1.School of Electrical & Electronic Engineering, Nanyang Technological University, Singapore 639798, Singapore
2.School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore
3.Key Laboratory of Optoelectronics Technology, Ministry of Education, School of Information Science and Technology, Beijing University of Technology, 100124 Beijing, China
4.Centre for Disruptive Photonic Technologies, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
Qi Jie Wang (qjwang@ntu.edu.sg)
收稿日期:2025-01-10,
修回日期:2025-05-09,
录用日期:2025-05-21,
网络出版日期:2025-07-21,
纸质出版日期:2025-09-30
Scan QR Code
Bipolar-barrier tunnel heterostructures for high-sensitivity mid-wave infrared photodetection[J]. LSA, 2025,14(9):2595-2604.
Wang, F. K. et al. Bipolar-barrier tunnel heterostructures for high-sensitivity mid-wave infrared photodetection. Light: Science & Applications, 14, 2595-2604 (2025).
Bipolar-barrier tunnel heterostructures for high-sensitivity mid-wave infrared photodetection[J]. LSA, 2025,14(9):2595-2604. DOI: 10.1038/s41377-025-01905-y.
Wang, F. K. et al. Bipolar-barrier tunnel heterostructures for high-sensitivity mid-wave infrared photodetection. Light: Science & Applications, 14, 2595-2604 (2025). DOI: 10.1038/s41377-025-01905-y.
The rapid development of modern infrared optoelectronic technology has driven a growing demand for high-sensitivity mid-wave infrared (MWIR) photodetectors capable of reliable room-temperature operation. Achieving optimal specific detectivity
a critical performance metric for MWIR photodetection
remains challenging due to inherent limitations imposed such as high dark current
low optical absorption
or both. To address these challenges
we present an approach based on a bipolar-barrier architecture featuring a black phosphorus (BP)/MoTe
2
/BP tunnel heterostructure integrated with an Au reflector. This configuration delivers simultaneous electrical and optical enhancement
effectively suppressing dark currents and significantly increasing optical absorption. The bipolar-barrier structure minimizes dark current by blocking thermally excited and bias-induced carrier leakage
while facilitating efficient tunneling of photogenerated carri
ers via trap-assisted photogating mechanisms. In addition
the Au reflector enhances optical absorption through interference effects. As a result
the heterostructure achieves remarkable performance metrics
including a room-temperature specific detectivity of ~3.0 × 10
10
cm Hz
0.5
W
−1
a high responsivity of ~4 A W
−1
and an external quantum efficiency of ~140% within the MWIR range. These results establish the bipolar-barrier tunnel heterostructure as a highly efficient platform
paving the way for the next generation of advanced infrared optoelectronic devices.
Chen, D. K. et al. Photon-trapping-enhanced avalanche photodiodes for mid-infrared applications. Nat. Photonics 17 , 594–600 (2023)..
Wang, F. K. et al. Multidimensional detection enabled by twisted black arsenic-phosphorus homojunctions. Nat. Nanotechnol. 19 , 455–462 (2024)..
Jiang, H. et al. Synergistic-potential engineering enables high-efficiency graphene photodetectors for near- to mid-infrared light. Nat. Commun. 15 , 1225 (2024)..
Liu, J. et al. Semimetals for high-performance photodetection. Nat. Mater. 19 , 830–837 (2020)..
Gupta, N. et al. Large-scale efficient mid-wave infrared optoelectronics based on black phosphorus ink. Sci. Adv. 9 , eadi9384 (2023)..
Vella, J. H. et al. Broadband in frared photodetection using a narrow bandgap conjugated polymer. Sci. Adv. 7 , eabg2418 (2021)..
Zhang, Y. Z. et al. Broadband high photoresponse from pure monolayer graphene photodetector. Nat. Commun. 4 , 1811 (2013)..
Yu, X. C. et al. Atomically thin noble metal dichalcogenide: a broadband mid-infrared semiconductor. Nat. Commun. 9 , 1545 (2018)..
Chen, Y. F. et al. Unipolar barrier photodetectors based on van der Waals heterostructures. Nat. Electron. 4 , 357–363 (2021)..
Martyniuk, P., Kopytko, M. A. & Rogalski, A. Barrier infrared detectors. Opto-Electron. Rev. 22 , 127–146 (2014)..
Zhang, X. L. et al. Dark current mechanisms and suppression strategies for infrared photodetectors based on two‐dimensional materials. Laser Photonics Rev. 17 , 2300936 (2023)..
Deng, Z. et al. Mid-wave infrared InAs/GaSb type-Ⅱ superlattice photodetector with n-B-p design grown on GaAs substrate. IEEE J. Quantum Electron. 55 , 1–5 (2019)..
Delli, E. et al. Mid-infrared InAs/InAsSb superlattice nBn photodetector monolithically integrated onto silicon. ACS Photonics 6 , 538–544 (2019)..
Zhang, S. K. et al. Black arsenic phosphorus mid-wave infrared barrier detector with high detectivity at room temperature. Adv. Mater. 36 , 2313134 (2024)..
Deng, W. J. et al. Switchable unipolar-barrier van der Waals heterostructures with natural anisotropy for full linear polarimetry detection. Adv. Mater. 34 , 2203766 (2022)..
