Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry

Miroslav D. Dramićanin; Łukasz Marciniak; Sanja Kuzman; Wojciech Piotrowsk; Zoran Ristić; Jovana Periša; Ivana Evans; Jelena Mitrić; Vesna Đorđević; Nebojša Romčević; Mikhail G. Brik; Chong-Geng Ma

doi:10.1038/s41377-022-00958-7

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Mn⁵⁺-activated Ca₆Ba(PO₄)₄O near-infrared phosphor and its application in luminescence thermometry

Original Articles

- Mn⁵⁺-activated Ca₆Ba(PO₄)₄O near-infrared phosphor and its application in luminescence thermometry
- Light: Science & Applications Vol. 11, Issue 10, Pages: 2463-2475(2022)
- Affiliations：
  
  1.School of Optoelectronic Engineering & CQUPT-BUL Innovation Institute, Chongqing University of Posts and Telecommunications, Chongqing 400065, PR China
  2.Centre of Excellence for Photoconversion, Vinca Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, P.O. Box 522, Belgrade 11001, Serbia
  3.Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, 50-422 Wroclaw, Poland
  4.Department of Chemistry, Durham University, Durham DH1 3LE, UK
  5.Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade, Serbia
  6.Institute of Physics, University of Tartu, Tartu 50411, Estonia
  7.Department of Theoretical Physics, Jan Długosz University, Czestochowa PL 42200, Poland
  8.Academy of Romanian Scientists, Ilfov Str. No. 3, 050044 Bucharest, Romania
- Author bio：
  
  Miroslav D. Dramićanin (dramican@vinca.rs)
  Chong-Geng Ma (cgma.ustc@gmail.com)
- Funds：
- DOI：10.1038/s41377-022-00958-7
  CLC：
- Published：31 October 2022，
  
  Published Online：22 September 2022，
  
  Received：30 April 2022，
  
  Revised：08 August 2022，
  
  Accepted：16 August 2022
- Accepted：
Scan QR Code
Dramićanin, M. D. et al. Mn⁵⁺-activated Ca₆Ba(PO₄)₄O near-infrared phosphor and its application in luminescence thermometry. Light: Science & Applications, 11, 2463-2475 (2022).
DOI：

Dramićanin, M. D. et al. Mn⁵⁺-activated Ca₆Ba(PO₄)₄O near-infrared phosphor and its application in luminescence thermometry. Light: Science & Applications, 11, 2463-2475 (2022). DOI： 10.1038/s41377-022-00958-7.

摘要

Abstract

The near-infrared luminescence of Ca

Ba(PO

)

O: Mn

is demonstrated and explained. When excited into the broad and strong absorption band that spans the 500–1000 nm spectral range

this phosphor provides an ultranarrow (FWHM = 5 nm) emission centered at 1140 nm that originates from a spin-forbidden

E →

transition with a 37.5% internal quantum efficiency and an excited-state lifetime of about 350 μs. We derived the crystal field and Racah parameters and calculated the appropriate Tanabe–Sugano diagram for this phosphor. We found that

E emission quenches due to the thermally-assisted cross-over with the

state and that the relatively high Debye temperature of 783 K of Ca

Ba(PO

)

O facilitates efficient emission. Since Ca

Ba(PO

)

O also provides efficient yellow emission of the Eu

dopant

we calculated and explained its electronic band structure

the partial and total density of states

effective Mulliken charges of all ions

elastic constants

Debye temperature

and vibrational spectra. Finally

we demonstrated the application of phosphor in a luminescence intensity ratio thermometry and obtained a relative sensitivity of 1.92%K

−1

and a temperature resolution of 0.2 K in the range of physiological temperatures.

关键词

Keywords

references

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