1.State Key Laboratory of Integrated Optoelectronics, College of Electronics Science and Engineering, Jilin University, 130012 Changchun, China
2.Department of Engineering Science and Mechanics, Department of Biomedical Engineering, Materials Research Institute, Pennsylvania State University, 16802 University Park, USA
Wenfa Xie (xiewf@jlu.edu.cn)
Cunjiang Yu (cmy5358@psu.edu)
纸质出版日期:2022-03-31,
网络出版日期:2022-03-14,
收稿日期:2021-10-20,
修回日期:2022-02-28,
录用日期:2022-03-02
Scan QR Code
A flexible, multifunctional, optoelectronic anticounterfeiting device from high-performance organic light-emitting paper[J]. LSA, 2022,11(3):431-441.
Pan, T. et al. A flexible, multifunctional, optoelectronic anticounterfeiting device from high-performance organic light-emitting paper. Light: Science & Applications, 11, 431-441 (2022).
A flexible, multifunctional, optoelectronic anticounterfeiting device from high-performance organic light-emitting paper[J]. LSA, 2022,11(3):431-441. DOI: 10.1038/s41377-022-00760-5.
Pan, T. et al. A flexible, multifunctional, optoelectronic anticounterfeiting device from high-performance organic light-emitting paper. Light: Science & Applications, 11, 431-441 (2022). DOI: 10.1038/s41377-022-00760-5.
As a primary anticounterfeiting technology
most paper anticounterfeiting devices take advantage of photoresponsive behaviors of certain security materials or structures
thus featuring low-security threshold
which has been a critical global issue. To incorporate optoelectronic devices into existing anticounterfeiting technology suggests a feasible avenue to address this challenge. Here we report a high-performance organic light-emitting paper-based flexible anticounterfeiting (FAC) device with multiple stimuli-responsiveness
including light
electricity
and their combination. Without sacrificing the preexisted security information on the paper
we fabricate FAC device in a facile
low-cost yet high-fidelity fashion by integrating patterned electro-responsive and photo-responsive organic emitters onto paper substrates. By introducin
g optical microcavities
the FAC device shows considerable color shift upon different viewing angle and applied voltage
which is easily discernible by naked eyes. Notably
the FAC device is bendable
unclonable
and durable (a half-lifetime over 4000 hours at 100 cd m
−2
).
Ren, W. et al. Optical nanomaterials and enabling technologies for high-security-level anticounterfeiting.Adv. Mater.32, 1901430 (2020)..
Hu, Z. Y. et al. Physically unclonable cryptographic primitives using self-assembled carbon nanotubes.Nat. Nanotechnol.11, 559–565 (2016)..
Tang, G. S. et al. Faithful fabrication of biocompatible multicompartmental memomicrospheres for digitally color-tunable barcoding.Small16, 1907586 (2020)..
Zeng, Z. C. et al. Multimodal luminescent Yb3+/Er3+/Bi3+-doped perovskite single crystals for X-ray detection and anti-counterfeiting.Adv. Mater.32, 2004506 (2020)..
Shi, L. F. et al. In situ inkjet printing strategy for fabricating perovskite quantum dot patterns.Adv. Funct. Mater.29, 1903648 (2019)..
Zhang, Y. C. et al. 3D fluorescent hydrogel origami for multistage data security protection.Adv. Funct. Mater.29, 1905514 (2019)..
Arppe, R.&Sorensen, T. J. Physical unclonable functions generated through chemical methods for anti-counterfeiting.Nat. Rev. Chem.1, 0031 (2017)..
Li, W. Y. et al. Inkjet printing of patterned, multispectral, and biocompatible photonic crystals.Adv. Mater.31, 1901036 (2019)..
Duan, X. Y., Kamin, S.&Liu, N. Dynamic plasmonic colour display.Nat. Commun.8, 14606(2017)..
Ding, M. Y. et al. Energy manipulation in lanthanide-doped core-shell nanoparticles for tunable dual-mode luminescence toward advanced anti-counterfeiting.Adv. Mater.32, 2002121 (2020)..
Lim, K. T. P. et al. Holographic colour prints for enhanced optical security by combined phase and amplitude control.Nat. Commun.10, 25 (2019)..
Hu, H. B. et al. Magnetically responsive photonic watermarks on banknotes.J. Mater. Chem. C.2, 3695–3702 (2014)..
Liu, Y. et al. Inkjet-printed unclonable quantum dot fluorescent anti-counterfeiting labels with artificial intelligence authentication.Nat. Commun.10, 2409 (2019)..
Liu, J. C. et al. Carbon dots in zeolites: a new class of thermally activated delayed fluorescence materials with ultralong lifetimes.Sci. Adv.3, e1603171 (2017)..
Liu, X. W. et al. Binary temporal upconversion codes of Mn2+-activated nanoparticles for multilevel anti-counterfeiting.Nat. Commun.8, 899 (2017)..
Yang, Y. M. et al. X-ray-activated long persistent phosphors featuring strong UVC afterglow emissions.Light. : Sci. Appl.7, 88 (2018)..
