An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains
An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains
- Light: Science & Applications 2022年11卷第9期 页码：2217-2224
- Affiliations：
1.Research Center for Crystal Materials, CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China
2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, 100049 Beijing, China
- Author bio：
Shilie Pan (slpan@ms.xjb.ac.cn)
- Funds：
DOI：10.1038/s41377-022-00941-2
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Fangfang Zhang, Xinglong Chen, Min Zhang, 等. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains[J]. Light: Science & Applications, 2022,11(9):2217-2224.
Zhang, F. F. et al. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains. Light: Science & Applications, 11, 2217-2224 (2022).
Fangfang Zhang, Xinglong Chen, Min Zhang, 等. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains[J]. Light: Science & Applications, 2022,11(9):2217-2224. DOI： 10.1038/s41377-022-00941-2.
Zhang, F. F. et al. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains. Light: Science & Applications, 11, 2217-2224 (2022). DOI： 10.1038/s41377-022-00941-2.
摘要
Abstract
Birefringent materials play indispensable roles in modulating the polarization of light and are vital in the laser science and technology. Currently, the design of birefringent materials operating in the deep-ultraviolet region (DUV,λ, ≤200 nm) is still a great challenge. In this work, we developed a new DUV birefringent crystal LiBO,2, based on [BO,2,],∞, infinite chains in the Li-B-O system, which simultaneously achieves the shortest UV cutoff edge (164 nm) and the largest birefringence (≥0.168 at 266 nm) among all the reported borate-based DUV birefringent materials. Single crystals of LiBO,2, with dimensions up to Ø55 × 34 mm,3, were grown by the Czochralski method, providing access to large-sized single crystal with low cost. Moreover, it has a high laser damage threshold and stable physicochemical properties. These outstanding characters unambiguously support that LiBO,2, can be an excellent birefringent material for DUV application.
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references
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