Broadband perovskite quantum dot spectrometer beyond human visual resolution

Xiaoxiu Zhu; Liheng Bian; Hao Fu; Lingxue Wang; Bingsuo Zou; Qionghai Dai; Jun Zhang; Haizheng Zhong

doi:10.1038/s41377-020-0301-4

Go to Nature Website

Your Location：

Home >

Browse articles >

Broadband perovskite quantum dot spectrometer beyond human visual resolution

Original Articles

- Broadband perovskite quantum dot spectrometer beyond human visual resolution
- Broadband perovskite quantum dot spectrometer beyond human visual resolution
- LSA 2020年9卷第3期页码：730-738
- Affiliations：
  
  1.MIIT Key Laboratory for Low-dimensional Quantum Structure and Devices, Beijing Institute of Technology, 100081 Beijing, China
  2.School of Materials Science & Engineering, Beijing Institute of Technology, 100081 Beijing, China
  3.School of Information and Electronics & Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, 100081 Beijing, China
  4.Beijing Key Laboratory of Nanophotonics and Ultrafine Optoelectronic Systems, School of Optics and Photonics, Beijing Institute of Technology, 100081 Beijing, China
  5.Department of Automation & School of Information Science and Technology, Tsinghua University, 100086 Beijing, China
  6.Beijing National Research Center for Information Science and Technology, 100086 Beijing, China
- Author bio：
  
  Liheng Bian (bian@bit.edu.cn)
  Haizheng Zhong (hzzhong@bit.edu.cn)
- Funds：
- DOI：10.1038/s41377-020-0301-4
  中图分类号：
- 纸质出版日期：2020，
  
  网络出版日期：2020-04-29，
  
  收稿日期：2020-02-26，
  
  修回日期：2020-03-15，
  
  录用日期：2020-03-23
- Accepted：
Scan QR Code
Broadband perovskite quantum dot spectrometer beyond human visual resolution[J]. LSA, 2020,9(3):730-738.

Zhu, X. X. et al. Broadband perovskite quantum dot spectrometer beyond human visual resolution. Light: Science & Applications, 9, 730-738 (2020).
Broadband perovskite quantum dot spectrometer beyond human visual resolution[J]. LSA, 2020,9(3):730-738. DOI： 10.1038/s41377-020-0301-4.

Zhu, X. X. et al. Broadband perovskite quantum dot spectrometer beyond human visual resolution. Light: Science & Applications, 9, 730-738 (2020). DOI： 10.1038/s41377-020-0301-4.

摘要

Abstract

The quantum dot spectrometer

fabricated by integrating different quantum dots with an image sensor to reconstruct the target spectrum from spectral-coupled measurements

is an emerging and promising hyperspectrometry technology with high resolution and a compact size. The spectral resolution and spectral range of quantum dot spectrometers have been limited by the spectral variety of the available quantum dots and the robustness of algorithmic reconstruction. Moreover

the spectrometer integration of quantum dots also suffers from inherent photoluminescence emission and poor batch-to-batch repeatability. In this work

we developed nonemissive in situ fabricated MA

and Cs

SnX

(MA = CH

;

= Cl

I) perovskite-quantum-dot-embedded films (PQDFs) with precisely tunable transmittance spectra for quantum dot spectrometer applications. The resulting PQDFs contain in situ fabricated perovskite nanocrystals with homogenous dispersion in a polymeric matrix

giving them advantageous features such as high transmittance efficiency and good batch-to-batch repeatability. By integrating a filter array of 361 kinds of PQDFs with a silicon-based photodetector array

we successfully demonstrated the construction of a perovskite quantum dot spectrometer combined with a compressive-sensing-based total-variation optimization algorithm. A spectral resolution of ~1.6 nm was achieved in the

broadband of 250–1000 nm. The performance of the perovskite quantum dot spectrometer is well beyond that of human eyes in terms of both the spectral range and spectral resolution. This advancement will not only pave the way for using quantum dot spectrometers for practical applications but also significantly impact the development of artificial intelligence products

clinical treatment equipment

scientific instruments

etc.

