A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells

Yue Wang; Wen Xu; Haichun Liu; Yuhan Jing; Donglei Zhou; Yanan Ji; Jerker Widengren; Xue Bai; Hongwei Song

doi:10.1038/s41377-024-01661-5

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A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells

Original Articles

- A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells
- A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells
- LSA 2024年13卷第12期页码：3261-3271
- Affiliations：
  
  1.State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, 130012 Changchun, China
  2.Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, School of Physics and Materials Engineering, Dalian Minzu University, Dalian 116600, China
  3.Department of Applied Physics, KTH Royal Institute of Technology, SE-106 91 Stockholm, Sweden
- Author bio：
  
  Wen Xu (xuwen@dlnu.edu.cn)
  Hongwei Song (songhw@jlu.edu.cn)
- Funds：
- DOI：10.1038/s41377-024-01661-5
  中图分类号：
- 收稿日期：2024-05-26，
  
  修回日期：2024-10-08，
  
  录用日期：2024-10-12，
  
  网络出版日期：2024-11-25，
  
  纸质出版日期：2024-12-31
- Accepted：
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A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells[J]. LSA, 2024,13(12):3261-3271.

Wang, Y. et al. A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells. Light: Science & Applications, 13, 3261-3271 (2024).
A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells[J]. LSA, 2024,13(12):3261-3271. DOI： 10.1038/s41377-024-01661-5.

Wang, Y. et al. A multiband NIR upconversion core-shell design for enhanced light harvesting of silicon solar cells. Light: Science & Applications, 13, 3261-3271 (2024). DOI： 10.1038/s41377-024-01661-5.

摘要

Abstract

Exploring lanthanide light upconversion (UC) has emerged as a promising strategy to enhance the near-infrared (NIR) responsive region of silicon solar cells (SSCs). However

its practical application under normal sunlight conditions has been hindered by the narrow NIR excitation bandwidth and the low UC efficiency of conventional materials. Here

we report the design of an efficient multiband UC system based on Ln

/Yb

-doped core-shell upconversion nanoparticles (Ln/Yb-UCNPs

= Ho

). In our design

ions are incorporated into distinct layers of Ln/Yb-UCNPs to function as near-infrared (NIR) absorbers across different spectral ranges. This design achieves broad multiband absorption withtin the 1100 to 2200 nm range

with an aggregated bandwidth of ~500 nm. We have identified a synthetic electron pumping (SEP) effect involving Yb

ions

facilitated by the synergistic interplay of energy transfer and cross-relaxation between Yb

and other ions Ln

(Ho

). This SEP effect enhances the UC efficiency of the nanomaterials by effectively transferring electrons from the low-excited states of Ln

to the excited state of Yb

resulting in intense Yb

luminescence at ~980 nm within the optimal response region for SSCs

thus markedly improving their overall performance. The SSCs integrated with Ln/Yb-UCNPs with multiband excitation demonstrate the largest reported NIR response range up to 2200 nm

while enabling the highest imp

rovement in absolute photovoltaic efficiency reported

with an increase of 0.87% (resulting in a total efficiency of 19.37%) under standard AM 1.5 G irradiation. Our work tackles the bottlenecks in UCNP-coupled SSCs and introduces a viable approach to extend the NIR response of SSCs.

关键词

Keywords

references

Holzhey, P. et al. Toward commercialization with lightweight, flexible perovskite solar cells for residential photovoltaics. Joule 7 , 257–271, https://doi.org/10.1016/j.joule.2022.12.012 (2023)..

Li, W. J. et al. High-performance solar flow battery powered by a perovskite/silicon tandem solar cell. Nat. Mater. 19 , 1326–1331, https://doi.org/10.1038/s41563-020-0720-x (2020)..

Zhang, C. Y. et al. Ti 1 –graphene single-atom material for improved energy level alignment in perovskite solar cells. Nat. Energy 6 , 1154–1163, https://doi.org/10.1038/s41560-021-00944-0 (2021)..

Ballif, C. et al. Status and perspectives of crystalline silicon photovoltaics in research and industry. Nat. Rev. Mater. 7 , 597–616, https://doi.org/10.1038/s41578-022-00423-2 (2022)..

