Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance

Rui Sun; Donglei Zhou; Yujiao Ding; Yue Wang; Yuqi Wang; Xinmeng Zhuang; Shuainan Liu; Nan Ding; Tianyuan Wang; Wen Xu; Hongwei Song

doi:10.1038/s41377-022-01027-9

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Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance

Original Articles

- Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance
- Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance
- LSA 2022年11卷第12期页码：3044-3058
- Affiliations：
  
  State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, China
- Author bio：
  
  Donglei Zhou (zhoudl@jlu.edu.cn)
  Hongwei Song (songhw@jlu.edu.cn)
- Funds：
- DOI：10.1038/s41377-022-01027-9
  中图分类号：
- 纸质出版日期：2022-12-31，
  
  网络出版日期：2022-12-06，
  
  收稿日期：2022-06-09，
  
  修回日期：2022-10-10，
  
  录用日期：2022-10-25
- Accepted：
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Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance[J]. LSA, 2022,11(12):3044-3058.

Sun, R. et al. Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance. Light: Science & Applications, 11, 3044-3058 (2022).
Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance[J]. LSA, 2022,11(12):3044-3058. DOI： 10.1038/s41377-022-01027-9.

Sun, R. et al. Efficient single-component white light emitting diodes enabled by lanthanide ions doped lead halide perovskites via controlling Förster energy transfer and specific defect clearance. Light: Science & Applications, 11, 3044-3058 (2022). DOI： 10.1038/s41377-022-01027-9.

摘要

Abstract

Currently

a major challenge for metal-halide perovskite light emitting diodes (LEDs) is to achieve stable and efficient white light emission due to halide ion segregation. Herein

we report a promising method to fabricate white perovskite LEDs using lanthanide (Ln

) ions doped CsPbCl

perovskite nanocrystals (PeNCs). First

ions are doped into the lattice to tune the perovskite bandgap by partially substituting Cs

ions

which are well matched to the transition energy of some Ln

ions from the ground state to the excited state

thereby greatly improving the Förster energy transfer efficiency from excitons to Ln

ions. Then

creatine phosphate (CP)

a phospholipid widely found in organisms

serves as a tightly binding surface-capping multi-functional ligand which regulates the film formation and enhances the optical and electrical properties of PeNC film. Consequently

the Eu

doped PeNCs based-white LEDs show a peak luminance of 1678 cd m

-2

and a maximum external quantum efficiency (EQE) of 5.4%

demonstrating excellent performance among existing white PeNC LEDs from a single chip. Furthermore

the method of bandgap modulation and the defect passivation were generalized to other Ln

ions doped perovskite LEDs and successfully obtained improved electroluminescence (EL). This work demonstrates the comprehensive and universal strategies in the realization of highly efficient and stable white LEDs via single-component Ln

ions doped PeNCs

which provides an optimal solution for the development of low-cost and simple white perovskite LEDs.

关键词

Keywords

references

D. L. Zhou , 等 . Cerium and ytterbium codoped halide perovskite quantum dots: a novel and efficient downconverter for improving the performance of silicon solar cells . Adv. Mater. , 2017 . 29 1704149 DOI:10.1002/adma.201704149http://doi.org/10.1002/adma.201704149 .

W. C. Xiang , S. Z. Liu , W. Tress . A review on the stability of inorganic metal halide perovskites: challenges and opportunities for stable solar cells . Energy Environ. Sci. , 2021 . 14 2090 -2113 . DOI:10.1039/D1EE00157Dhttp://doi.org/10.1039/D1EE00157D .

J. B. Li , 等 . Review on recent progress of lead-free halide perovskites in optoelectronic applications . Nano Energy , 2021 . 80 105526 DOI:10.1016/j.nanoen.2020.105526http://doi.org/10.1016/j.nanoen.2020.105526 .

R. Sun , D. L. Zhou , H. W. Song . Rare earth doping in perovskite luminescent nanocrystals and photoelectric devices . Nano Sel. , 2022 . 3 531 -554 . DOI:10.1002/nano.202100187http://doi.org/10.1002/nano.202100187 .

Y. K. Wang , 等 . All-inorganic quantum-dot LEDs based on a phase-stabilized α-CsPbI3 perovskite . Angew. Chem. Int. Ed. , 2021 . 60 16164 -16170 . DOI:10.1002/anie.202104812http://doi.org/10.1002/anie.202104812 .

