1.National and Local United Engineering Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, 350108, Fuzhou, China
2.Wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information, Huazhong University of Science and Technology, 430074, Wuhan, China
3.Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, 350108, Fuzhou, China
Enguo Chen (ceg@fzu.edu.cn)
收稿日期:2024-04-17,
修回日期:2024-12-08,
录用日期:2025-01-02,
网络出版日期:2025-01-17,
纸质出版日期:2025-02-28
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Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays[J]. LSA, 2025,14(2):476-489.
Cai, J. H. et al. Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays. Light: Science & Applications, 14, 476-489 (2025).
Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays[J]. LSA, 2025,14(2):476-489. DOI: 10.1038/s41377-025-01742-z.
Cai, J. H. et al. Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays. Light: Science & Applications, 14, 476-489 (2025). DOI: 10.1038/s41377-025-01742-z.
Multifunctional materials have attracted tremendous attention in intelligent and interactive devices. However
achieving multi-dimensional sensing capabilities with the same perovskite quantum dot (PQD) material is still in its infancy
with some considering it currently challenging and even unattainable. Drawing inspiration from neurons
a novel multifunctional CsPbBr
3
/PDMS nanosphere is devised to se
nse humidity
temperature
and pressure simultaneously with unique interactive responses. The carefully engineered polydimethylsiloxane (PDMS) shell enables the reversible activity of the core CsPbBr
3
serving a dual role similar to dendrites in conveying and evaluating external stimuli with high sensitivity. Molecular dynamics analysis reveals that the PDMS shell with proper pore density enhances the conductivity in water and heat
imparting CsPbBr
3
with sensitive but reversible properties. By tailoring the crosslinking density of the PDMS shell
nanospheres can surprisingly show customized sensitivity and reversible responses to different level of stimuli
achieving over 95% accuracy in multi-dimensional and wide-range sensing. The regular pressure-sensitive property
discovered for the first time
is attributed to the regular morphology of the nanosphere
the inherent low rigidity of the PDMS shell
and the uniform distribution of the CsPbBr
3
core material in combination. This study breaks away from conventional design paradigms of perovskite core-shell materials by customizing the cross-linked density of the shell material. The reversible response mechanism of nanospheres with gradient shell density is deeply explored in response to environmental stimuli
which offers fresh insights into multi-dimensional sensing and interactive display applications.
Bae, G. Y. et al. Pressure/temperature sensing bimodal electronic skin with stimulus discriminability and linear sensitivity. Adv. Mater. 30 , 1803388 (2018)..
Li, S. L. et al. Geometric phase-encoded stimuli-responsive cholesteric liquid crystals for visualizing real-time remote monitoring: humidity sensing as a proof of concept. Light Sci. Appl. 13 , 27 (2024)..
Lee, W. et al. High-resolution spin-on-patterning of perovskite thin films for a multiplexed image sensor array. Adv. Mater. 29 , 1702902 (2017)..
Bao, C. X. et al. A multifunctional display based on photo-responsive perovskite light-emitting diodes. Nat. Electron. 7 , 375–382 (2024)..
Cai, J. H. et al. Water-driven photoluminescence reversibility in CsPbBr3/PDMS–PUa composite. Nano Res. 15 , 6466–6476 (2022)..
Shangguan, Z. et al. The stability of metal halide perovskite nanocrystals-a key issue for the application on quantum-dot-based micro light-emitting diodes display. Nanomaterials 10 , 1375 (2020)..
Li, G. H. et al. Stability of perovskite light sources: status and challenges. Adv. Opt. Mater. 8 , 1902012 (2020)..
Shan, Q. S. et al. Perovskite quantum dots for the next-generation displays: progress and prospect. Adv. Funct. Mater. 34 , 2401284 (2024)..
Cai, J. H. et al. Two-step performance optimization of CsPbBr3 perovskite nanocrystals for wide color gamut displays. Photonics 10 , 1113 (2023)..
Wang, R. et al. Minimizing energy barrier in intermediate connection layer for monolithic tandem WPeLEDs with wide color gamut. Adv. Funct. Mater. 33 , 2215189 (2023)..
Han, T. H. et al. A roadmap for the commercialization of perovskite light emitters. Nat. Rev. Mater. 7 , 757–777 (2022)..
Gao, Y. et al. Elimination of unstable residual lead iodide near the buried interface for the stability improvement of perovskite solar cells. Energy Environ. Sci. 16 , 2295–2303 (2023)..
Lee, K. M. et al. Enhanced efficiency and stability of quasi-2D/3D perovskite solar cells by thermal assisted blade coating method. Chem. Eng. J. 405 , 126992 (2021)..
Tien, C. H. et al. Two-dimensional (PEA)2PbBr4 perovskites sensors for highly sensitive ethanol vapor detection. Sensors 22 , 8155 (2022)..
Li, L. D. et al. Recent advances in perovskite photodetectors for image sensing. Small 17 , 2005606 (2021)..
Li, S. F. et al. Preparation of PDMS membrane using water as solvent for pervaporation separation of butanol–water mixture. Green Chem. 15 , 2180–2190 (2013)..
Yang, D. D. et al. CsPbBr3 quantum dots 2.0: benzenesulfonic acid equivalent ligand awakens complete purification. Adv. Mater. 31 , 1900767 (2019)..
Schnapf, J. L., Kraft, T. W. & Baylor, D. A. Spectral sensitivity of human cone photoreceptors. Nature 325 , 439–441 (1987)..
Bian, H. Y. et al. Stimuli-responsive memristive materials for artificial synapses and neuromorphic computing. Adv. Mater. 33 , 2006469 (2021)..
Wang, C. F. et al. Structure and photoluminescence properties of ZnS films grown on porous Si substrates. Opt. Laser Technol. 43 , 1453–1457 (2011)..
