1.School of Materials Science & Engineering, Shandong University, Jinan 250061, China
2.State Key Laboratory of Coatings for Advanced Equipment, Shandong University, Jinan 250061, China
3.School of Information and Communication Engineering, Beijing University of Posts and Telecommunications, Beijing 100876, China
4.Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai, Yantai 264006, China
5.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
6.Department of Oral and Maxillofacial Surgery, School and Hospital of Stomatology, Cheeloo College of Medicine, Shandong University, Jinan 250012, China
7.Department of Oral and Maxillofacial Surgery, Qilu Hospital of Shandong University, Jinan 250012, China
8.Department of Physics, Georgia Southern University, Statesboro, GA 30460, USA
Zhaofeng Wang (zhfwang@licp.cas.cn)
Xiao-Jun Wang (xwang@georgiasouthern.edu)
Yanjie Liang (yanjie.liang@sdu.edu.cn)
收稿:2025-08-20,
修回:2025-11-09,
录用:2025-11-10,
网络首发:2026-01-12,
纸质出版:2026-04-30
Scan QR Code
Xulong Lv, Tianyi Duan, Shaofan Fang, 等. Self-powered mechanoluminescent elastomer for solar-blind ultraviolet emission[J]. Light: Science & Applications, 2026,15(4):1089-1104.
Lv, X. L. et al. Self-powered mechanoluminescent elastomer for solar-blind ultraviolet emission. Light: Science & Applications, 15, 1089-1104 (2026).
Xulong Lv, Tianyi Duan, Shaofan Fang, 等. Self-powered mechanoluminescent elastomer for solar-blind ultraviolet emission[J]. Light: Science & Applications, 2026,15(4):1089-1104. DOI: 10.1038/s41377-025-02131-2.
Lv, X. L. et al. Self-powered mechanoluminescent elastomer for solar-blind ultraviolet emission. Light: Science & Applications, 15, 1089-1104 (2026). DOI: 10.1038/s41377-025-02131-2.
Flexible mechanoluminescence (ML) elastomers show significant potential for next-generation wearable electronics
artificial skin
advanced sensing
and human-machine interaction. However
their broader application has been hindered by challenges such as restricted emission wavelengths
inadequate repeatability
insufficient cyclic stability
and poor self-recovery. Here
we report an innovative and high-performance solar-blind ultraviolet ML elastomer by combining commercial polydimethylsiloxane (PDMS)
and newly fabricated Sr
3
(BO
3
)
2
:Pr
3+
phosphors
capable of generating intense ultraviolet-C (UVC) ML peaked at 272 nm under mechanical stimulation. The composite elastomer exhibits exceptional repeatability and cyclic stability
maintaining detectable UVC emission over 10
000 continuous stretching cycles (power intensity at the 1st cycle is ~6.2 mW m
−2
). It also demonstrates rapid and efficient self-recovery behavior
restoring 43.2% of its initial intensity within 1 s and 90.2% after 24 h. Combined experimental and theoretical analyses reveal that interfacial triboelectrification
involving electron transfer from the phosphor to the PDMS matrix
leads to the observed UVC ML emission. Leveraging the solar-blind nature and high photon energy of UVC light
we further demonstrate the feasibility of self-powered photonics applications. This work not only offers novel insights into the design of advanced UVC ML systems but also provides “power-free” solutions for important applications where UVC photons are essential
such as outdoor optical tagging and microbial sterilization.
Jiang, S. et al. Activation of mechanoluminescent nanotransducers by focused ultrasound enables light delivery to deep-seated tissue in vivo. Nat. Protoc. 18 , 3787–3820 (2023)..
Wang, X. D. et al. Dynamic pressure mapping of personalized handwriting by a flexible sensor matrix based on the mechanoluminescence process. Adv. Mater. 27 , 2324–2331 (2015)..
Zhang, Q. Y. et al. A flexible organic mechanoluminophore device. Nat. Commun. 14 , 1257 (2023)..
