Highly efficient Fe3+-doped A2<italic style="font-style: italic">BB</italic>′O6 (<italic style="font-style: italic">A</italic> = Sr2+, Ca2+; <italic style="font-style: italic">B</italic>, <italic style="font-style: italic">B</italic>′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis

Dongjie Liu; Guogang Li; Peipei Dang; Qianqian Zhang; Yi Wei; Lei Qiu; Maxim S. Molokeev; Hongzhou Lian; Mengmeng Shang; Jun Lin

doi:10.1038/s41377-022-00803-x

Go to Nature Website

Your Location：

Home >

Browse articles >

Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis

Articles

- Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis
- Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis
- LSA 2022年11卷第5期页码：969-978
- Affiliations：
  
  1.State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022, Changchun, China
  2.University of Science and Technology of China, 230026, Hefei, China
  3.Faculty of Materials Science and Chemistry, China University of Geosciences, 430074, Wuhan, China
  4.Zhejiang Institute, China University of Geosciences, 311305, Hangzhou, China
  5.Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
  6.Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660041, Russia
  7.Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russia
  8.School of Material Science and Engineering, Shandong University, 266071, Jinan, China
- Author bio：
  
  Guogang Li (ggli@cug.edu.cn)
  Jun Lin (jlin@ciac.ac.cn)
- Funds：
- DOI：10.1038/s41377-022-00803-x
  中图分类号：
- 纸质出版日期：2022-05-31，
  
  网络出版日期：2022-04-27，
  
  收稿日期：2022-02-25，
  
  修回日期：2022-04-02，
  
  录用日期：2022-04-14
- Accepted：
Scan QR Code
Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis[J]. LSA, 2022,11(5):969-978.

Liu, D. J. et al. Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis. Light: Science & Applications, 11, 969-978 (2022).
Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis[J]. LSA, 2022,11(5):969-978. DOI： 10.1038/s41377-022-00803-x.

Liu, D. J. et al. Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis. Light: Science & Applications, 11, 969-978 (2022). DOI： 10.1038/s41377-022-00803-x.

摘要

Abstract

Near-infrared (NIR)-emitting phosphor-converted light-emitting diodes have attracted widespread attention in various applications based on NIR spectroscopy. Except for typical Cr

-activated NIR-emitting phosphors

next-generation Cr

-free NIR-emitting phosphors with high efficiency and tunable optical properties are highly desired to enrich the types of NIR luminescent materials for different application fields. Here

we report the Fe

-activated Sr

2−

(InSb)

1−

phosphors that exhibit unprecedented long-wavelength NIR emission. The overall emission tuning from 885 to 1005 nm with broadened full-width at half maximum from 108 to 146 nm was realized through a crystallographic site engineering strategy. The NIR emission was significantly enhanced after complete Ca

incorporation owing to the substitution-induced lower symmetry of the Fe

sites. The Ca

InSbO

: Fe

phosphor peaking at 935 nm showed an ultra-high internal quantum efficiency of 87%. The as-synthesized emission-tunable phosphors demonstrated great potential for NIR spectroscopy detection. This work initiates the development of efficient Fe

-activated broadband NIR-emitting phosphors and opens up a new avenue for designing NIR-emitting phosphor materials.

关键词

Keywords

references

Huang, W. T. et al. Near-infrared nanophosphor embedded in mesoporous silica nanoparticle with high light-harvesting efficiency for dual photosystem enhancement.Angew. Chem. Int. Ed.60, 6955–6959 (2021)..

Zhang, L. L. et al. Cr3+-doped broadband NIR garnet phosphor with enhanced luminescence and its application in NIR spectroscopy.Adv. Opt. Mater.7, 1900185 (2019)..

Mao, M. Q. et al. Broadband near-infrared (NIR) emission realized by the crystal-field engineering of Y3−xCaxAl5−xSixO12: Cr3+(x= 0–2.0) garnet phosphors.J. Mater. Chem. C8, 1981–1988 (2020)..

Xie, R. J. Light-emitting diodes: brighter NIR-emitting phosphor making light sources smarter.Light.: Sci. Appl.9, 155 (2020)..

Zhao, F. Y. et al. Structural confinement for Cr3+activators toward efficient near-infrared phosphors with suppressed concentration quenching.Chem. Mater.33, 3621–3630 (2021)..

Zeng, H. T. et al. Two-site occupation for exploring ultra-broadband near-infrared phosphor-double-perovskite La2MgZrO6: Cr3+.Chem. Mater.31, 5245–5253 (2019)..

Liu, G. C. et al. Li/Na substitution and Yb3+co-doping enabling tunable near-infrared emission in LiIn2SbO6: Cr3+phosphors for light-emitting diodes.iScience24, 102250 (2021)..