关键词

Keywords

references

Bacon, C. P., Mattley, Y.&DeFrece, R. Miniature spectroscopic instrumentation: applications to biology and chemistry.Rev. Sci. Instrum.75, 1–16 (2004)..

Li, Q. T. et al. Transparent multispectral photodetectors mimicking the human visual system.Nat. Commun.10, 4982 (2019)..

Khorasaninejad, M. et al. Metalenses at visible wavelengths: diffraction-limited focusing and subwavelength resolution imaging.Science352, 1190–1194 (2016)..

Yakunin, S. et al. Non-dissipative internal optical filtering with solution-grown perovskite single crystals for full-colour imaging.NPG Asia.Materials9, e431 (2017)..

Goossens, S. et al. Broadband image sensor array based on graphene–CMOS integration.Nat. Photonics11, 366–371 (2017)..

Park, H. L.et al. Retina-inspired carbon nitride-based photonic synapses for selective detection of UV light.Adv. Mater.https://doi.org/10.1002/adma.201906899https://doi.org/10.1002/adma.201906899(2020)...

Fischer, C.&Kakoulli, I. Multispectral and hyperspectral imaging technologies in conservation: current research and potential applications.Stud. Conserv.51, 3–16 (2006)..

Khan, M. J. et al. Modern trends in hyperspectral image analysis: a review.IEEE Access6, 14118–14129 (2018)..

McGonigle, A. J. S. et al. Smartphone spectrometers.Sensors18, 223 (2018)..

Chen, Q. et al. Nanophotonic image sensors.Small12, 4922–4935 (2016)..

Kim, S. H. et al. Integration of colloidal photonic crystals toward miniaturized spectrometers.Adv. Mater.22, 946–950 (2010)..

Bryan, K. M. et al. Inexpensive photonic crystal spectrometer for colorimetric sensing applications.Opt. Express21, 4411–4423 (2013)..

Xu, T. et al. Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging.Nat. Commun.1, 59 (2010)..

Yokogawa, S., Burgos, S. P.&Atwater, H. A. Plasmonic color filters for CMOS image sensor applications.Nano Lett.12, 4349–4354 (2012)..

Zheng, B. Y. et al. Color-selective and CMOS-compatible photodetection based on aluminum plasmonics.Adv. Mater.26, 6318–6323 (2014)..

Jang, W. Y. et al. Experimental demonstration of adaptive infrared multispectral imaging using plasmonic filter array.Sci. Rep.6, 34876 (2016)..

Duempelmann, L., Gallinet, B.&Novotny, L. Multispectral imaging with tunable plasmonic filters.ACS Photonics4, 236–241 (2017)..

Kanamori, Y., Shimono, M.&Hane, K. Fabrication of transmission color filters using silicon subwavelength gratings on quartz substrates.IEEE Photonics Technol. Lett.18, 2126–2128 (2006)..

Horie, Y. et al. Visible wavelength color filters using dielectric subwavelength gratings for backside-illuminated CMOS image sensor technologies.Nano Lett.17, 3159–3164 (2017)..

Yang, Z. Y. et al. Single-nanowire spectrometers.Science365, 1017–1020 (2019)..

Bao, J.&Bawendi, M. G. A colloidal quantum dot spectrometer.Nature523, 67–70 (2015)..

Khan, S. A.&Ellerbee Bowden, A. K. Colloidal quantum dots for cost-effective, miniaturized, and simple spectrometers.Clin. Chem.62, 548–550 (2016)..

Shirasaki, Y. et al. Emergence of colloidal quantum-dot light-emitting technologies.Nat. Photonics7, 13–23 (2013)..

Saran, R.&Curry, R. J. Lead sulphide nanocrystal photodetector technologies.Nat. Photonics10, 81–92 (2016)..