Zhuang, Y. X. & Xie, R. J. Mechanoluminescence rebrightening the prospects of stress sensing: a review. Adv. Mater. 33 , 2005925 (2021)..
Hong, G. S. Seeing the sound. Science 369 , 638 (2020)..
Terasaki, N. & Xu, C. N. Mechanoluminescence recording device integrated with photosensitive material and europium-doped SrAl 2 O 4 . J. Appl. Phys. 48 , 04C150 (2009)..
Jha, P. & Chandra, B. P. Survey of the literature on mechanoluminescence from 1605 to 2013. Luminescence 29 , 977–993 (2014)..
Zhang, J. C. et al. Trap-controlled mechanoluminescent materials. Prog. Mater. Sci. 103 , 678–742 (2019)..
Yang, J. H. et al. Achieving efficient phosphorescence and mechanoluminescence in organic host–guest system by energy transfer. Adv. Funct. Mater. 31 , 2108072 (2021)..
Chang, K. et al. Achieving ultrasound-excited emission with organic mechanoluminescent materials. Adv. Mater. 36 , 2407875 (2024)..
Yang, L. et al. Intense and recoverable piezoluminescence in Pr 3+ -activated CaTiO 3 with centrosymmetric structure. Appl. Phys. Lett. 118 , 053901 (2021)..
Feng, A. & Smet, P. F. A revi ew of mechanoluminescence in inorganic solids: compounds, mechanisms, models and applications. Materials 11 , 484 (2018)..
Zhan, L. S. et al. A simple organic molecule realizing simultaneous TADF, RTP, AIE, and mechanoluminescence: understanding the mechanism behind the multifunctional emitter. Angew. Chem. Int. Ed. 58 , 17651–17655 (2019)..
Wang, Y. Z. et al. Synthesis of SrZnOSe crystals with low phonon energy for enhancing near-infrared mechanoluminescence. Adv. Mater. 36 , 2406899 (2024)..
Wong, M. C. et al. Temporal and remote tuning of piezophotonic-effect-induced luminescence and color gamut via modulating magnetic field. Adv. Mater. 29 , 1701945 (2017)..
Zhuang, Y. X. et al. Visualizing dynamic mechanical actions with high sensitivity and high resolution by near-distance mechanoluminescence imaging. Adv. Mater. 34 , 2202864 (2022)..
Deng, Y. et al. Energy transfer-assisted color conversion of persistent mechanoluminescence in RhB@SiO 2 /SrAl 2 O 4 :Eu,dy system for multilevel information encryption. Laser Photonics Rev. 18 , 2400251 (2024)..
Guo, J. X. et al. In-sensor computing with visual-tactile perception enabled by mechano-optical artificial synapse. Adv. Mater. 37 , 2419405 (2025)..
Hou, B. et al. An interactive mouthguard based on mechanoluminescence-powered optical fibre sensors for bite-controlled device operation. Nat. Electron. 5 , 682–693 (2022)..
Wu, S. et al. Multiple defect-induced high-resolution near-infrared mechanoluminescent materials for non-destructive detection of blood glucose and lipids. Adv. Mater. 36 , 2408508 (2024)..
Su, L. et al. Self-powered visualized tactile-acoustic sensor for accurate artificial perception with high brightness and record-low detection limit. Sci. Adv. 10 , eadq8989 (2024)..
Qin, S. Y. et al. Self-recoverable, highly repeatable, and thermally stable mechanoluminescence for dual-mode information storage and photonic skin applications. Adv. Funct. Mater. 34 , 2401535 (2024)..
Yu, S. et al. Soft human–machine interface sensing displays: materials and devices. Adv. Mater. 35 , 2204964 (2023)..
Li, L. P. et al. Stress-triggered mechanoluminescence in ZnO-based heterojunction for flexible and stretchable mechano-optics. Adv. Funct. Mater. 33 , 2301372 (2023)..
Wang, W. X. et al. Contact-separation-induced self-recoverable mechanoluminescence of CaF 2 :Tb 3+ /PDMS elastomer. Nat. Commun. 15 , 2014 (2024)..
