Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal

Hao Suo; Nan Wang; Yu Zhang; Xin Zhang; Jinmeng Xiang; Xiaojia Wang; Guansheng Xing; Dongxu Guo; Jiwen Chang; Yu Wang; Panlai Li; Zhijun Wang; Yuhai Zhang; Bing Chen; Shuzhou Li; Chongfeng Guo; Feng Wang

doi:10.1038/s41377-024-01689-7

Go to Nature Website

Your Location：

Home >

Browse articles >

Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal

Original Articles

- Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal
- Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal
- LSA 2025年14卷第1期页码：186-196
- Affiliations：
  
  1.Hebei Key Laboratory of Optic-electronic Information and Materials, College of Physics Science & Technology, Hebei University, Baoding 071002, China
  2.Department of Materials Science and Engineering, City University of Hong Kong, Kowloon 999077 Hong Kong SAR, China
  3.State Key Laboratory of Photon-Technology in Western China Energy, Institute of Photonics & PhotonTechnology, Northwest University, Xi'an 710127, China
  4.Institute for Advanced Interdisciplinary Research, University of Jinan, Jinan, Shandong 250022, China
  5.College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing 210023, China
  6.School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore
- Author bio：
  
  Hao Suo (suo@hbu.edu.cn)
  Chongfeng Guo (guocf@nwu.edu.cn)
  Feng Wang (fwang24@cityu.edu.hk)
- Funds：
- DOI：10.1038/s41377-024-01689-7
  中图分类号：
- 纸质出版日期：2025-01-31，
  
  网络出版日期：2025-01-02，
  
  收稿日期：2024-09-11，
  
  修回日期：2024-11-12，
  
  录用日期：2024-11-12
- Accepted：
Scan QR Code
Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal[J]. LSA, 2025,14(1):186-196.

Suo, H. et al. Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal. Light: Science & Applications, 14, 186-196 (2025).
Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal[J]. LSA, 2025,14(1):186-196. DOI： 10.1038/s41377-024-01689-7.

Suo, H. et al. Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal. Light: Science & Applications, 14, 186-196 (2025). DOI： 10.1038/s41377-024-01689-7.

摘要

Abstract

Low-dimensional lead-free metal halide perovskites are highly attractive for cutting-edge optoelectronic applications. Herein

we report a class of scandium-based double perovskite crystals comprising antimony dopants that can generate multiexcitonic emissions in the ultraviolet

blue

and yellow spectral regions. Owing to the zero-dimensional nature of the crystal lattice that minimizes energy crosstalk

different excitonic states in the crystals can be selectively excited by ultraviolet light

X-ray irradiation

and mechanical action

enabling dynamic control of steady/transient-state spectral features by modulating the excitation modes. Remarkably

the transparent crystal exhibits highly efficient white photoluminescence (quantum yield > 97%)

X-ray excited blue emission with long afterglow (duration > 9 h)

and high-brightness self-reproducible violet-blue mechanoluminescence. These findings reveal the exceptional capability of low-dimensional perovskite crystals for integrating various excitonic luminescence

offering exciting opportunities for multi-level data encryption and all-in-one authentication technologies.

关键词

Keywords

references

Wang, C. et al. Heartbeat-sensing mechanoluminescent device based on a quantitative relationship between pressure and emissive intensity. Matter 2 , 181–193 (2020)..

Xiao, H. et al. Core-shell structured upconversion/lead-free perovskite nanoparticles for anticounterfeiting applications. Angew. Chem. Int. Ed. 61 , e202115136 (2022)..

Li, D. et al. Stimulus-responsive room temperature phosphorescence materials with full-color tunability from pure organic amorphous polymers. Sci. Adv. 8 , eabl8392 (2022)..

Wu, Y. M. et al. Dynamic upconversion multicolour editing enabled by molecule-assisted opto-electrochemical modulation. Nat. Commun. 12 , 2022 (2021)..

Suo, H. et al. Ultrasensitive colorimetric luminescence thermometry by progressive phase transition. Adv. Sci. 11 , 2305241 (2024)..