Köhler, M. et al. A silicon carbide-based highly transparent passivating contact for crystalline silicon solar cells approaching efficiencies of 24%. Nat. Energy 6 , 529–537, https://doi.org/10.1038/s41560-021-00806-9 (2021)..

Lin, H. et al. Silicon heterojunction solar cells with up to 26.81% efficiency achieved by electrically optimized nanocrystalline-silicon hole contact layers. Nat. Energy 8 , 789–799, https://doi.org/10.1038/s41560-023-01255-2 (2023)..

Liu, W. Z. et al. Flexible solar cells based on foldable silicon wafers with blunted edges. Nature 617 , 717–723, https://doi.org/10.1038/s41586-023-05921-z (2023)..

Yoshikawa, K. et al. Silicon heterojunction solar cell with interdigitated back con tacts for a photoconversion efficiency over 26%. Nat. Energy 2 , 17032, https://doi.org/10.1038/nenergy.2017.32 (2017)..

Yu, Z. S., Leilaeioun, M. & Holman, Z. Selecting tandem partners for silicon solar cells. Nat. Energy 1 , 16137, https://doi.org/10.1038/nenergy.2016.137 (2016)..

Huang, X. Y. et al. Enhancing solar cell efficiency: the search for luminescent materials as spectral converters. Chem. Soc. Rev. 42 , 173–201, https://doi.org/10.1039/c2cs35288e (2013)..

Zhou, D. L. et al. Cerium and ytterbium codoped halide perovskite quantum dots: a novel and efficient downconverter for improving the performance of silicon solar cells. Adv. Mater. 29 , 1704149, https://doi.org/10.1002/adma.201704149 (2017)..

Zhou, D. L. et al. Impact of host composition, codoping, or tridoping on quantum-cutting emission of ytterbium in halide perovskite quantum dots and solar cell applications. Nano Lett. 19 , 6904–6913, https://doi.org/10.1021/acs.nanolett.9b02139 (2019)..

Green, M. A. et al. Solar cell efficiency tables (version 52). Prog. Photovolt. Res. Appl. 26 , 427–436, https://doi.org/10.1002/pip.3040 (2018)..

Cheema, H., Rodrigues, R. R. & Delcamp, J. H. Sequential series multijunction dye-sensitized solar cells (SSM-DSCs): 4.7 volts from a single illuminated area. Energy Environ. Sci. 10 , 1764–1769, https://doi.org/10.1039/c7ee01526G (2017)..

Chin, X. Y. et al. Interface passivation for 31.25%-efficient perovskite/silicon tandem solar cells. Science 381 , 59–63, https://doi.org/10.1126/science.adg0091 (2023)..

Aydin, E. et al. Enhanced optoelectronic coupling for perovskite/silicon tandem solar cells. Nature 623 , 732–738, https://doi.org/10.1038/s41586-023-06667-4 (2023)..

Mariotti, S. et al. Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells. Science 381 , 63–69, https://doi.org/10.1126/science.adf5872 (2023)..

Fischer, S. et al. Record efficient upconverter solar cell devices with optimized bifacial silicon solar cells and monocrystalline BaY 2 F 8 : 30% Er 3+ upconverter. Sol. Energy Mater. Sol. Cells 136 , 127–134, https://doi.org/10.1016/j.solmat.2014.12.023 (2015)..

Fischer, S. et al. Absolute upconversion quantu m yield of β -NaYF 4 doped with Er 3+ and external quantum efficiency of upconverter solar cell devices under broad-band excitation considering spectral mismatch corrections. Sol. Energy Mater. Sol. Cells 122 , 197–207, https://doi.org/10.1016/j.solmat.2013.12.001 (2014)..

Fischer, S. et al. Enhancement of silicon solar cell efficiency by upconversion: optical and electrical characterization. J. Appl. Phys. 108 , 044912, https://doi.org/10.1063/1.3478742 (2010)..

Fischer, S. et al. Upconverter silicon solar cell devices for efficient utilization of sub-band-gap photons under concentrated solar radiation. IEEE J. Photovolt. 4 , 183–189, https://doi.org/10.1109/jphotov.2013.2282744 (2014)..