Wright, W. D.&Pitt, F. H. G. Hue-discrimination in normal colour-vision.Proc. Phys. Soc.46, 459–473 (1934)..

Glover, J. H. Chemiluminescence in gas analysis and flame-emission spectrometry. A review.Analyst100, 449–464 (1975)..

Winefordner, J. D.&Vickers, T. J. Flame spectrometry.Anal. Chem.44, 150–182 (1972)..

Zawisza, B. et al. Determination of rare earth elements by spectroscopic techniques: a review.J. Anal. At. Spectrom.26, 2373–2390 (2011)..

Protesescu, L. et al. Nanocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br and I): novel optoelectronic materials showing bright emission with wide color gamut.Nano Lett.15, 3692–3696 (2015)..

Zhang, F. et al. Brightly luminescent and color-tunable colloidal CH3NH3PbX3(X = Br, I, Cl) quantum dots: potential alternatives for display technology.ACS Nano9, 4533–4542 (2015)..

Song, J. Z. et al. Quantum dot light‐emitting diodes based on inorganic perovskite cesium lead halides (CsPbX3).Adv. Mater.27, 7162–7167 (2015)..

Zhou, Q. C. et al. In situ fabrication of halide perovskite nanocrystal-embedded polymer composite films with enhanced photoluminescence for display backlights.Adv. Mater.28, 9163–9168 (2016)..

Wang, Y. N. et al. Ultrastable, highly luminescent organic–inorganic perovskite–polymer composite films.Adv. Mater.28, 10710–10717 (2016)..

Chang, S., Bai, Z. L.&Zhong, H. Z. In situ fabricated perovskite nanocrystals: a revolution in optical materials.Adv. Opt. Mater.6, 1800380 (2018)..

Jung, B. et al. Effect of crystallization and annealing on polyacrylonitrile membranes for ultrafiltration.J. Membr. Sci.246, 67–76 (2005)..

Leng, M. Y. et al. Lead-free, blue emitting bismuth halide perovskite quantum dots.Angew. Chem. Int. Ed.55, 15012–15016 (2016)..

Lee, B. et al. Solution processing of air-stable molecular semiconducting iodosalts, Cs2SnI6-xBrx, for potential solar cell applications.Sustain. Energy Fuels1, 710–724 (2017)..

Saparov, B. et al. Thin-film deposition and characterization of a Sn-deficient perovskite derivative Cs2SnI6.Chem. Mater.28, 2315–2322 (2016)..

Southwell, W. H.&Hall, R. L. Rugate filter sidelobe suppression using quintic and rugated quintic matching layers.Appl. Opt.28, 2949–2951 (1989)..

Hoye, R. L. Z. et al. Methylammonium bismuth iodide as a lead-free, stable hybrid organic–inorganic solar absorber.Chem.—A Eur. J.22, 2605–2610 (2016)..

Donoho, D. L. Compressed sensing.IEEE Trans. Inf. Theory52, 1289–1306 (2006)..

Candès, E. J., Romberg, J. K.&Tao, T. Stable signal recovery from incomplete and inaccurate measurements.Commun. Pure Appl. Math.59, 1207–1223 (2006)..

Candès, E. J.&Wakin, M. B. An introduction to compressive sampling.IEEE Signal Process. Mag.25, 21–30 (2008)..

Lin, Z. C., Liu, R. S.&Su, Z. X. Linearized alternating direction method with adaptive penalty for low-rank representation. InProc. Advances in Neural Information Processing Systems24 (eds Shawe-Taylor, J., Zemel, R. S., Bartlett, P. L., Pereira, F.&Weinberger, K. Q.) 612–620 (Curran Associates Inc., Red Hook, 2011).

Suo, J. L. et al. Joint non-Gaussian denoising and superresolving of raw high frame rate videos.IEEE Trans. Image Process.23, 1154–1168 (2014)..

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

暂无数据