Rajendran, V. et al. Super broadband near-infrared phosphors with high radiant flux as future light sources for spectroscopy applications.ACS Energy Lett.3, 2679–2684 (2018)..

Jia, Z. W. et al. Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources.Light.: Sci. Appl.9, 86 (2020)..

Zhou, X. F. et al. An Ultraviolet-visible and near-infrared-responded broadband NIR phosphor and its NIR spectroscopy application.Adv. Opt. Mater.8, 1902003 (2020)..

Liu, G. C. et al. Two-site Cr3+occupation in the MgTa2O6: Cr3+phosphor toward broad-band near-infrared emission for vessel visualization.J. Mater. Chem. C8, 9322–9328 (2020)..

Liu, D. J. et al. Simultaneous broadening and enhancement of Cr3+photoluminescence in LiIn2SbO6by chemical unit cosubstitution: night-vision and near-infrared spectroscopy detection applications.Angew. Chem. Int. Ed.60, 14644–14649 (2021)..

Cai, H. et al. Tuning luminescence from NIR-Ⅰ to NIR-Ⅱ in Cr3+-doped olivine phosphors for nondestructive analysis.J. Mater. Chem. C9, 5469–5477 (2021)..

Fang, M. H. et al. Hidden structural evolution and bond valence control in near-infrared phosphors for light-emitting diodes.ACS Energy Lett.6, 109–114 (2021)..

Qiao, J. W. et al. Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes.Nat. Commun.10, 5267 (2019)..

Wei, Y. et al. Advances in near-infrared luminescent materials without Cr3+: crystal structure design, luminescence properties, and applications.Chem. Mater.33, 5496–5526 (2021)..

Zhang, Q. et al. A K3ScSi2O7: Eu2+based phosphor with broad-band NIR emission and robust thermal stability for NIR pc-LEDs.Chem. Commun.56, 4644–4647 (2020)..

Zhou, Z. H. et al. Cr3+-Free near-infrared persistent luminescence material LiGaO2: Fe3+: optical properties, afterglow mechanism and potential bioimaging.J. Mater. Chem. C8, 14100–14108 (2020)..

Song, E. H. et al. Heavy Mn2+doped MgAl2O4phosphor for high-efficient near-infrared light-emitting diode and the night-vision application.Adv. Opt. Mater.7, 1901105 (2019)..

Que, E. L., Domaille, D. W.&Chang, C. J. Metals in neurobiology: probing their chemistry and biology with molecular imaging.Chem. Rev.108, 1517–1549 (2008)..

Zhou, Z. H. et al. Defect enrichment in near inverse spinel configuration to enhance the persistent luminescence of Fe3+.Adv. Opt. Mater.10, 2101669 (2021)..

Takahashi, H. A. et al. Fe3+red phosphors based on lithium aluminates and an aluminum lithium oxyfluoride prepared from LiF as the Li Source.J. Lumin.182, 53–58 (2017)..

Shu, W. et al. Enhanced red emission in LiAl5O8: Fe3+phosphor by B3+doping.J. Alloy. Compd.509, 3886–3888 (2011)..

Van Schaik, W.&Blasse, G. Luminescence of Fe3+in LaPO4.J. Alloy. Compd.198, 69–72 (1993)..

Soppin, K.&Manohara, B. M. CdSiO3: Fe3+nanophosphors: structural and luminescence properties.Bull. Mater. Sci.44, 49 (2021)..

Kniec, K. et al. From quencher to potent activator – Multimodal luminescence thermometry with Fe3+in the oxides MAl4O7(M = Ca, Sr, Ba).J. Mater. Chem. C9, 6268–6276 (2021)..

Li, Y. J. et al. Site-related near-infrared luminescence in MAl12O19(M=Ca, Sr, Ba): Fe3+phosphors.Mater. Res. Bull.51, 1–5 (2014)..

Zeng, J. W. et al. In-situ Insights into trap attributions in Fe3+-activated long persistent phosphors.J. Lumin.232, 117810 (2021)..

Kniec, K. et al. Spectral and thermometric properties altering through crystal field strength modification and host material composition in luminescence thermometers based on Fe3+doped AB2O4type nanocrystals (A = Mg, Ca; B = Al, Ga).J. Mater. Chem. C9, 517–527 (2021)..

Lin, L. T. Comment on "oxygen-vacancy-induced Midgap states responsible for the fluorescence and the long-lasting phosphorescence of the inverse Spinel Mg(Mg, Sn)O4".Chem. Mater.32, 7564–7567 (2020)..