Fischer, S. et al. Upconversion solar cell measurements under real sunlight. Opt. Mater. 84 , 389–395, https://doi.org/10.1016/j.optmat.2018.05.072 (2018)..

Fuentes, S. et al. Upconversion of Bi 4 Ti 3 O 12 : Er and its evaluation in silicon solar cell yield. Mater. Lett. 296 , 129889, https://doi.org/10.1016/j.matlet.2021.129889 (2021)..

Ghazy, A. et al. Luminescent (Er, Ho) 2 O 3 thin films by ALD to enhance the perf ormance of silicon solar cells. Sol. Energy Mater. Sol. Cells 219 , 110787, https://doi.org/10.1016/j.solmat.2020.110787 (2021)..

Tockhorn, P. et al. Nano-optical designs for high-efficiency monolithic perovskite–silicon tandem solar cells. Nat. Nanotechnol. 17 , 1214–1221, https://doi.org/10.1038/s41565-022-01228-8 (2022)..

Xu, Q. J. et al. Conductive passivator for efficient monolithic perovskite/silicon tandem solar cell on commercially textured silicon. Adv. Energy Mater. 12 , 2202404, https://doi.org/10.1002/aenm.202202404 (2022)..

Chen, B. et al. Blade-coatedperovskites on textured silicon for 26%-efficient monolithic perovskite/silicon tandem solar cells. Joule 4 , 850–864, https://doi.org/10.1016/j.joule.2020.01.008 (2020)..

Li, R. J. et al. CsPbCl 3 ‐cluster‐widened bandgap and inhibited phase segregation in a wide‐bandgap perovskite and its application to NiO x -based perovskite/silicon tandem solar cells. Adv. Mater. 34 , 2201451, https://doi.org/10.1002/adma.202201451 (2022)..

Crane, M. J.,Kroupa, D. M. & Gamelin, D. R. Detailed-balance analysis of Yb 3+ : CsPb(Cl 1− x Br x ) 3 quantum-cutting layers for high-efficiency photovoltaics under real-world conditions. Energy Environ. Sci. 12 , 2486–2495, https://doi.org/10.1039/c9ee01493d (2019)..

Liang, L. L. et al. Continuous-wave near-infrared stimulated-emission depletion microscopy using downshifting lanthanide nanoparticles. Nat. Nanotechnol. 16 , 975–980, https://doi.org/10.1038/s41565-021-00927-y (2021)..

Xu, H. et al. Anomalous upconversion amplification induced by surface reconstruction in lanthanide sublattices. Nat. Photonics 15 , 732–737, https://doi.org/10.1038/s41566-021-00862-3 (2021)..

Liu, X. et al. Near-infrared manipulation of multiple neuronal populations via trichromatic upconversion. Nat. Commun. 12 , 5662, https://doi.org/10.1038/s41467-021-25993-7 (2021)..

Zhou, B. et al. NIR II-responsive photon upconversion through energy migration in an ytterbium sublattice. Nat. Photonics 14 , 760–766, https://doi.org/10.1038/s41566-020-00714-6 (2020)..

Ji, Y. N. et al. Huge upconversion luminescence enhancement by a cascade optical field modulation strategy facilitating selective multispectral narrow-band near-infrared photodetection. Light Sci. Appl. 9 , 184, https://doi.org/10.1038/s41377-020-00418-0 (2020)..

Kotulska, A. M. et al. Upconversion FRET quantitation: the role of donor photoexcitation mode and compositional architecture on the decay and intensity based responses. Light Sci. Appl. 11 , 256, https://doi.org/10.1038/s41377-022-00946-x (2022)..

Xie, Y. et al. Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage. Light Sci. Appl. 11 , 150, https://doi.org/10.1038/s41377-022-00813-9 (2022)..

Richards, B. S. et al. Photon upconversion for photovoltaics and photocatalysis: a critical review. Chem. Rev. 121 , 9165–9195, https://doi.org/10.1021/acs.chemrev.1c00034 (2021)..

Ivanova, S. et al. Upconversion luminescence dynamics of Er-doped fluoride crystals for optical converters. J. Lumin. 128 , 914–917, https://doi.org/10.1016/j.jlumin.2007.11.031 (2008)..