Zheng, B. Z. et al. Rare-earth doping in nanostructured inorganic materials. Chem. Rev. 122 , 5519–5603 (2022)..

Zhou, X. Q. et al. Interplay of defect levels and rare earth emission centers in multimode luminescent phosphors. Nat. Commun. 13 , 7589 (2022)..

Zhang, X. et al. Continuous tuning of persistent luminescence wavelength by intermediate-phase engineering in inorganic crystals. Nat. Commun. 15 , 6797 (2024)..

Tang, Y. Q. et al. Dynamic multicolor emissions of multimodal phosphors by Mn 2+ trace doping in self-activated CaGa 4 O 7 . Nat. Commun. 15 , 3209 (2024)..

Suo, H. et al. A broadband near-infrared nanoemitter powered by mechanical action. Matter 6 , 2935–2949 (2023)..

Liang, L. L. et al. Controlling persistent luminescence in nanocrystalline phosphors. Nat. Mater. 22 , 289–304 (2023)..

Huang, K. et al. Designing next generation of persistent luminescence: recent advances in uniform persistent luminescence nanoparticles. Adv. Mater. 34 , 2107962 (2021)..

Luo, J. J. et al. Efficient and stable emission of warm-white light from lead-free halide double perovskites. Nature 563 , 541–545 (2018)..

Folgueras, M. C. et al. High-entropy halide perovskite single crystals stabilized by mild chemistry. Nature 621 , 282–288 (2023)..

He, C. L. et al. Room temperature circularly polarized emission in perovskite nanocrystals through bichiral-molecule-induced lattice reconstruction. Matter 7 , 475–484 (2024)..

Zhou, B. et al. Self-trapped exciton emission in highly polar 0D hybrid ammonium/hydronium-based perovskites triggered by antimony doping. J. Am. Chem. Soc. 146 , 15198–15208 (2024)..

Liao, J. F. et al. Achieving near-unity red light photoluminescence in antimony halide crystals via polyhedron regulation. Angew. Chem. Int. Ed. 63 , e202404100 (2024)..

Bai, W. H. et al. Ligand engineering enables efficient pure red tin-based perovskite light-emitting diodes. Angew. Chem. Int. Ed. 62 , e202312728 (2023)..

Liu, Y. et al. Near-infrared light emitting metal halides: materials, mechanisms, and applications. Adv. Mater. 36 , 2312482 (2024)..

Wang, Y. S. et al. Multimode luminescence tailoring and improvement of Cs 2 NaHoCl 6 cryolite Crystals via Sb 3+ /Yb 3+ alloying for versatile photoelectric applications. Angew. Chem. Int. Ed. 62 , e202311699 (2023)..

He, T. Y. et al. Multi-energy X-ray imaging enabled by ΔE-E telescope scintillator. Matter 7 , 2521–2535 (2024)..

Guo, Q. X. et al. Light emission of self-trapped excitons in inorganic metal halides for optoelectronic applications. Adv. Mater. 34 , 2201008 (2022)..

Li, M. Z. & Xia, Z. G. Recent progress of zero-dimensional luminescent metal halides. Chem. Soc. Rev. 50 , 2626–2662 (2021)..

Zhang, X. Z. et al. Afterglow phosphor goes transparent. J. Phys. Chem. Lett. 14 , 10003–10011 (2023)..

Zhu, C. et al. Supramolecular assembly of blue and green halide perovskites with near-unity photoluminescence. Science 383 , 86–93 (2024)..

Chen, B. et al. Multiexcitonic emission in zero-dimensional Cs 2 ZrCl 6 : Sb 3+ perovskite crystals. J. Am. Chem. Soc. 143 , 17599–17606 (2021)..

Pan, X. et al. Quantifying the interfacial triboelectricity in inorganic-organic composite mechanoluminescent materials. Nat. Commun. 15 , 2673 (2024)..

Hou, B. et al. An interactivemouthguard based on mechanoluminescence-powered optical fibre sensors for bite-controlled device operation. Nat. Electron. 5 , 682–693 (2022)..

