1.Ministry of Education Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry, Sun Yat-sen University, Guangzhou 510006, China
2.School of Optoelectronic Engineering & CQUPT-BUL Innovation Institute, Chongqing University of Posts and Telecommunications, Chongqing 400065, China
3.The State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Technology, South China University of Technology, Guangzhou 510641, China
4.Northeast Guangdong Key Laboratory of New Functional Materials, Guangdong Rare Earth Photofunctional Materials Engineering Technology Research Center, School of Chemistry and Environment, Jiaying University, Meizhou 514015, China
Chonggeng Ma (cgma.ustc@gmail.com)
Jing Wang (ceswj@mail.sysu.edu.cn)
收稿:2025-03-24,
修回:2025-07-02,
录用:2025-07-03,
网络出版:2025-09-11,
纸质出版:2025-10-31
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Simin Gu, Huiwang Lian, Rongyi Kuang, 等. Laser-driven luminescent ceramic-converted near-infrared Ⅱ light source for advanced imaging and detection techniques[J]. Light: Science & Applications, 2025,14(10):3301-3310.
Gu, S. M. et al. Laser-driven luminescent ceramic-converted near-infrared Ⅱ light source for advanced imaging and detection techniques. Light: Science & Applications, 14, 3301-3310 (2025).
Simin Gu, Huiwang Lian, Rongyi Kuang, 等. Laser-driven luminescent ceramic-converted near-infrared Ⅱ light source for advanced imaging and detection techniques[J]. Light: Science & Applications, 2025,14(10):3301-3310. DOI: 10.1038/s41377-025-01953-4.
Gu, S. M. et al. Laser-driven luminescent ceramic-converted near-infrared Ⅱ light source for advanced imaging and detection techniques. Light: Science & Applications, 14, 3301-3310 (2025). DOI: 10.1038/s41377-025-01953-4.
Laser-driven near-infrared Ⅱ (NIR-Ⅱ) light sources comprising luminescent ceramics represent a promising research frontier
yet their development remains constrained by the external quantum efficiency (EQE) and thermal stability bottleneck of current luminescent materials. Herein
we present a non-equivalent cation substitution strategy to fabricate high-efficiency translucent MgO: Ni
2+
Cr
3+
NIR-Ⅱ luminescent ceramics. The co-doping of Cr
3+
induces structural distortion at Ni
2+
-occupied octahedral sites
effectively breaking the parity-forbidden d-d transition constraint while enabling efficient energy transfer from Cr
3+
to Ni
2+
. These synergistic effects yield remarkable internal and external quantum efficiencies of 61.06% and 39.69%
respectively. The developed ceramic demonstrates exceptional thermal management capabilities with 31.28 W·m
−1
·K
−1
thermal conductivity and 92.11% emission retention at 478 K. When integrated into laser-driven NIR-Ⅱ light sources
the system achieves record-breaking performance of 214 mW output power under 21.43 W/mm
2
blue laser excitation. Practical demonstrations showcase superior non-destructive imaging capabilities with 5.29 lp/mm spatial resolution and 0.97 contrast ratio. This work establishes a new paradigm for developing high-performance NIR-Ⅱ light sources in advanced imaging and detection technologies.
Sun, Y. et al. Bright and stable perovskite light-emitting diodes in the near-infrared range. Nature 615 , 830–835 (2023)..
Saif, M. et al. Non-invasive monitoring of chronic liver disease via near-infrared and shortwave-infrared imaging of endogenous lipofuscin. Nat. Biomed. Eng. 4 , 801–813 (2020)..
He, Y. et al. Recent progress of nondestructive techniques for fruits damage inspection: a review. Crit. Rev. Food Sci. Nutr. 62 , 5476–5494 (2021)..
Vasilopoulou, M. et al. Advances in solution-processed near-infrared light-emitting diodes. Nat. Photonics 15 , 656–669 (2021)..
Qiao, J. et al. Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes. Nat. commun. 10 , 5267 (2019)..
Jia, Z. et al. Strategies to approach high performance in Cr 3+ -doped phosphors for high-power NIR-LED light sources. Light Sci. Appl. 9 , 86 (2020)..
Wang, S. et al. Achieving high quantum efficiency broadband NIR Mg4Ta2O9:Cr3+ phosphor through lithium ion compensation. Adv. Mater 35 , e2300124 (2023)..
Laubsch, A. et al. Indirect Auger recombination as a cause of efficiency droop in nitride light-emitting diodes. Phys. Status Solidi C. 6 , S913 (2009)..
Schubert, M. F. et al. Auger recombination in InGaN measured by photoluminescence. Appl. Phys. Lett. 91 , 141101 (2007)..
Miao, S. et al. Blue LED‐Pumped broadband short‐wave infrared emitter based on LiMgPO 4 : Cr 3+ , Ni 2+ phosphor. Adv. Mater. Technol. 7 , 2200320 (2022)..
Tang, C. et al. Ni 2+ -activated MgTi 2 O 5 with broadband emission beyond 1200 nm for NIR-Ⅱ light source applications. J. Mater. Chem. C. 10 , 18234–18240 (2022)..