Adikaari, A. A. D. et al. Near infrared up-conversion in organic photovoltaic devices using an efficient Yb 3+ : Ho 3+ Co-doped Ln 2 BaZnO 5 (Ln = Y, Gd) phosphor. J. Appl. Phys. 111 , 094502, https://doi.org/10.1063/1.4704687 (2012)..

de Wild, J. et al. Towards upconversion for amorphous silicon solar cells. Sol. Energy Mater. Sol. Cells 94 , 1919–1922, https://doi.org/10.1016/j.solmat.2010.06.006 (2010)..

Zhang, J. H. et al. Observation of efficient population of the red-emitting state from the green state by non-multiphonon relaxation in the Er 3+ –Yb 3+ system. Light Sci. Appl. 4 , e239, https://doi.org/10.1038/lsa.2015.12 (2015)..

Zhan, Q. Q. et al. Achieving high-efficiency emission depletion nanoscopy by employing cross relaxation in upconversion nanoparticles. Nat. Commun. 8 , 1058, https://doi.org/10.1038/s41467-017-01141-y (2017)..

Shao, W. et al. Lanthanide-doped fluoride core/multishell nanoparticles for broadband upconversion of infrared light. Adv. Opt. Mater. 3 , 575–582, https://doi.org/10.1002/adom.201400404 (2015)..

Zhao, S. L. et al. Er 3+ /Yb 3+ codoped oxyfluoride borosilicate glass ceramic containing NaYF 4 nanocrystals for amorphous silicon solar cells. Mater. Lett. 65 , 2407–2409, https://doi.org/10.1016/j.matlet.2011.04.084 (2011)..

Zhang, X. D. et al. Synthesis of NaYF 4 : Yb, Er nanocrystals and its application in silicon thin film solar cells. Phys. Status Solidi C 7 , 1128–1131, https://doi.org/10.1002/pssc.200982762 (2010)..

Wang, F., Wang, J. & Liu, X. G. Direct evidence of a surface quenching effect on size-dependent luminescence of upconversion nanoparticles. Angew. Chem. Int. Ed. 49 , 7456–7460, https://doi.org/10.1002/anie.201003959 (2010)..

Sun, T. Y. et al. Ultralarge anti-stokes lasing through tandem upconversion. Nat. Commun. 13 , 1032, https://doi.org/10.1038/s41467-022-28701-1 (2022)..

Zhong, Y. T. et al. Boosting the down-shifting luminescence of rare-earth nanocrystals for biological imaging beyond 1500 nm. Nat. Commun. 8 , 737, https://doi.org/10.1038/s41467-017-00917-6 (2017)..

Shang, Y. F. et al. Low threshold lasing emissions from a single upconversion nanocrystal. Nat. Commun. 11 , 6156, https://doi.org/10.1038/s41467-020-19797-4 (2020)..

Sun, T. Y. et al. Integrating temporal and spatial control of electronic transitions for bright multiphoton upconversion. Nat. Commun. 10 , 1811, https://doi.org/10.1038/s41467-019-09850 -2 (2019)..

Yu, D. C. et al. Efficient first-order resonant near-infrared quantum cutting in β -NaYF 4 : Ho 3+ , Yb 3+ . J. Alloy. Compd. 509 , 9919–9923, https://doi.org/10.1016/j.jallcom.2011.07.088 (2011)..

Lahoz, F. et al. Upconversion mechanisms in rare-earth doped glasses to improve the efficiency of silicon solar cells. Sol. Energy Mater. Sol. Cells 95 , 1671–1677, https://doi.org/10.1016/j.solmat.2011.01.027 (2011)..

Fuhua, H. H. et al. Suppression of cation intermixing highly boosts the performance of core–shell lanthanide upconversion nanoparticles. J. Am. Chem. Soc. 145 , 17621–17631, https://doi.org/10.1021/jacs.3c03019 (2023)..

Liu, H. C. et al. Balancing power density based quantum yield characterization of upconverting nanoparticles for arbitrary excitation intensities. Nanoscale 5 , 4770–4775, https://doi.org/10.1039/c3nr00469D (2013)..

Khenkin, M. V. et al. Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures. Nat. Energy 5 , 35–49, https://doi.org/10.1038/s41560-019-0529-5 (2020)..

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