Xia, Y. F., Zeng, Y. P. & Jiang, D. L. Mechanical and dielectric properties of porous Si3N4 ceramics using PMMA as pore former. Ceram. Int. 37 , 3775–3779 (2011)..
Yang, X. L. et al. Preparation of CsPbBr3@PS composite microspheres with high stability by electrospraying. J. Mater. Chem. C 6 , 7971–7975 (2018)..
Chen, H. et al. One-step spray coating strategy toward a highly uniform large-area CsPbBr3@PMMA composite film for backlit display. Opt. Express 30 , 20241–20249 (2022)..
Meng, C. et al. Synthesis of single CsPbBr3@SiO2 core–shell particles via surface activation. J. Mater. Chem. C. 8 , 17403–17409 (2020)..
Tan, Y. S. et al. Ultrastable and reversible fluorescent perovskite films used for flexible instantaneous display. Adv. Funct. Mater. 29 , 1900730 (2019)..
Dong, H. et al. Water-triggered transformation of ligand-free lead halide perovskite nanocrystal-embedded Pb(OH)Br with ultrahigh stability. ACS Appl. Mater. Interfaces 13 , 23960–23969 (2021)..
Kitaura, M. et al. Atomic positions and displacements in piezoelectric materials Ca3TaGa3Si2O14 and Ca3TaGa1.5Al1.5Si2O14 investigated by Ta-Lα X-ray fluorescence holography. Front. Mater. 9 , 977371 (2022)..
Shahbaz Tehrani, F. & Daadmehr, V. Superconductivity versus structural parameter s in calcium-doped Nd1- x Ca x FeAsO0.8F0.2 superconductors. J. Supercond. Nov. Magn. 33 , 337–345 (2020)..
Yu, X. et al. Hydrochromic CsPbBr3 nanocrystals for anti-counterfeiting. Angew. Chem. Int. Ed. 59 , 14527–14532 (2020)..
Zhou, Y. H. et al. Perovskite anion exchange: a microdynamics model and a polar adsorption strategy for precise control of luminescence color. Adv. Funct. Mater. 31 , 2106871 (2021)..
Yan, Y. G. et al. Quantum-dot color wheel for projection displays. Optica 10 , 1559–1566 (2023)..
Vale, B. R. C. et al. Exciton, biexciton, and hot exciton dynamics in CsPbBr3 colloidal nanoplatelets. J. Phys. Chem. Lett. 11 , 387–394 (2020)..
Huo, T. Y. et al. Ultrafast photoinduced carrier dynamics in single crystalline perovskite films. J. Mater. Chem. C 11 , 3736–3742 (2023)..
Zhang, J. B. et al. In situ synthesis of ultrastable CsPbBr3 perovskite nanocrystals coated with polyimide in a CSTR System. ACS Appl. Mater. Interfaces 12 , 3080–3085 (2020) ..
Qiao, B. et al. Water-resistant, monodispersed and stably luminescent CsPbBr3/CsPb2Br5 core–shell-like structure lead halide perovskite nanocrystals. Nanotechnology 28 , 445602 (2017)..
Luo, X. et al. Unraveling the microstructure of inorganic halide perovskites during thermally driven phase transition and degradation. J. Phys. Chem. C 127 , 11632–11640 (2023)..
Zheng, J. X. et al. Phase transition induced thermal reversible luminescent of perovskite quantum dots fibers. Adv. Funct. Mater. 33 , 2300607 (2023)..
Zhang, H. D. et al. Ultra-small-size, highly efficient and stable CsPbBr3 quantum dots synthesized by using a cesium-dodecyl benzene sulfonic acid solution. Chem. Eng. J. 473 , 145213 (2023)..
Ai, B. et al. Low temperature photoluminescence properties of CsPbBr3 quantum dots embedded in glasses. Adv. Funct. Mater. 19 , 17349–17355 (2017)..
Chen, S. Y. et al. Reprocessable silyl ether-based dynamic covalent poly(dimethylsiloxane) networks with superb thermal stability and creep resistance. ACS Appl. Polym. Mater. 6 , 4c00291 (2024)..
Guan, X. X., Bartschat, K. & Schneider, B. I. Dynamics of two-photon double ionization of helium in short intense XUV laser pulses. Phys. Rev. A 77 , 043421 (2008)..
Singh, K. P., Arya, R. & Malik, A. K. Effect of initial phase on error in electron energy obtained using paraxial approximation for a focused laser pulse in vacuum. J. Appl. Phys. 118 , 104902 (2015)..
Notta-Cuvier, D. et al. Design of toughened PLA based material for application in structures subjected to severe loading conditions. Part 1. Quasi-static and dynamic tensile tests at ambient temperature. Polym. Test. 54 , 233–243 (2016)..
Fang, J. et al. Fouling release nanostructured coatings based on PDMS-polyurea segmented copolymers. Polymer 51 , 2636–2642 (2010)..
Bar-Sadeh, E. et al. Single-electron tunneling effects in granular metal-films. Phys. Rev. B 50 , 8961–8964 (1994)..
Wei, Z. et al. Polymer-mediated electron tunneling towards solar water oxidation. Adv. Funct. Mater. 32 , 2106338 (2022)..
Shen, Z. Y. et al. Tuning the interfacial electronic conductivity by artificial electron tunneling barriers for practical lithium metal batteries. Nano Lett. 20 , 6606–6613 (2020)..
Yang, Z. Y. et al. Single-nanowire spectrometers. Science 365 , 1017–1020 (2019)..
Jund, P. & Jullien, R. Molecular-dynamics calculation of the thermal conductivity of vitreous silica. Phys. Rev. B 59 , 13707–13711 (1999)..
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