Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage

Yao Xie; Yapai Song; Guotao Sun; Pengfei Hu; Artur Bednarkiewicz; Lining Sun

doi:10.1038/s41377-022-00813-9

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Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage

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- Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage
- Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage
- LSA 2022年11卷第6期页码：1264-1273
- Affiliations：
  
  1.Department of Physics, College of Sciences, Shanghai University, Shanghai 200444, China
  2.Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China
  3.School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
  4.Research Center of Nano Science and Technology, College of Sciences, Shanghai University, Shanghai 200444, China
  5.Instrumental Analysis & Research Center, Shanghai University, Shanghai 200444, China
  6.Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-422 Wrocław, Poland
- Author bio：
  
  Lining Sun (lnsun@shu.edu.cn)
- Funds：
- DOI：10.1038/s41377-022-00813-9
  中图分类号：
- 纸质出版日期：2022-06-30，
  
  网络出版日期：2022-05-20，
  
  收稿日期：2022-02-08，
  
  修回日期：2022-04-12，
  
  录用日期：2022-04-22
- Accepted：
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Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage[J]. LSA, 2022,11(6):1264-1273.

Xie, Y. et al. Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage. Light: Science & Applications, 11, 1264-1273 (2022).
Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage[J]. LSA, 2022,11(6):1264-1273. DOI： 10.1038/s41377-022-00813-9.

Xie, Y. et al. Lanthanide-doped heterostructured nanocomposites toward advanced optical anti-counterfeiting and information storage. Light: Science & Applications, 11, 1264-1273 (2022). DOI： 10.1038/s41377-022-00813-9.

摘要

Abstract

The continuously growing importance of information storage

transmission

and authentication impose many new demands and challenges for modern nano-photonic materials and information storage technologies

both in security and storage capacity. Recently

luminescent lanthanide-doped

nanomaterials have drawn much attention in this field because of their photostability

multimodal/multicolor/narrowband emissions

and long luminescence lifetime. Here

we report a multimodal nanocomposite composed of lanthanide-doped upconverting nanoparticle and EuSe semiconductor

which was constructed by utilizing a cation exchange strategy. The nanocomposite can emit blue and white light under 365 and 394 nm excitation

respectively. Meanwhile

the nanocomposites show different colors under 980 nm laser excitation when the content of Tb

ions is changed in the upconversion nanoparticles. Moreover

the time-gating technology is used to filter the upconversion emission of a long lifetime from Tb

or Eu

and the possibilities for modulating the emission color of the nanocomposites are further expanded. Based on the advantage of multiple tunable luminescence

the nanocomposites are designed as optical modules to load optical information. This work enables multi-dimensional storage of information and provides new insights into the design and fabrication of next-generation storage materials.

关键词

Keywords

references

Gu, M., Li, X. P.&Cao, Y. Y. Optical storage arrays: a perspective for future big data storage.Light Sci. Appl.3, e177 (2014)..

Lin, S. S. et al. High-security-level multi-dimensional optical storage medium: nanostructured glass embedded with LiGa5O8: Mn2+with photostimulated luminescence.Light Sci. Appl.9, 22 (2020)..

Zijlstra, P., Chon, J. W. M.&Gu, M. Five-dimensional optical recording mediated by surface plasmons in gold nanorods.Nature459, 410–413 (2009)..

Li, Z. W. et al. Creation and reconstruction of thermochromic Au nanorods with surface concavity.J. Am. Chem. Soc.143, 15791–15799 (2021)..

Bae, J. et al. 3D-printed quantum dot nanopixels.ACS Nano14, 10993–11001 (2020)..

Song, Z. P. et al. Invisible security ink based on water-soluble graphitic carbon nitride quantum dots.Angew. Chem. Int. Ed.55, 2773–2777 (2016)..

Huang, X. J. et al. Reversible 3D laser printing of perovskite quantum dots inside a transparent medium.Nat. Photonics14, 82–88 (2020)..

Du, K. M. et al. Embellishment of upconversion nanoparticles with ultrasmall perovskite quantum dots for full‐color tunable, dual‐modal luminescence anticounterfeiting.Adv. Optical Mater.9, 2100814 (2021)..

Li, Z. Q. et al. Loading photochromic molecules into a luminescent metal-organic framework for information anticounterfeiting.Angew. Chem. Int. Ed.58, 18025–18031 (2019)..

