
1.Department of Electronic Engineering, Hanyang University, 222 Wangsimniro, Seongdong-gu, Seoul 04763, Republic of Korea
2.LG Display Co., Ltd., LG Science Park, 30 Magokjungang 10-ro, Gangseo-gu, Seoul 07796, Republic of Korea
Chang-Jae Yu (cjyu@hanyang.ac.kr)
Jae-Hoon Kim (jhoon@hanyang.ac.kr)
Published:2019,
Published Online:12 December 2019,
Received:12 August 2019,
Revised:23 November 2019,
Accepted:29 November 2019
Scan QR Code
Baek, K. et al. Simultaneous emission of orthogonal handedness in circular polarization from a single luminophore. Light: Science & Applications, 8, 1160-1167 (2019).
Baek, K. et al. Simultaneous emission of orthogonal handedness in circular polarization from a single luminophore. Light: Science & Applications, 8, 1160-1167 (2019). DOI: 10.1038/s41377-019-0232-0.
The direct emission of circularly polarized (CP) light improves the efficiency of an organic light-emitting diode and characterizes the secondary structure of proteins. In most cases
CP light is generated from a luminescent layer containing chiral characteristics
thereby generating only one kind of CP light in an entire device. Here
we propose direct CP light emissions using a twisted achiral conjugate polymer without any chiral dopant as an emitting layer (EML). The twisted structure is induced in the mesogenic conjugate polymer due to its elasticity by applying different alignment directions to its upper and lower interfaces. Furthermore
we demonstrate the simultaneous emission of orthogonal CP light in a single luminescent device by patterning different alignment directions on the surfaces of the EML. The light source with multipolarization including the orthogonal CP states is applicable to many applications in biosensors and optical devices.
Singh, R. et al. Improving the contrast ratio of OLED displays: an analysis of various techniques.Optical Mater.34, 716-723 (2012)..
Wang, C. S. et al. Photoinduced birefringence and reversible optical storage in liquid-crystalline azobenzene side-chain polymers.Appl. Phys. Lett.74, 19-21 (1999)..
Wagenknecht, C. et al. Experimental demonstration of a heralded entanglement source.Nat. Photonics4, 549-552 (2010)..
Yang, Y. et al. Circularly polarized light detection by a chiral organic semiconductor transistor.Nat. Photonics7, 634-638 (2013)..
Kwon, D. H., Werner, P. L.&Werner, D. H. Optical planar chiral metamaterial designs for strong circular dichroism and polarization rotation.Opt. Express16, 11802-11807 (2008)..
Zhao, Y., Belkin, M. A.&Alù, A. Twisted optical metamaterials for planarized ultrathin broadband circular polarizers.Nat. Commun.3, 870 (2012)..
Nagata, Y., Takagi, K.&Suginome, M. Solid polymer films exhibiting handedness-switchable, full-color-tunable selective reflection of circularly polarized light.J. Am. Chem. Soc.136, 9858-9861 (2014)..
Lueder, E.Liquid Crystal Displays(John Wiley&Sons, Chichester, 2010).
Lee, D. M. et al. Birefringence-dependent linearly-polarized emission in a liquid crystalline organic light emitting polymer.Opt. Express25, 3737-3742 (2017)..
Choi, G. J. et al. Polarized light-emitting diodes based on patterned MoS2nanosheet hole transport layer.Adv. Mater.29, 1702598 (2017)..
Lee, D. M. et al. Control of circularly polarized electroluminescence in induced twist structure of conjugate polymer.Adv. Mater.29, 1700907 (2017)..
Ranjbar, B.&Gill, P. Circular dichroism techniques: biomolecular and nanostructural analyses—a review.Chem. Biol. Drug Des.74, 101-120 (2009)..
Greenfield, N. J. Using circular dichroism spectra to estimate protein secondary structure.Nat. Protoc.1, 2876-2890 (2006)..
Han, J. M. et al. Circularly polarized phosphorescent electroluminescence from chiral cationic Iridium(Ⅲ) isocyanide complexes.Adv. Optical Mater.5, 1700359 (2017)..
