1.School of Flexible Electronics (Future Technologies) & Institute of Advanced Materials, Key Laboratory of Flexible Electronics, Jiangsu National Synergetic Innovation Center for Advanced Materials, School of Physical and Mathematical Sciences, Nanjing Tech University, Nanjing 211816, China
2.Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen 518055, China
Lv, Y. et al. Enlighten the non-illuminated region by phase segregation of mixed halide perovskites. Light: Science & Applications, 11, 2561-2563 (2022).
DOI:
Lv, Y. et al. Enlighten the non-illuminated region by phase segregation of mixed halide perovskites. Light: Science & Applications, 11, 2561-2563 (2022). DOI: 10.1038/s41377-022-01019-9.
Enlighten the non-illuminated region by phase segregation of mixed halide perovskites
The well-known ion migration in mixed halide perovskites has been intensely investigated within the area under uniform light illumination. Here
the authors demonstrate that the anion segregation in these materials is a nonlocal effect of which the ion redistribution may occur at a macroscopic or mesoscopic scale beyond.
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references
E. T. Hoke, 等. Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics. Chem. Sci., 2015. 6613-617. DOI:10.1039/C4SC03141Ehttp://doi.org/10.1039/C4SC03141E.
S. J. Yoon, 等. Tracking iodide and bromide ion segregation in mixed halide lead perovskites during photoirradiation. ACS Energy Lett., 2016. 1290-296. DOI:10.1021/acsenergylett.6b00158http://doi.org/10.1021/acsenergylett.6b00158.
D. W. deQuilettes, 等. Photo-induced halide redistribution in organic-inorganic perovskite films. Nat. Commun., 2016. 711683DOI:10.1038/ncomms11683http://doi.org/10.1038/ncomms11683.
A. J. Barker, 等. Defect-assisted photoinduced halide segregation in mixed-halide perovskite thin films. ACS Energy Lett., 2017. 21416-1424. DOI:10.1021/acsenergylett.7b00282http://doi.org/10.1021/acsenergylett.7b00282.
S. Draguta, 等. Rationalizing the light-induced phase separation of mixed halide organic-inorganic perovskites. Nat. Commun., 2017. 8200DOI:10.1038/s41467-017-00284-2http://doi.org/10.1038/s41467-017-00284-2.
C. G. Bischak, 等. Origin of reversible photoinduced phase separation in hybrid perovskites. Nano Lett., 2017. 171028-1033. DOI:10.1021/acs.nanolett.6b04453http://doi.org/10.1021/acs.nanolett.6b04453.
H. C. Zhang, 等. Phase segregation due to ion migration in all-inorganic mixed-halide perovskite nanocrystals. Nat. Commun., 2019. 101088DOI:10.1038/s41467-019-09047-7http://doi.org/10.1038/s41467-019-09047-7.
X. F. Tang, 等. Local observation of phase segregation in mixed-halide perovskite. Nano Lett., 2018. 182172-2178. DOI:10.1021/acs.nanolett.8b00505http://doi.org/10.1021/acs.nanolett.8b00505.
X. X. Sun, Y. Zhang, W. K. Ge. Photo-induced macro/mesoscopic scale ion displacement in mixed-halide perovskites: ring structures and ionic plasma oscillations. Light Sci. Appl., 2022. 11262DOI:10.1038/s41377-022-00957-8http://doi.org/10.1038/s41377-022-00957-8.
D. J. Slotcavage, 等. Light-induced phase segregation in halide-perovskite absorbers. ACS Energy Lett., 2016. 11199-1205. DOI:10.1021/acsenergylett.6b00495http://doi.org/10.1021/acsenergylett.6b00495.
W. X. Mao, 等. Light-induced reversal of ion segregation in mixed-halide perovskites. Nat. Mater., 2021. 2055-61. DOI:10.1038/s41563-020-00826-yhttp://doi.org/10.1038/s41563-020-00826-y.