Precise tracking of tip-induced structural variation at the single-chemical-bond limit

Sayantan Mahapatra; Nan Jiang

doi:10.1038/s41377-022-01055-5

Go to Nature Website

Your Location：

Home >

Browse articles >

Precise tracking of tip-induced structural variation at the single-chemical-bond limit

News & Views

- Precise tracking of tip-induced structural variation at the single-chemical-bond limit
- Light: Science & Applications Vol. 12, Issue 1, Pages: 15-16(2023)
- Affiliations：
  
  Department of Chemistry, University of Illinois Chicago, Chicago, IL 60607, USA
- Author bio：
  
  Nan Jiang (njiang@uic.edu)
- Funds：
- DOI：10.1038/s41377-022-01055-5
  CLC：
- Published：31 January 2023，
  
  Published Online：11 January 2023，
Scan for full text
Mahapatra, S. & Jiang, N. Precise tracking of tip-induced structural variation at the single-chemical-bond limit. Light: Science & Applications, 12, 15-16 (2023).
DOI：

Mahapatra, S. & Jiang, N. Precise tracking of tip-induced structural variation at the single-chemical-bond limit. Light: Science & Applications, 12, 15-16 (2023). DOI： 10.1038/s41377-022-01055-5.

摘要

Abstract

Sub-nanometer-resolved TERS provides a systematic way for investigating tip-molecule interaction and molecular motions

enabling a promising approach to examine on-surface reaction mechanisms and catalysis at the microscopic level.

关键词

Keywords

references

S. Mahapatra , 等 . Tip-enhanced Raman spectroscopy: chemical analysis with nanoscale to angstrom scale resolution . J. Chem. Phys. , 2020 . 153 010902 DOI:10.1063/5.0009766http://doi.org/10.1063/5.0009766 .

R. Zhang , 等 . Chemical mapping of a single molecule by plasmon-enhanced Raman scattering . Nature , 2013 . 498 82 -86 . DOI:10.1038/nature12151http://doi.org/10.1038/nature12151 .

R. B. Jaculbia , 等 . Single-molecule resonance Raman effect in a plasmonic nanocavity . Nat. Nanotechnol. , 2020 . 15 105 -110 . DOI:10.1038/s41565-019-0614-8http://doi.org/10.1038/s41565-019-0614-8 .

Y. Zhang , 等 . Visually constructing the chemical structure of a single molecule by scanning Raman picoscopy . Natl Sci. Rev. , 2019 . 6 1169 -1175 . DOI:10.1093/nsr/nwz180http://doi.org/10.1093/nsr/nwz180 .

S. Mahapatra , 等 . Angstrom scale chemical analysis of metal supported Trans- and Cis-regioisomers by ultrahigh vacuum tip-enhanced Raman mapping . Nano Lett. , 2019 . 19 3267 -3272 . DOI:10.1021/acs.nanolett.9b00826http://doi.org/10.1021/acs.nanolett.9b00826 .

S. Jiang , 等 . Distinguishing adjacent molecules on a surface using plasmon-enhanced Raman scattering . Nat. Nanotechnol. , 2015 . 10 865 -869 . DOI:10.1038/nnano.2015.170http://doi.org/10.1038/nnano.2015.170 .

L. F. Li , 等 . Angstrom-Scale Spectroscopic Visualization of Interfacial Interactions in an Organic/Borophene Vertical Heterostructure . J. Am. Chem. Soc. , 2021 . 143 15624 -15634 . DOI:10.1021/jacs.1c04380http://doi.org/10.1021/jacs.1c04380 .

J. Y. Xu , 等 . Determining structural and chemical heterogeneities of surface species at the single-bond limit . Science , 2021 . 371 818 -822 . DOI:10.1126/science.abd1827http://doi.org/10.1126/science.abd1827 .

L. F. Li , 等 . Chemically identifying single adatoms with single-bond sensitivity during oxidation reactions of borophene . Nat. Commun. , 2022 . 13 1796 DOI:10.1038/s41467-022-29445-8http://doi.org/10.1038/s41467-022-29445-8 .

T. Kumagai . Sub-molecular photoluminescence . Nat. Photonics , 2020 . 14 653 -655 . DOI:10.1038/s41566-020-00706-6http://doi.org/10.1038/s41566-020-00706-6 .

J. Lee , 等 . Visualizing vibrational normal modes of a single molecule with atomically confined light . Nature , 2019 . 568 78 -82 . DOI:10.1038/s41586-019-1059-9http://doi.org/10.1038/s41586-019-1059-9 .

R. P. Wang , 等 . Raman detection of bond breaking and making of a chemisorbed up-standing single molecule at single-bond level . J. Phys. Chem. Lett. , 2021 . 12 1961 -1968 . DOI:10.1021/acs.jpclett.1c00074http://doi.org/10.1021/acs.jpclett.1c00074 .

Dong, X. R. et al. Tip-induced bond weakening, tilting, and hopping of a single CO molecule on Cu(100). Light Adv. Manuf. 3, 52 (2022).

S. Mahapatra , 等 . Controlling localized plasmons via an atomistic approach: attainment of site-selective activation inside a single molecule . J. Am. Chem. Soc. , 2022 . 144 2051 -2055 . DOI:10.1021/jacs.1c11547http://doi.org/10.1021/jacs.1c11547 .

S. W. Hla , 等 . Inducing all steps of a chemical reaction with the scanning tunneling microscope Tip: towards single molecule engineering . Phys. Rev. Lett. , 2000 . 85 2777 -2780 . DOI:10.1103/PhysRevLett.85.2777http://doi.org/10.1103/PhysRevLett.85.2777 .

I. Stone , 等 . A single-molecule blueprint for synthesis . Nat. Rev. Chem. , 2021 . 5 695 -710 . DOI:10.1038/s41570-021-00316-yhttp://doi.org/10.1038/s41570-021-00316-y .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

No data

Related Author

No data

Related Institution

No data

⁰