Wu, C. et al. Efficient mechanoluminescent elastomers for dual-responsive anticounterfeiting device and stretching/strain sensor with multimode sensibility.Adv. Funct. Mater.28, 1803168 (2018)..
Abdollahi, A. et al. Photoluminescent and chromic nanomaterials for anticounterfeiting technologies: recent advances and future challenges.ACS Nano14, 14417–14492 (2020)..
Cao, L. Y. et al. Efficient and stable organic light-emitting devices employing phosphorescent molecular aggregates.Nat. Photonics15, 230–237 (2021)..
Chan, C. Y. et al. Stable pure-blue hyperfluorescence organic light-emitting diodes with high-efficiency and narrow emission.Nat. Photonics15, 203–207 (2021)..
Zang, C. X. et al. Top-emitting thermally activated delayed fluorescence organic light-emitting devices with weak light-matter coupling.Light. Sci. Appl.10, 116 (2021)..
Liu, S. H. et al. Air-stable ultrabright inverted organic light-emitting devices with metal ion-chelated polymer injection layer.Nano-Micro. Lett.14, 14 (2022)..
Purandare, S., Gomez, E. F.&Steckl, A. J. High brightness phosphorescent organic light emitting diodes on transparent and flexible cellulose films.Nanotechnology25, 094012 (2014)..
Yoon, D. Y.&Moon, D. G. Bright flexible organic light-emitting devices on copy paper substrates.Curr. Appl. Phys.12, e29–e32 (2012)..
Legnani, C. et al. Bacterial cellulose membrane as flexible substrate for organic light emitting devices.Thin Solid Films517, 1016–1020 (2008)..
Jin, J. et al. Chitin nanofiber transparent paper for flexible green electronics.Adv. Mater.28, 5169–5175 (2016)..
Yao, Y. G. et al. Light management in plastic-paper hybrid substrate towards high-performance optoelectronics.Energy Environ. Sci.9, 2278–2285 (2016)..
Gomez, E. F.&Steckl, A. J. Improved performance of OLEDs on cellulose/epoxy substrate using adenine as a hole injection layer.ACS Photonics2, 439–445 (2015)..
Huang, Q. B. et al. Highly smooth, stable and reflective Ag-paper electrode enabled by silver mirror reaction for organic optoelectronics.Chem. Eng. J.370, 1048–1056 (2019)..
Kim, S.&Hwang, B. Ag nanowire electrode with patterned dry film photoresist insulator for flexible organic light-emitting diode with various designs.Mater. Des.160, 572–577 (2018)..
Kim, K. B. et al. Relationship between surface roughness of indium Tin oxide and leakage current of organic light-emitting diode.Jpn. J. Appl. Phys.42, L438–L440 (2003)..
Jonda, C. et al. Surface roughness effects and their influence on the degradation of organic light emitting devices.J. Mater. Sci.35, 5645–5651 (2000)..
Ueno, S. et al. A new wettability-control technique for fabricating color OLED panels by an ink-jet-printing method.J. Soc. Inf. Disp.19, 87–93 (2011)..
Wang, M., Wang, D.&Schaaf, P. Layer thickness effect on fracture behavior of Al/Si3N4multilayer on Si substrate under three-point bending.Appl. Surf. Sci.445, 563–567 (2018)..
Mujika, F. On the difference between flexural moduli obtained by three-point and four-point bending tests.Polym. Test.25, 214–220 (2006)..
Mujika, F. et al. New correction terms concerning three-point and four-point bending tests.Polym. Test.55, 25–37 (2016)..
Wang, M., Porter, D.&Bonfield, W. Processing, characterisation, and evaluation of hydroxyapatite reinforced polyethylene composites.Br. Ceram. Trans.93, 91–95 (1994)..
Yamamoto, S. et al. Relationship between adsorbed fibronectin and cell adhesion on a honeycomb-patterned film.Surf. Sci.600, 3785–3791(2006)..
Gupta, B. S., Reiniati, I.&Laborie, M. P. G. Surface properties and adhesion of wood fiber reinforced thermoplastic composites.Colloids Surf. A Physicochem. Eng. Asp.302, 388–395 (2007)..
Lee, S. et al. Tuning the energy level of TAPC: crystal structure and photophysical and electrochemical properties of 4, 4'-(cyclohexane-1, 1-diyl) bis[N, N-bis(4-methoxyphenyl)aniline].Acta Crystallogr. Sect. C Struct. Chem.75, 919–926 (2019)..
Woon, K. L. et al. Conformational distortion in solution processable PVK: TcTa blends and the effect on extra warm white organic phosphorescent light emitting diodes.Org. Electron.74, 1–6 (2019)..
Han, J. et al. Highly enhanced phosphorescent organic light emitting diodes with cesium fluoride doped electron injection layer.Proc. SPIE9566, 95662E (2015)..
MacAdam, D. L. Visual sensitivities to color differences in daylight.J. Opt. Soc. Am.32, 247–274 (1942)..
Pan, T. et al. Flexible organic optoelectronic devices on paper.iScience25, 103782 (2022)..
0
浏览量
0
Downloads
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621