Zhang, P. F. et al. Design of visualized ratiometric mechanoluminescent materials for high-resolution pressure sensing. Adv. Funct. Mater. 35 , 2412911 (2025)..
Ma, Z. D. et al. Efficient blue mechanoluminescence in Eu 2+ -Activated Sr 5 (PO 4 ) 3 Cl for advanced anticounterfeiting with mildew-resistant behavior. Mater. Today Chem. 36 , 101917 (2024)..
Zhou, J. Y. et al. An ultra-strong non-pre-irradiation and self-recoverable mechanoluminescent elastomer. Chem. Eng. J. 390 , 124473 (2020)..
Moon Jeong, S. et al. Mechanically driven light-generator with high durability. Appl. Phys. Lett. 102 , 051110 (2013)..
Lee, Y. H., Chung, I. J. & Oh, M. H. Possible degradation mechanism in ZnS:Mn alternating current thin-film electroluminescent display. Appl. Phys. Lett. 58 , 962–964 (1991)..
Chandra, V. K., Chandra, B. P. & Jha, P. Self-recovery of mechanoluminescence in ZnS:Cu and ZnS:Mn phosphors by trapping of drifting charge carriers. Appl. Phys. Lett. 103 , 161113 (2013)..
Wang, Z. X. et al. Size and Structural control of mechanoluminescent ZnS:Mn 2+ nanocrystals for optogenetic neuromodulation. ACS Nano. 19 , 19340–19352 (2025)..
Wang, W. X. et al. Contact electrification induced mechanoluminescence. Nano Energy 94 , 106920 (2022)..
Ma, Z. D. et al. Mechanics-induced triple-mode anticounterfeiting and moving tactile sensing by simultaneously utilizing instantaneous and persistent mechanoluminescence. Mater. Horiz. 6 , 2003–2008 (2019)..
Shao, P. S. et al. Self-recoverable NIR mechanoluminescence from Cr 3+ doped perovskite type aluminate. Adv. Powder Mater. 3 , 100165 (2024)..
Yang, X. X. et al. Energy focusing reinforced narrowband ultraviolet-B mechanoluminescence for bright-field stress visualization. J. Mater. Chem. C. 11 , 6912–6919 (2023)..
Yu, S. S. et al. Self-recoverable and cyclically stable near-infrared mechanoluminescence for dual-mode mechanics visualization and biomechanics detection. Chem. Eng. J. 474 , 145542 (2023)..
Ma, Z. D. et al. Near-ultraviolet and deep red dual-band mechanoluminescence for color manipulation and biomechanics detection. Chem. Eng. J. 456 , 141122 (2023)..
Zhang, W. X. et al. Ratiometric mechanoluminescence in LiSrPO 4 :Eu 2+ /Eu 3+ for stress sensing: dopant concentration dependent sensitivity. Mater. Res. Bull. 163 , 112219 (2023)..
Cai, C. Y. et al. All-lanthanide mechanoluminescence from transparent Ln-doped MgF 2 @elastomer for flexible and stretchable lighting and stress sensing. Adv. Mater. Technol. 9 , 2301855 (2024)..
Pan, X. et al. Quantifying the interfacial triboelectricity in inorganic-organic composite mechanoluminescent materials. Nat. Commun. 15 , 2673 (2024)..
Zou, H. Y. et al. Quantifying the triboelectric series. Nat. Commun. 10 , 1427 (2019)..
Jeong, H. I. et al. Super elastic and negative triboelectric polymer matrix for high performance mechanoluminescent platforms. Nat. Commun. 16 , 854 (2025)..
Fang, S. F. et al. Highly repeatable and cyclically stable mechanoluminescence of the flexible composite elastomer. Adv. Mater. 37 , 2505071 (2025)..
Dou, C. et al. Self-recoverable and NIR-Ⅰ to NIR-Ⅱ tunable broadband mechanoluminescence of Cr 3+ -doped antimonate double perovskites. Adv. Funct. Mater. 35 , 2419716 (2025)..