Pott, G. T.&McNicol, B. D. The luminescence of Fe3+and Cr3+in α-gallia.J. Lumin.6, 225–228 (1973)..

Xie, Y. et al. Luminescence of a novel double-perovskite Sr2InSbO6: Eu3+orange-red-emitting phosphor for white LEDs and visualization of latent fingerprints.Mater. Res. Bull.146, 111574 (2022)..

Zhao, F. Y. et al. Double perovskite Cs2AgInCl6: Cr3+: broadband and near-infrared luminescent materials.Inorg. Chem. Front.6, 3621–3628 (2019)..

Zhong, J. Y. et al. Efficient and Tunable Luminescence in Ga2-xInxO3: Cr3+for Near-Infrared Imaging.ACS Appl. Mater. Interfaces13, 31835–31842 (2021)..

Xu, X. X. et al. Highly efficient and thermally stable Cr3+-activated silicate phosphors for broadband near-infrared LED applications.Chem. Eng. J.383, 123108 (2020)..

Cai, C. Y. et al. Microwave dielectric properties of Ca1-xSrxMgSi2O6ceramics.Ceram. Int.46, 27679–27685 (2020)..

Dias, A. et al. Raman-spectroscopic investigation of Ba2InTaO6and Sr2InTaO6perovskites.J. Solid State Chem.180, 2143–2148 (2007)..

Vijayakumar, C. et al. FT-Raman and FT-IR vibrational spectroscopic studies of nanocrystalline Ba2RESbO6(RE=Sm, Gd, Dy and Y) perovskites.J. Alloy. Compd.480, 167–170 (2009)..

Halder, S. et al. Octahedral distortion induced phonon vibration and electrical conduction in A2NdSbO6(A = Ba, Sr, Ca).Mater. Chem. Phys.199, 508–521 (2017)..

Liu, Y. F. et al. An excellent cyan-emitting orthosilicate phosphor for NUV-pumped white LED application.J. Mater. Chem. C5, 12365–12377 (2017)..

Zhong, C. S. et al. Novel broadband near-infrared emitting phosphor LiGe2(PO4)3: Cr3+with tuning and enhancement of NIR emission by codoping Sb5+.J. Alloy. Compd.903, 163945 (2022)..

Yu, D. C. et al. Non-rare-earth Na3AlF6: Cr3+phosphors for far-red light-emitting diodes.ACS Appl. Electron. Mater.1, 2325–2333 (2019)..

De Guzman, G. N. A. et al. Multi-site cation control of ultra-broadband near-infrared phosphors for application in light-emitting diodes.Inorg. Chem.59, 15101–15110 (2020)..

Shao, Q. Y. et al. Photoluminescence properties of a ScBO3: Cr3+phosphor and its applications for broadband near-infrared LEDs.RSC Adv.8, 12035–12042 (2018)..

Mao, N. et al. A broadband near-infrared phosphor Ca3Y2Ge3O12: Cr3+with garnet structure.J. Alloy. Compd.863, 158699 (2021)..

Malysa, B., Meijerink, A.&Jüstel, T. Temperature dependent Cr3+photoluminescence in garnets of the type X3Sc2Ga3O12(X = Lu, Y, Gd, La).J. Lumin.202, 523–531 (2018)..

Lai, J. A. et al. Broadband near-infrared emission enhancement in K2Ga2Sn6O16: Cr3+phosphor by electron-lattice coupling regulation.J. Am. Ceram. Soc.103, 5067–5075 (2020)..

Gao, T. Y. et al. Design of a broadband NIR phosphor for security-monitoring LEDs: tunable photoluminescence properties and enhanced thermal stability.Cryst. Growth Des.20, 3851–3860 (2020)..

Yao, L. Q. et al. Enhancing near-infrared photoluminescence intensity and spectral properties in Yb3+codoped LiScP2O7: Cr3+.Chem. Mater.32, 2430–2439 (2020)..

Dai, D. J. et al. Broad band emission near-infrared material Mg3Ga2GeO8: Cr3+: substitution of Ga-In, structural modification, luminescence property and application for high efficiency LED.J. Alloy. Compd.806, 926–938 (2019)..

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

高效率Fe³⁺掺杂宽带近红外荧光粉用于光谱分析

暂无数据

Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis

Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis

DOI：10.1038/s41377-022-00803-x

摘要

Abstract

关键词

Keywords

references

Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis

Highly efficient Fe³⁺-doped A₂BB′O₆ (A = Sr²⁺, Ca²⁺; B, B′ = In³⁺, Sb⁵⁺, Sn⁴⁺) broadband near-infrared-emitting phosphors for spectroscopic analysis