao, Y. Y. Optical storage arrays: aperspective for future big data storage. Light Sci. Appl. 3 , e177 (2014)..

Lin, S. S. et al. High-security-level multi-dimensional optical storage medium: nanostructured glass embedded with LiGa 5 O 8 : Mn 2+ with photostimula ted luminescence. Light Sci. Appl. 9 , 22 (2020)..

Sang, J. K. et al. Multilevel static−dynamic anticounterfeiting based on stimuli-responsive luminescence in a niobate structure. ACS Appl. Mater. Interfaces 11 , 20150–20156 (2019)..

Ding, M. Y. et al. Energy manipulation in lanthanide-doped core-shell nanoparticles for tunable dual-mode luminescence toward advanced anti-counterfeiting. Adv. Mater. 32 , 2002121 (2020)..

Zhang, Y. et al. Multimodal luminescence in Pr 3+ single-doped Li 2 CaSiO 4 phosphor for optical information storage and anti-counterfeiting applications. Chem. Eng. J. 474 , 145886 (2023)..

Zhuang, Y. X. et al. Optical data storage and multicolor emission readout on flexible films using deep-trap persistent luminescence materials. Adv. Funct. Mater. 28 , 1705769 (2018)..

Long, Z. W. et al. No-interference reading for optical information storage and ultra-multiple anti-counterfeiting applications by designing targeted recombination in charge carrier trapping phosphors. Adv. Opt. Mater. 7 , 1900006 (2019)..

Zhuang, Y. X. et al. X-ray-charged bright persistent luminescence in NaYF 4 : Ln 3+ @NaYF 4 nanoparticles for multidimensional optical information storage. Light Sci. Appl. 10 , 132 (2021)..

Xiao, D. W. et al. Large reversible upconversion luminescence modification and 3D optical information storage in femtosecond laser irradiation-subjected photochromic glass. Sci. China Mater. 65 , 1586–1593 (2022)..

Li, Y., Gecevicius, M. & Qiu, J. R. Long persistent phosphors-from fundamentals to applications. Chem. Soc. Rev. 45 , 2090–2136 (2016)..

Li, X. et al. Ultraviolet glow of Lu 3 Ga 5 O 12 :Bi 3+ phosphor in indoor lighting. J. Lumin. 248 , 118932 (2022)..

Zhao, X. Y. et al. Emission from storage phosphors that glow even in bright ambient light. Phys. Rev. Appl. 15 , 064039 (2021)..

Li, L. P. et al. Mechanism of the trivalent la nthanides' persistent luminescence in wide bandgap materials. Light Sci. Appl. 11 , 51 (2022)..

Huang, K. et al. Designing next generation of persistent luminescence: recent advances in uniform persistent luminescence nanoparticles. Adv. Mater. 34 , 2107962 (2022)..

Suo, H., Zhang, X. & Wang, F. Controlling X-ray-activated persistent luminescence for emerging applications. Trends Chem. 4 , 726–738 (2022)..

Fan, X. T. et al. Recent developments and progress of inorganic photo-stimulated phosphors. J. Rare Earths 37 , 679–690 (2019)..

Gao, Y. et al. Broadband NIR photostimulated luminescence nanoprobes based on CaS: Eu 2+ , Sm 3+ nanocrystals. Chem. Sci. 10 , 5452–5460 (2019)..

Yuan, L. F. et al. Optically stimulated luminescence phosphors: principles, applications, and prospects. Laser Photonics Rev. 14 , 2000123 (2020)..

Van der Heggen, D. et al. Persistent luminescence in strontium aluminate: a roadmap to a brighter future. Adv. Funct. Mater. 32 , 2208809 (2022)..

Peng, Q. P. et al. Up-converted long persistent luminescence from CsPbBr 3 nanocrystals in glass. Laser Photonics Rev. 16 , 2200449 (2022)..

Liang, L. L. et al. Controlling persistent luminescence in nanocrystalline phosphors. Nat. Mater. 22 , 289–304 (2023)..

Giordano, L. et al. Persistent luminescence induced by upconversion: an alternative approach for rechargeable bio-emitters. Adv. Opt. Mater. 11 , 2201468 (2023)..

Wang, C. L. et al. Trap distribution tailoring guided design of super-long-persistent phosphor Ba 2 SiO 4 :Eu 2+ , Ho 3+ and photostimulable luminescence for optical information storage. J. Mater. Chem. C. 6 , 6058–6067 (2018)..

Chen, W. et al. Structure and luminescence of BaFBr: Eu 2+ and BaFBr: Eu 2+ , Tb 3+ phosphors and thin films. J. Appl. Phys. 97 , 083506 (2005)..

Wang, J. et al. Enhanced photoluminescence and phosphorescence properties of red CaAlSiN 3 :Eu 2+ phosphor via simultaneous UV-NIR stimulation. J. Mater. Chem. C. 3 , 4445–4451 (2015)..

Liu, F. et al. Photostimulated near-infrared persistent luminescence as a new optical read-out from Cr 3+ -doped LiGa 5 O 8 . Sci. Rep. 3 , 1554 (2013)..

Liu, D. et al. Tailoring multidimensional traps for rewritable multilevel optical data storage. ACS Appl. Mater. Interfaces 11 , 35023–35029 (2019)..

Zhang, Y. et al. Triple-mode emissions with invisible near-infrared after-glow from Cr 3+ -doped zinc aluminum germanium nanoparticles for advanced anti-counterfeiting applications. Small 16 , 2003121 (2020)..