Wang, F. K. et al. High-sensitivity shortwave infrared photodetectors of metal-organic frameworks integrated on 2D layered materials. Sci. China Mater. 65 , 451–459 (2021)..
Lien, M. R. et al. Black phosphorus molybdenum disulfide midwave infrared photodiodes with broadband absorption-increasing metasurfaces. Nano Lett. 23 , 9980–9987 (2023)..
Wang, H. Y. et al. Van der Waals integration based on two‐dimensional materials for high‐performance infrared photodetectors. Adv. Funct. Mater. 31 , 2103106 (2021)..
Guan, X. W. et al. Recent progress in short‐ to long‐wave infrared photodetection using 2D materials and heterostructures. Adv. Opt. Mater. 9 , 2001708 (2020)..
Wang, F. K. et al. A two-dimensional mid-infrared optoelectronic retina enabling simultaneous perception and encoding. Nat. Commun. 14 , 1938 (2023)..
Pi, L. J. et al. Broadband convolutional processing using band-alignment-tunable heterostructures. Nat. Electron. 5 , 248–254 (2022)..
Wang, F. K. et al. Band structure engineered tunneling heterostructures for high-performance visible and near-infrared photodetection. Sci. China Mater. 63 , 1537–1547 (2020)..
Fang, Y. J. et al. Accurate characterization of next-generation thin-film photodetectors. Nat. Photonics 13 , 1–4 (2018)..
Wang, F. et al. How to characterize figures of merit of two-dimensional photodetectors. Nat. Commun. 14 , 2224 (2023)..
Shen, D. Z. et al. High-performance mid-IR to deep-UV van der Waals photodetector s capable of local spectroscopy at room temperature. Nano Lett. 22 , 3425–3432 (2022)..
Bullock, J. et al. Polarization-resolved black phosphorus/molybdenum disulfide mid-wave infrared photodiodes with high detectivity at room temperature. Nat. Photonics 12 , 601–607 (2018)..
Zhang, S. K. et al. Multi-dimensional optical information acquisition based on a misaligned unipolar barrier photodetector. Nat. Commun. 15 , 7071 (2024)..
Amani, M. et al. Mid-wave infrared photoconductors based on black phosphorus-arsenic alloys. ACS Nano 11 , 11724–11731 (2017)..
Liu, M. X. et al. Photogating-assisted tunneling boosts the responsivity and speed of heterogeneous WSe 2 /Ta 2 NiSe 5 photodetectors. Nat. Commun. 15 , 141 (2024)..
Bai, Z. Q. et al. Highly tunable carrier tunneling in vertical graphene-WS 2 -graphene van der Waals heterostructures. ACS Nano 16 , 7880–7889 (2022)..
Yu, W. J. et al. Unusually efficient photocurrent extraction in monolayer van der Waals heterostructu re by tunnelling through discretized barriers. Nat. Commun. 7 , 13278 (2016)..
Vu, Q. A. et al. Tuning carrier tunneling in van der Waals heterostructures for ultrahigh detectivity. Nano Lett. 17 , 453–459 (2017)..
Hwang, A. et al. Visible and infrared dual-band imaging via Ge/MoS 2 van der Waals heterostructure. Sci. Adv. 7 , eabj2521 (2021)..
Guo, Q. S. et al. Black phosphorus mid-infrared photodetectors with high gain. Nano Lett. 16 , 4648–4655 (2016)..
Xu, T. F. et al. Van der Waals mid-wavelength infrared detector linear array for room temperature passive imaging. Sci. Adv. 10 , eadn0560 (2024)..
Xu, Y. S. et al. Scalable integration of hybrid high- k dielectric materials on two-dimensional semiconductors. Nat. Mater. 22 , 1078–1084 (2023)..
Liu, K. L. et al. A wafer-scale van der Waals dielectric made from an inorganic molecular crystal film. Nat. Electron. 4 , 906–913 (2021)..
Li, J. et al. Towards the scalable synthesis of two-dimensional heterostructures and superlattices beyond exfoliation and restacking. Nat. Mater. 23 , 1326–1338 (2024)..
Chen, C. et al. Growth of single-crystal black phosphorus and its alloy films through sustained feedstock release. Nat. Mater. 22 , 717–724 (2023)..
Wu, J. F. et al. High-sensitivity, high-speed, broadband mid-infrared photodetector enabled by a van der Waals heterostructure with a vertical transport channel. Nat. Commun. 16 , 564 (2025)..
Liu, K. L. & Zhai, T. Y. Emergence of two-dimensional inorganic molecular crystals. Acc. Mater. Res. 5 , 665–674 (2024)..
Ma, Y. R., Wang, M. H. & Zhai, T. Y. 2D molecular crystals for electronic and optoelectronic devices: status and challenges. Adv. Mater. 37 , 2416160 (2025)..
Li, Y. F. et al. Near-infrared photonic phase-change properties of transition metal ditellurides. Proceedings of SPIE 11085, Low-Dimensional Materials and Devices 2019. San Diego: SPIE, 110850T. (2019).
Liu, Y. et al. Approaching the Schottky-Mott limit in van der Waals metal-semiconductor junctions. Nature 557 , 696–700 (2018)..
0
浏览量
0
Downloads
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621