Zhuang, Y. X. & Xie, R. J. Mechanoluminescence rebrightening the prospects of stress sensing: a review. Adv. Mater. 33 , 2005925 (2021)..

Peng, D. F. et al. A ZnS/CaZnOS heterojunction for efficient mechanical-to-optical energy conversion by conduction band offset. Adv. Mater. 32 , 1907747 (2020)..

Zhang, R. L. et al. All-inorganic rare-earth halide double perovskite single crystals with highly efficient photoluminescence. Adv. Opt. Mater. 9 , 2100689 (2021)..

Wang, X. J. et al. Nearly-unity quantum yield and 12-h afterglow from a transparent perovskite of Cs 2 NaScCl 6 : Tb. Angew. Chem. Int. Ed. 61 , e202210853 (2022)..

Smit, W. M. A., Dirksen, G. J. & Stufke ns, D. J. Infrared and Raman spectra of the elpasolites Cs 2 NaSbCl 6 and Cs 2 NaBiCl 6 : evidence for a pseudo Jahn-Teller distorted ground state. J. Phys. Chem. Solids 51 , 189–196 (1990)..

Zhang, A. R., Jin, J. C. & Xia, Z. G. Tunable luminescence of Sb 3+ doped 0D Cs 4 PbCl 6 nanocrystals from three distinct emission centers. Adv. Opt. Mater. 10 , 2200720 (2022)..

Zhou, B. et al. Achieving tunable cold/warm white-light emission in a single perovskite material with near-unity photoluminescence quantum yield. Nano-Micro Lett. 15 , 207 (2023)..

Wright, A. D. et al. Electron-phonon coupling in hybrid lead halide perovskites. Nat. Commun. 7 , 11755 (2016)..

Wang, Z. Y. et al. Boosting the self-trapped exciton emission in Cs 2 NaYCl 6 double perovskite single crystals and nanocrystals. J. Phys. Chem. Lett. 13 , 8613–8619 (2022)..

Zhang, G. D. et al. Boosting energy transfer from self-trapped exciton to Er 3+ through Sb 3+ Doping in Cs 2 Na(Lu/Er)Cl 6 double perovskites. Adv. Opt. Mater. 11 , 2202369 (2023)..

Su, B. B. et al. Highly distorted antimony(Ⅲ) chloride [Sb 2 Cl 8 ] 2− dimers for near-infrared luminescence up to 1070 nm. Angew. Chem. Int. Ed. 61 , e202208881 (2022)..

Zhou, B. et al. Efficient white photoluminescence from self-trapped excitons in Sb 3+ /Bi 3+ -Codoped Cs 2 NaInCl 6 double perovskites with tunable dual-emission. ACS Energy Lett. 6 , 3343–3351 (2021)..

Zorenko, Y. et al. Luminescent and scintillation properties of Lu 3 Al 5 O 12 : Sc single crystal and single crystalline films. Opt. Mater. 34 , 2080–2085 (2012)..

Lin, J. et al. Copper(Ⅰ)-based highly emissive all-inorganic rare-earth halide clusters. Matter 1 , 180–191 (2019)..

van den Eeckhout, K. et al. Revealing trap depth distributions in persistent phosphors. Phys. Rev. B 87 , 045126 (2013)..

van der Heggen, V. et al. Persistent luminescence in strontium aluminate: a roadmap to a brighter future. Adv. Funct. Mater. 32 , 2208809 (2022)..

Chen, B., Zhang, X. & Wang, F. Expanding the toolbox of inorganic mechanoluminescence materials. Acc. Mater. Res. 2 , 364–373 (2021)..

Xie, Y. J. & Li, Z. Triboluminescence: recalling interest and new aspects. Chem 4 , 943–971 (2018)..

Ernzerhof, M. & Scuseria, G. Assessment of the Perdew-Burke-Ernzerhof exchange-correlation functional. J. Chem. Phys. 110 , 5029–5036 (1999)..

Mopoung, K. etal. Spin centers in vanadium-doped Cs 2 NaInCl 6 halide double perovskites. ACS Mater. Lett. 6 , 566–571 (2024)..

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

暂无数据