Hu, R. et al. UV-Vis-NIR broadband-photostimulated luminescence of LiTaO 3 :Bi 3+ long-persistent phosphor and the optical storage properties. Chem. Eng. J. 392 , 124807 (2020)..

Tian, S. Y. et al. Red photo-stimulated luminescence from deep traps of BaZrGe 3 O 9 : Pr 3+ for optical imaging application. J. Alloy. Compd. 800 , 224–230 (2019)..

Wang, C. Y. et al. Modulating trap properties by Nd 3+ -Eu 3+ co-doping in Sr 2 SnO 4 host for optical information storage. Opt. Express 28 , 4249–4257 (2020)..

Wu, H. et al. Optical storage and operation based on photostimulated luminescence. Nano Energy 90 , 106546 (2021)..

Zhang, J. M. et al. Giant enhancement of a long afterglow and optically stimulated luminescence phosphor BaCaSiO 4 :Eu 2+ via Pr 3+ codoping for optical data storage. J. Lumin. 263 , 119971 (2023)..

Wang, X. L. et al. Solar-blind ultraviolet-C persistent luminescence phosphors. Nat. Commun. 11 , 2040 (2020)..

Liu, L. et al. Disguise as fluorescent powder: ultraviolet-B persistent luminescence material without visible light for advanced information encryption and anti-counterfeiting applications. Chem. Eng. J. 430 , 132884 (2022)..

Yang, Y. M. et al. X-ray-activated long persistent phosphors featuring strong UVC afterglow emissions. Light Sci. Appl. 7 , 88 (2018)..

Wang, X. L. et al. Gd 3+ -activated narrowband ultraviolet-B persistent luminescence through persistent energy transfer. Dalton Trans. 50 , 3499–3505 (2021)..

Sun, L. L. et al. Bi-induced photochromism and photo-stimulated luminescence with fast photochromic response for multi-mode dynamic anti-counterfeiting and optical information storage. Chem. Eng. J. 455 , 140752 (2023)..

Wei, Y. et al. New strategy for designing orangish-red-emitting phosphor via oxygen-vacancy-induced electronic localization. Light Sci. Appl. 8 , 15 (2019)..

Wei, Y. et al. Abnormal Bi 3+ -activated NIR emission in highly symmetric XAl 12 O 19 (X = Ba, Sr, Ca) by selective sites occupation. Chem. Mater. 32 , 8747–8753 (2020)..

Feng, Z. Y. et al. First-principles study of Bi 3+ -related luminescence and electron and hole traps in (Y/Lu/La)PO 4 . Inorg. Chem. 60 , 4434–4446 (2021)..

Wang, C. et al. Te 4+ /Bi 3+ co-doped double perovskites with tunable dual-emission for contactless light sensor, encrypted information transmission and white light emitting diodes. Chem. Eng. J. 431 , 134135 (2022)..

Tang, Y. M. et al. Bismuth-activated persistent phosphors. Adv. Opt. Mater. 11 , 2201827 (2023)..

Liu, L. et al. Developing dual-mode material with ultraviolet and visible persistent luminescence for multi-mode anti-counterfeiting and information encryption. Inorg. Chem. Front. 10 , 3131–3138 (2023)..

Boutinaud, P. Luminescence-structure relationships in solids doped with Bi 3+ . Phys. Chem. Chem. Phys. 25 , 11027–11054 (2023)..

Zhou, Z. H. et al. Rechargeable and sunlight-activated Sr 3 Y 2 Ge 3 O 12 :Bi 3+ UV-Visible-NIR persistent luminescence material for night-vision signage and optical information storage. Chem. Eng. J. 421 , 127820 (2021)..

Zhang, Y. et al. Long-lasting ultraviolet-A persistent luminescence and photostimulated persistent luminescence in Bi 3+ -doped LiScGeO 4 phosphor. Inorg. Chem. Front. 7 , 3063–3071 (2020)..

Zhou, Z. H. et al. Ultraviolet-A persistent luminescence of a Bi 3+ -activated LiScGeO 4 material. Inorg. Chem. 59 , 12920–12927 (2020)..

Lai, S. F. et al. Investigation of persistent luminescence property of Bi 3+ , Dy 3+ co-doped CdSiO 3 phosphor. Mater. Res. Bull. 60 , 714–718 (2014)..

Liu, B. M. et al. X-ray-activated, UVA persistent luminescent materials based on Bi-doped SrLaAlO 4 for deep-Seated photodynamic activation. J. Appl. Phys. 129 , 120901 (2021)..

Shao, P. S. et al. Novel spectral band: ultraviolet A mechanoluminescence from Bi 3+ -doped LiYGeO 4 . J. Mater. Chem. C. 10 , 16670–16678 (2022)..

Wang, X. L. & Mao, Y. B. Emerging ultraviolet persistent luminescent materials. Adv. Opt. Mater. 10 , 2201466 (2022)..

Qiao, Z. et al. Exploring intrinsic electron-trapping centers for persistent luminescence in Bi 3+ -doped LiREGeO 4 (RE = Y, Sc, Lu): mechanistic origin from first-principles calculations. Inorg. Chem. 60 , 16604–16613 (2021)..

Lyu, T. S. & Dorenbos, P. Bi 3+ acting both as an electron and as a hole trap in La-, Y-, and LuPO 4 . J. Mater. Chem. C. 6 , 6240–6249 (2018)..

Zhang, S. Y. et al. An improved method to evaluate trap depth from thermoluminescence. J. Rare Earths https://doi.org/10.1016/j.jre.2024.02.004 (2024).

Ou, X. Y. et al. High-resolution X-ray luminescence extension imaging. Nature 590 , 410–415 (2021)..

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