Z. Liu , 等 . Perovskite light-emitting diodes with EQE exceeding 28% through a synergetic dual-additive strategy for defect passivation and nanostructure regulation . Adv. Mater. , 2021 . 33 2103268 DOI:10.1002/adma.202103268http://doi.org/10.1002/adma.202103268 .

Y. Liu , 等 . Wide-bandgap perovskite quantum dots in perovskite matrix for sky-blue light-emitting diodes . J. Am. Chem. Soc. , 2022 . 144 4009 -4016 . DOI:10.1021/jacs.1c12556http://doi.org/10.1021/jacs.1c12556 .

J. W. Chen , 等 . Perovskite white light emitting diodes: progress, challenges, and opportunities . ACS Nano , 2021 . 15 17150 -17174 . DOI:10.1021/acsnano.1c06849http://doi.org/10.1021/acsnano.1c06849 .

H. Chen , 等 . Efficient and bright warm-white electroluminescence from lead-free metal halides . Nat. Commun. , 2021 . 12 1421 DOI:10.1038/s41467-021-21638-xhttp://doi.org/10.1038/s41467-021-21638-x .

E. P. Yao , 等 . High-brightness blue and white LEDs based on inorganic perovskite nanocrystals and their composites . Adv. Mater. , 2017 . 29 1606859 DOI:10.1002/adma.201606859http://doi.org/10.1002/adma.201606859 .

J. Mao , 等 . All-perovskite emission architecture for white light-emitting diodes . ACS Nano , 2018 . 12 10486 -10492 . DOI:10.1021/acsnano.8b06196http://doi.org/10.1021/acsnano.8b06196 .

J. W. Chen , 等 . Efficient and bright white light-emitting diodes based on single-layer heterophase halide perovskites . Nat. Photonics , 2021 . 15 238 -244 . DOI:10.1038/s41566-020-00743-1http://doi.org/10.1038/s41566-020-00743-1 .

Z. M. Chen , 等 . Utilization of trapped optical modes for white perovskite light-emitting diodes with efficiency over 12% . Joule , 2021 . 5 456 -466 . DOI:10.1016/j.joule.2020.12.008http://doi.org/10.1016/j.joule.2020.12.008 .

G. C. Pan , 等 . Doping lanthanide into perovskite nanocrystals: highly improved and expanded optical properties . Nano Lett. , 2017 . 17 8005 -8011 . DOI:10.1021/acs.nanolett.7b04575http://doi.org/10.1021/acs.nanolett.7b04575 .

D. L. Zhou , 等 . Impact of host composition, codoping, or tridoping on quantum-cutting emission of ytterbium in halide perovskite quantum dots and solar cell applications . Nano Lett. , 2019 . 19 6904 -6913 . DOI:10.1021/acs.nanolett.9b02139http://doi.org/10.1021/acs.nanolett.9b02139 .

R. Sun , 等 . Samarium-doped metal halide perovskite nanocrystals for single-component electroluminescent white light-emitting diodes . ACS Energy Lett. , 2020 . 5 2131 -2139 . DOI:10.1021/acsenergylett.0c00931http://doi.org/10.1021/acsenergylett.0c00931 .

L. N. Puntus , 等 . Charge transfer bands in the Eu3+ luminescence excitation spectra of isomeric europium pyridine-dicarboxylates . Phys. Solid State , 2002 . 44 1440 -1444 . DOI:10.1134/1.1501333http://doi.org/10.1134/1.1501333 .

R. Wang , 等 . Constructive molecular configurations for surface-defect passivation of perovskite photovoltaics . Science , 2019 . 366 1509 -1513 . DOI:10.1126/science.aay9698http://doi.org/10.1126/science.aay9698 .

R. Begum , 等 . Engineering interfacial charge transfer in CsPbBr3 perovskite nanocrystals by heterovalent doping . J. Am. Chem. Soc. , 2017 . 139 731 -737 . DOI:10.1021/jacs.6b09575http://doi.org/10.1021/jacs.6b09575 .

W. Van Der Stam , 等 . Highly emissive divalent-ion-doped colloidal CsPb1–xMxBr3 perovskite nanocrystals through cation exchange . J. Am. Chem. Soc. , 2017 . 139 4087 -4097 . DOI:10.1021/jacs.6b13079http://doi.org/10.1021/jacs.6b13079 .

J. N. Yang , 等 . Potassium bromide surface passivation on CsPbI3-xBrx nanocrystals for efficient and stable pure red perovskite light-emitting diodes . J. Am. Chem. Soc. , 2020 . 142 2956 -2967 . DOI:10.1021/jacs.9b11719http://doi.org/10.1021/jacs.9b11719 .