Da Luz, L. L. et al. Inkjet printing of lanthanide-organic frameworks for anti-counterfeiting applications.ACS Appl. Mater. Interfaces7, 27115–27123 (2015)..

Ding, W. et al. Multicolour barcoding in one MOF crystal through rational postsynthetic transmetalation.J. Mater. Chem. C.8, 3176–3182 (2020)..

Zhang, P. et al. Tuning the photoluminescence of lanthanide metal–organic framework nanospheres through ligand-induced phase transition towards sensing.J. Mater. Chem. C.9, 6208–6216 (2021)..

Li, D., Yang, X. G.&Yan, D. P. Cluster-based metal-organic frameworks: modulated singlet-triplet excited states and temperature-responsive phosphorescent switch.ACS Appl. Mater. Interfaces10, 34377–34384 (2018)..

Ju, L. et al. A new absorption/fluorescence dual-mode hydrochromic dye for water-jet printing and anti-counterfeiting applications.J. Mater. Chem. C.8, 2806–2811 (2020)..

Yang, C. C. et al. Controllable co-assembly of organic micro/nano heterostructures from fluorescent and phosphorescent molecules for dual anti-counterfeiting.Mater. Horiz.6, 984–989 (2019)..

Ding, M. Y. et al. Energy manipulation in lanthanide-doped core-shell nanoparticles for tunable dual-mode luminescence toward advanced anti-counterfeiting.Adv. Mater.32, 2002121 (2020)..

Li, Z. J. et al. Coloring afterglow nanoparticles for high-contrast time-gating-free multiplex luminescence imaging.Adv. Mater.32, 2003881 (2020)..

Wang, Y. K. et al. NaMgF3: Tb3+@NaMgF3nanoparticles containing deep traps for optical information storage.Adv. Optical Mater.9, 2100624 (2021)..

Shikha, S. et al. Versatile design and synthesis of nano-barcodes.Chem. Soc. Rev.46, 7054–7093 (2017)..

Ma, B. L. et al. Orthogonal shortwave infrared emission based on rare earth nanoparticles for interference-free logical codes and bio-imaging.Chem. Sci.10, 3281–3288 (2019)..

Wu, Y. M. et al. Dynamic upconversion multicolour editing enabled by molecule-assisted opto-electrochemical modulation.Nat. Commun.12, 2022 (2021)..

Song, Y. P. et al. Energy migration control of multimodal emissions in an Er3+-Doped nanostructure for information encryption and deep-learning decoding.Angew. Chem. Int. Ed.60, 23790–23796 (2021)..

Zhang, H. X. et al. Tm3+-sensitized NIR-Ⅱ fluorescent nanocrystals for in vivo information storage and decoding.Angew. Chem. Int. Ed.58, 10153–10157 (2019)..

Law, L. L. et al. Nonlinearoptical activity in dipolar organic-lanthanide complexes.J. Mater. Chem.20, 4074–4079 (2010)..

Wang, F. et al. Tuning upconversion through energy migration in core-shell nanoparticles.Nat. Mater.10, 968–973 (2011)..

Zhu, X. Y. et al. High-fidelity NIR-Ⅱ multiplexed lifetime bioimaging with bright double interfaced lanthanide nanoparticles.Angew. Chem. Int. Ed.60, 23545–23551 (2021)..

Liu, X. et al. Independent luminescent lifetime and intensity tuning of upconversion nanoparticles by gradient doping for multiplexed encoding.Angew. Chem. Int. Ed.60, 7041–7045 (2021)..

Wang, F. et al. Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping.Nature463, 1061–1065 (2010)..

Chen, G. Y. et al. Upconversion nanoparticles: design, nanochemistry, and applications in theranostics.Chem. Rev.114, 5161–5214 (2014)..

Wen, S. H. et al. Future and challenges for hybrid upconversion nanosystems.Nat. Photonics13, 828–838 (2019)..

Auzel, F. Upconversion and anti-stokes processes with f and d Ions in solids.Chem. Rev.104, 139–173 (2004)..

Liu, S. B. et al. Tri-channel photon emission of lanthanides in lithium-sublattice core-shell nanostructures for multiple anti-counterfeiting.Chem. Eng. J.397, 125451 (2020)..

Liu, X. W. et al. Dual-mode long-lived luminescence of Mn2+-doped nanoparticles for multilevel anticounterfeiting.ACS Appl. Mater. Interfaces11, 30146–30153 (2019)..

