Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics

Guillaume Baffou; Ivan Bordacchini; Andrea Baldi; Romain Quidant

doi:10.1038/s41377-020-00345-0

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Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics

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- Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics
- Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics
- LSA 2020年9卷第4期页码：935-950
- Affiliations：
  
  1.Institut Fresnel, CNRS, Aix Marseille University, Centrale Marseille, Marseille, France
  2.ICFO-Institut de Ciències Fotòniques, The Barcelona Institute of Science and Technology, 08860Castelldefels, Barcelona, Spain
  3.DIFFER – Dutch Institute for Fundamental Energy Research, De Zaale 20, 5612 AJ Eindhoven, The Netherlands
  4.Vrije Universiteit Amsterdam, De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands
  5.ICREA-Institució Catalana de Recerca i Estudis Avançats, 08010 Barcelona, Spain
  6.Nanophotonic Systems Laboratory, Department of Mechanical and Process Engineering, ETH Zurich, 8092, Zurich, Switzerland
- Author bio：
  
  Guillaume Baffou (guillaume.baffou@fresnel.fr)
- Funds：
- DOI：10.1038/s41377-020-00345-0
  中图分类号：
- 纸质出版日期：2020，
  
  网络出版日期：2020-06-28，
  
  收稿日期：2020-01-31，
  
  修回日期：2020-05-27，
  
  录用日期：2020-06-08
- Accepted：
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Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics[J]. LSA, 2020,9(4):935-950.

Baffou, G. et al. Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics. Light: Science & Applications, 9, 935-950 (2020).
Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics[J]. LSA, 2020,9(4):935-950. DOI： 10.1038/s41377-020-00345-0.

Baffou, G. et al. Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics. Light: Science & Applications, 9, 935-950 (2020). DOI： 10.1038/s41377-020-00345-0.

摘要

Abstract

Light absorption and scattering of plasmonic metal nanoparticles can lead to non-equilibrium charge carriers

intense electromagnetic near-fields

and heat generation

with promising applications in a vast range of fields

from chemical and physical sensing to nanomedicine and photocatalysis for the sustainable production of fuels and chemicals. Disentangling the relative contribution of thermal and non-thermal contributions in plasmon-driven processes is

however

difficult. Nanoscale temperature measurements are technically challenging

and macroscale experiments are often characterized by collective heating effects

which tend to make the actual temperature increase unpredictable. This work is intended to help the reader experimentally detect and quantify photothermal effects in plasmon-driven chemical reactions

to discriminate their contribution from that due to photochemical processes and to cast a critical eye on the current literature. To this aim

we review

and in some cases propose

seven simple experimental procedures that do not require the use of complex or expensive thermal microscopy techniques. These proposed procedures are adaptable to a wide range of experiments and fields of research where photothermal effects need to be assessed

such as plasmonic-assisted chemistry

heterogeneous catalysis

photovoltaics

biosensing

and enhanced molecular spectroscopy.

关键词

Keywords

references

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