Han, J. M. et al. Recent progress on circularly polarized luminescent materials for organic optoelectronic devices.Adv. Optical Mater.6, 1800538 (2018)..
Zinna, F., Giovanella, U.&di Bari, L. Highly circularly polarized electroluminescence from a chiral europium complex.Adv. Mater.27, 1791-1795 (2015)..
Peeters, E. et al. Circularly polarized electroluminescence from a polymer light-emitting diode.J. Am. Chem. Soc.119, 9909-9910 (1997)..
Oda, M. et al. Circularly polarized electroluminescence from liquid-crystalline chiral polyfluorenes.Adv. Mater.12, 362-365 (2000)..
Yang, Y. et al. Induction of circularly polarized electroluminescence from an achiral light-emitting polymer via a chiral small-molecule dopant.Adv. Mater.25, 2624-2628 (2013)..
Chen, S. H. et al. Circularly polarized light generated by photoexcitation of luminophores in glassy liquid-crystal films.Nature397, 506-508 (1999)..
Craig, M. R. et al. The chiroptical properties of a thermally annealed film of chiral substituted polyfluorene depend on film thickness.Adv. Mater.15, 1435-1438 (2003)..
Geng, Y. H. et al. Origin of strong chiroptical activities in films of nonafluorenes with a varying extent of pendant chirality.J. Am. Chem. Soc.125, 14032-14038 (2003)..
Haraguchi, S. et al. Circularly polarized luminescence from supramolecular chiral complexes of achiral conjugated polymers and a neutral polysaccharide.Chem. Lett.38, 254-255 (2009)..
Voigt, M., Chambers, M.&Grell, M. On the circular polarization of fluorescence from dyes dissolved in chiral nematic liquid crystals.Chem. Phys. Lett.347, 173-177(2001)..
Lee, D. M. et al. Brightness enhancement of 3D display through patterning linearly polarized OLED.SID Symp. Dig. Tech. Pap.48, 2018-2020 (2017)..
Schadt, M.&Helfrich, W. Voltage-dependent optical activity of a twisted nematic liquid crystal.Appl. Phys. Lett.18, 127-128 (1971)..
Hoogboom, J. et al. LCD alignment layers. Controlling nematic domain properties.J. Mater. Chem.16, 1305-1314 (2006)..
Jo, S. I. et al. Highly polarized emission of the liquid crystalline conjugated polymer by controlling the surface anchoring energy.Jpn. J. Appl. Phys.53, 03CD04 (2014)..
Hobdell, J. R., Lavine, M. S.&Windle, A. H. Hierarchical approach to modelling of liquid-crystalline polymers.J. Computer-Aided Mater. Des.3, 359-368 (1996)..
Sato, T.&Teramoto, A. On the frank elastic constants of lyotropic polymer liquid crystals.Macromolecules29, 4107-4114 (1996)..
de Gennes, P. G.&Prost, J.The Physics of Liquid Crystals, 2nd edn. (Oxford University Press, Oxford, 1993).
Chen, Y.&Wu, S. T. Recent advances on polymer-stabilized blue phase liquid crystal materials and devices.J. Appl. Polym. Sci.131, 40556 (2014)..
Jung, J. H. et al. Circularly polarized electroluminescence by controlling the emission zone in a twisted mesogenic conjugate polymer.J. Mater. Chem. C6, 726-730 (2018)..
Contoret, A. E. A. et al. Polarized electroluminescence from an anisotropic nematic network on a non-contact photoalignment layer.Adv. Mater.12, 971-974 (2000)..
Sakamoto, K. et al. Excellent uniaxial alignment of poly(9, 9-dioctylfluorenyl-2, 7-diyl) induced by photoaligned polyimide films.Appl. Phys. Lett.87, 211910 (2005)..
Zinna, F. et al. Design of lanthanide-based OLEDs with remarkable circularly polarized electroluminescence.Adv. Funct. Mater.27, 1603719 (2017)..
0
Views
0
Downloads
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution
京公网安备11010802024621