Liu, Y. S. et al. A strategy to achieve efficient dual-mode luminescence of Eu3+in lanthanides doped multifunctional NaGdF4nanocrystals.Adv. Mater.22, 3266–3271 (2010)..

Wang, C. X. et al. A simple reducing approach using amine to give dual functional EuSe nanocrystals and morphological tuning.Angew. Chem. Int. Ed.50, 7587–7591 (2011)..

Zhang, J. Z. et al. Facile synthesis of highly monodisperse EuSe nanocubes with size-dependent optical/magnetic properties and their electro-chemiluminescence performance.Nanoscale10, 13617–13625 (2018)..

Fischer, S. et al. Bright infrared-to-ultraviolet/visible upconversion in small alkaline earth-based nanoparticles with biocompatible CaF2shells.Angew. Chem. Int. Ed.59, 21603–21612 (2020)..

Dong, H. et al. Selective cation exchange enabled growth of lanthanide core/shell nanoparticles with dissimilar structure.J. Am. Chem. Soc.139, 18492–18495 (2017)..

Ren, Y. F. et al. PEGylated β-NaGdF4/Tb@CaF2core/shell nanophosphors for enhanced radioluminescence and folate receptor targeting.ACS Appl. Nano Mater.2, 3718–3727 (2019)..

Li, N. et al. High quality ultrathin lanthanide selenide nanostructures with dual modal functionalities.Chem. Mater.28, 2507–2510 (2016)..

Zhao, J. X., Chen, B.&Wang, F. Shedding light on the role of misfit strain in controlling core-shell nanocrystals.Adv. Mater.32, 2004142 (2020)..

Johnson, N. J. J.&Van Veggel, F. C. J. M. Lanthanide-based heteroepitaxial core-shell nanostructures: compressiveversustensile strain asymmetry.ACS Nano8, 10517–10527 (2014)..

Pei, P. X. et al. An advanced tunable multimodal luminescent La4GeO8: Eu2+, Er3+phosphor for multicolor anticounterfeiting.Adv. Funct. Mater.31, 2102479 (2021)..

Li, K. et al. Recent development in phosphors with different emitting colorsviaenergy transfer.J. Mater. Chem. C.4, 5507–5530 (2016)..

Zhou, B. et al. Photon upconversion through Tb3+-mediated interfacial energy transfer.Adv. Mater.27, 6208–6212 (2015)..

Zhou, B. et al. Probing energy migration through precise control of interfacial energy transfer in nanostructure.Adv. Mater.31, 1806308 (2019)..

Boyer, J. C. et al. Synthesis of colloidal upconverting NaYF4nanocrystals doped with Er3+, Yb3+and Tm3+, Yb3+via thermal decomposition of lanthanide trifluoroacetate precursors.J. Am. Chem. Soc.128, 7444–7445 (2006)..

Zhou, B. et al. Controlling upconversion nanocrystals for emerging applications.Nat. Nanotechnol.10, 924–936 (2015)..

Haase, M.&Schäfer, H. Upconverting nanoparticles.Angew. Chem. Int. Ed.50, 5808–5829 (2011)..

Liu, Q. et al. Sub-10 nm hexagonal lanthanide-doped NaLuF4upconversion nanocrystals for sensitive bioimaging in vivo.J. Am. Chem. Soc.133, 17122–17125 (2011)..

Kaiser, M. et al. Power-dependent upconversion quantum yield of NaYF4: Yb3+, Er3+nano- and micrometer-sized particles - measurements and simulations.Nanoscale9, 10051–10058 (2017)..

Wong, K. L., Bünzli, J. C. G.&Tanner, P. A. Quantum yield and brightness.J. Lumin.224, 117256 (2020)..

Brouwer, A. M. Standards for photoluminescence quantum yield measurements in solution (IUPAC technical report).Pure Appl. Chem.83, 2213–2228 (2011)..

Hu, Z. et al. Reversible 3D optical data storage and information encryption in photo-modulated transparent glass medium.Light Sci. Appl.10, 140 (2021)..

Bai, X. et al. Multiple anti-counterfeiting and optical storage of reversible dual-mode luminescence modification in photochromic CaWO4: Yb3+, Er3+, Bi3+phosphor.Chem. Eng. J.429, 132333 (2022)..

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