Zhou, S. et al. Ratiometric mechanoluminescence of double-activator doped phosphatic phosphors: color-resolved visualization of stress-sensing and quantified evaluation for sensing performance. Adv. Funct. Mater. 32 , 2208919 (2022)..
Bai, Y. Q. et al. Self-charging persistent mechanoluminescence with mechanics storage and visualization activities. Adv. Sci. 9 , 2203249 (2022)..
Tian, B. R. et al. Stress-induced color manipulation of mechanoluminescent elastomer for visualized mechanics sensing. Nano Energy 83 , 105860 (2021)..
Du, R. K. et al. Synergistic mechanoluminescence and mechanochromism via triboelectrification-induced Eu 3+ /Eu 2+ redox shuttle. Laser Photonics Rev. 19 , 2401211 (2025)..
Wang, M. et al. Visualization of strain rate based on mechanoluminescence tailing. Chem. Eng. J. 502 , 157876 (2024)..
Cheng, K. G. et al. A universal strategy for multicolor mechanoluminescence via radiative energy transfer based on ultraviolet mechanoluminescent material Ca 9 Al(PO 4 ) 7 :Ce 3+ . Laser Photonics Rev. 19 , 2401524 (2025)..
Li, H. M. et al. Force-induced ultraviolet c luminescence of Pr 3+ -Doped Sr 2 P 2 O 7 for X-ray dosimetry. Adv. Mater. 36 , 2411804 (2024)..
Cai, C. Y. et al. Multi-stimulated far-UVC luminescence for solar-blind imaging. Nat. Commun. 16 , 6224 (2025)..
Lv, X. L. et al. Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments. Light Sci. Appl. 13 , 253 (2024)..
Wang, X. L. et al. Solar-blind ultraviolet-C persistent luminescence phosphors. Nat. Commun. 11 , 2040 (2020)..
Yang, Y. M. et al. X-ray-activated long persistent phosphors featuring strong UVC afterglow emissions. Light Sci. Appl. 7 , 88 (2018)..
Lee, G. et al. Interfacial triboelectricity lights up phosphor-polymer elastic composites: unraveling the mechanism of mechanoluminescence inZinc sulfide microparticle-embedded polydimethylsiloxane films. Small 20 , 2307089 (2024)..
Kim, M. S. et al. A mechanoluminescent ZnS:Cu/PDMS and biocompatible piezoelectric silk fibroin/PDMS Hybrid sensor for self-powered sensing and artificial intelligence control. Adv. Mater. Technol. 9 , 2400255 (2024)..
Schröder, F. & Jüstel, T. Effect of Ga 3+ doping on the luminescence and up-conversion of Pr 3+ activated (Lu,Y) 3 Al 5 O 12 . Opt. Mater. X 12 , 100117 (2021)..
Zhang, Y. et al. Blue LED-pumped intense short-wave infrared luminescence based on Cr 3+ -Yb 3+ -co-doped phosphors. Light Sci. Appl. 11 , 136 (2022)..
Treloar, L. R. G. Stress-strain data for vulcanized rubber under various types of deformation. Rubber Chem. Technol. 17 , 813–825 (1944)..
Upadhyay, K., Subhash, G. & Spearot, D. Visco-hyperelasticconstitutive modeling of strain rate sensitive soft materials. J. Mech. Phys. Solids 135 , 103777 (2020)..
Fan, F. R., Tian, Z. Q. & Wang, Z. L. Flexible triboelectric generator. Nano Energy 1 , 328–334 (2012)..
Wang, Z. L. & Wang, A. C. On the origin of contact-electrification. Mater. Today 30 , 34–51 (2019)..
Wu, J. et al. First-principles investigations on the contact electrification mechanism between metal and amorphous polymers for triboelectric nanogenerators. Nano Energy 63 , 103864 (2019)..
Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a pl ane-wave basis set. Phys. Rev. B. 54 , 11169–11186 (1996)..
0
浏览量
0
Downloads
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621