
LumiLab, Department of Solid State Sciences, Ghent University, Krijgslaan 281- S1, 9000 Gent, Belgium
Philippe F. Smet (philippe.smet@ugent.be)
Published:2019,
Published Online:25 December 2019,
Received:04 February 2019,
Revised:26 November 2019,
Accepted:10 December 2019
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Petit, R. R. et al. Adding memory to pressure-sensitive phosphors. Light: Science & Applications, 8, 1209-1218 (2019).
Petit, R. R. et al. Adding memory to pressure-sensitive phosphors. Light: Science & Applications, 8, 1209-1218 (2019). DOI: 10.1038/s41377-019-0235-x.
Mechanoluminescence (ML) is the phenomenon describing the emission of light during mechanical action on a solid
leading to applications such as pressure sensing
damage detection and visualization of stress distributions. In most cases
this mechanical action releases energy that was previously stored in the crystal lattice of the phosphor by means of trapped charge carriers. A drawback is the need to record the ML emission during a pressure event. In this work
we provide a method for adding a memory function to these pressure-sensitive phosphors
allowing an optical readout of the location and intensity of a pressure event in excess of 72 h after the event. This is achieved in the BaSi
2
O
2
N
2
:Eu
2+
phosphor
where a broad trap depth distribution essential for the process is present. By merging optically stimulated luminescence (OSL)
thermoluminescence (TL) and ML measurements
the influence of light
heat and pressure on the trap depth distribution is carefully analysed. This analysis demonstrates that mechanical action can not only lead to direct light emission but also to a reshuffling of trap occupations. This memory effect not only is expected to lead to new pressure sensing applications but also offers an approach to study charge carrier transitions in energy storage phosphors.
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