Wierer, J. et al. Comparison between blue lasers and light-emitting diodes for future solid-state lighting. Laser Photonics Rev. 7 , 963–993 (2013)..
Rahman, F. Diode laser-excited phosphor-converted light sources: a review. Opt. Eng. 61 , 060901 (2022)..
Kim, M. et al. Origin of efficiency droop in GaN-based light-emitting diodes. Appl. Phys. Lett. 91 , 183507 (2007)..
Zheng, G. et al. Glass-crystallized luminescence translucent ceramics toward high-performance broadband NIR LEDs. Adv. Sci. 9 , 2105713 (2022)..
Jiang, H. et al. Ultra‐efficient GAGG: Cr 3+ ceramic phosphor‐converted laser diode: a promising high‐power compact near‐infrared light source enabling clear imaging. Adv. Optical Mater. 10 , 2102741 (2022)..
Liu, G. et al. Laser-driven broadband near-infrared light source with watt-level output. Nat. Photonics 18 , 562 (2024)..
Lu, X. et al. Long-wavelength near-infrared divalent nickel-activated double-perovskite Ba 2 MgWO 6 phosphor as imaging for human fingers. ACS Appl. Mater. Interfaces 15 , 39472–39479 (2023)..
Guo, X. et al. Valence state control of Cr 4+ -activated Li 2 SrGeO 4 for NIR-Ⅱ light source to distinguish deuterium and non-deuterium reagents. J. Mater. Chem. C. 11 , 7611–7618 (2023)..
Feng, Z. et al. Perfecting and extending the near-infrared imaging window. Light Sci. Appl. 10 , 197 (2021)..
Siesler, H. W. et al. Near-infrared spectroscopy: principles, instruments, applications (John Wiley & Sons, Press, 2008).
Rajendran, V. et al. Unraveling luminescent energy transfer pathways: futuristic approach of miniature shortwave infrared light-emitting diod e design. ACS Energy Lett. 8 , 2395–2400 (2023)..
Brik, M. G. et al. Spectroscopic properties of Ni 2+ ions in octahedral complexes. Chin. J. Lumin. 43 , 1459–1467 (2022)..
Yuan, L. et al. Ni 2+ -doped garnet solid-solution phosphor-converted broadband shortwave infrared light-emitting diodes toward spectroscopy application. ACS Appl. Mater. Interfaces 14 , 4265–4275 (2022)..
Liu, B. M. et al. Ultra-broadband and high-efficiency phosphors to brighten NIR-Ⅱ light source applications. Cell Rep. Phys. Sci. 3 , 101078 (2022)..
Miao, S. et al. Broadband short-wave infrared-emitting MgGa 2 O 4 : Cr 3+ , Ni 2+ phosphor with near-unity internal quantum efficiency and high thermal stability for light-emitting diode applications. ACS Appl. Mater. Interfaces 15 , 32580–32588 (2023)..
Liu, B. M. et al. A High-efficiency blue-LED-excitable NIR-Ⅱ-emitting MgO: Cr 3+ , Ni 2+ phosphor for future broadband light source toward multifunctional NIR spectroscopy applications. Chem. Eng. J. 452 , 139313 (2023)..
Shannon, R. D. Revised effective ionic radii and systematic studies of interatomie distances in halides and chaleogenides. Acta Cryst. 32 , 751–767 (1976)..
Mironova-Ulmane, N. et al. Crystal field calculations of energy levels of the Ni 2+ ions in MgO. J. Lumin. 135 , 74–78 (2013)..
Inokuti, M. & Hirayama, F. Influence of energy transfer by the exchange mechanism on donor luminescence. J. Chem. Phys. 43 , 1978–1989 (1965)..
Satpathy, A. et al. Near‐Infrared Ⅰ/Ⅱ nanophosphors with Cr 3+ /Ni 2+ energy transfer for bioimaging. Adv. Optical Mater. 11 , 2300321 (2023)..
Dexter, D. L. A theory of sensitized luminescence in solids. J. Chem. Phys. 21 , 836–850 (1953)..
Baur, W. H. The geometry of polyhedral distortions. Predictive relationships for the phosphate group. Acta Crystallogr. Sect. B Struct. Sci. 30 , 1195–1215 (1974)..
Peli, E. Contrast in complex images. J. Opt. Soc. Am. A 7 , 2032 (1990)..
Najjar, Y. Effect of contrast measures on the performance of no-reference image quality assessment algorithm for contrast-distorted images. Jordan J. Elec. Eng. 7 , 390–404 (2021)..
Kresse, G. et al. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54 , 11169–11186 (1996)..
Kresse, G. et al. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6 , 15–50 (1996)..
Perdew, J. P. et al. Generalized gradient approximation made simple. Phys. Rev. Lett. 77 , 3865–3868 (1996)..
Adamo, C. & Barone, V. Toward reliable density functional methods without adjustable parameters: the PBE0 model. J. Chem. Phys. 110 , 6158–6170 (1999)..
Kresse, G. & From, D. J. ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59 , 1758–1775 (1999)..
Blöchl, P. E. Projector augmented-wave method. Phys. Rev. B 50 , 17953–17979 (1994)..
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