J. K. Nam , 等 . Potassium incorporation for enhanced performance and stability of fully inorganic cesium lead halide perovskite solar cells . Nano Lett. , 2017 . 17 2028 -2033 . DOI:10.1021/acs.nanolett.7b00050http://doi.org/10.1021/acs.nanolett.7b00050 .

Z. L. Yu , 等 . Theoretical study on the effect of the optical properties and electronic structure for the Bi-doped CsPbBr3 . J. Phys. Condens. Matter , 2020 . 32 205504 DOI:10.1088/1361-648X/ab6e90http://doi.org/10.1088/1361-648X/ab6e90 .

J. Y. Zhang , 等 . Disappeared deep charge-states transition levels in the p-type intrinsic CsSnCl3 perovskite . Appl. Phys. Lett. , 2019 . 114 181902 DOI:10.1063/1.5090420http://doi.org/10.1063/1.5090420 .

J. Kang , L. W. Wang . High defect tolerance in lead halide perovskite CsPbBr3 . J. Phys. Chem. Lett. , 2017 . 8 489 -493 . DOI:10.1021/acs.jpclett.6b02800http://doi.org/10.1021/acs.jpclett.6b02800 .

Y. Kayanuma , H. Momiji . Incomplete confinement of electrons and holes in microcrystals . Phys. Rev. B , 1990 . 41 10261 -10263 . DOI:10.1103/PhysRevB.41.10261http://doi.org/10.1103/PhysRevB.41.10261 .

L. E. Brus . A simple model for the ionization potential, electron affinity, and aqueous redox potentials of small semiconductor crystallites . J. Chem. Phys. , 1983 . 79 5566 -5571 . DOI:10.1063/1.445676http://doi.org/10.1063/1.445676 .

D. Y. Kong , 等 . Spectroscopic studies on interaction of BSA and Eu(Ⅲ) complexes with H5ph-dtpa and H5dtpa ligands . Spectrochim. Acta A Mol. Biomol. Spectrosc. , 2015 . 140 372 -381 . DOI:10.1016/j.saa.2015.01.004http://doi.org/10.1016/j.saa.2015.01.004 .

J. Tang , 等 . Colloidal-quantum-dot photovoltaics using atomic-ligand passivation . Nat. Mater. , 2011 . 10 765 -771 . DOI:10.1038/nmat3118http://doi.org/10.1038/nmat3118 .

D. L. Zhou , 等 . Semiconductor plasmon induced up-conversion enhancement in mCu2–xS@SiO2@Y2O3: Yb3+/Er3+ core–shell nanocomposites . ACS Appl. Mater. Interfaces , 2017 . 9 35226 -35233 . DOI:10.1021/acsami.7b09850http://doi.org/10.1021/acsami.7b09850 .

L. Prodi , 等 . Luminescence properties of cryptate europium (Ⅲ) complexes incorporating heterocyclic N-oxide groups . Chem. Phys. Lett. , 1991 . 180 45 -50 . DOI:10.1016/0009-2614(91)87114-Qhttp://doi.org/10.1016/0009-2614(91)87114-Q .

K. J. Karki , 等 . Different emissive states in the bulk and at the surface of methylammonium lead bromide perovskite revealed by two-photon micro-spectroscopy and lifetime measurements . APL Photonics , 2016 . 1 046103 DOI:10.1063/1.4948645http://doi.org/10.1063/1.4948645 .

C. F. Han , 等 . Unraveling surface and bulk trap states in lead halide perovskite solar cells using impedance spectroscopy . J. Phys. D Appl. Phys. , 2018 . 51 095501 DOI:10.1088/1361-6463/aaa7cdhttp://doi.org/10.1088/1361-6463/aaa7cd .

Y. Yang , 等 . Low surface recombination velocity in solution-grown CH3NH3PbBr3 perovskite single crystal . Nat. Commun. , 2015 . 6 7961 DOI:10.1038/ncomms8961http://doi.org/10.1038/ncomms8961 .

S. Q. Huang , 等 . Postsynthesis potassium-modification method to improve stability of CsPbBr3 perovskite nanocrystals . Adv. Optical Mater. , 2018 . 6 1701106 DOI:10.1002/adom.201701106http://doi.org/10.1002/adom.201701106 .

F. Palazon , 等 . X-ray lithography on perovskite nanocrystals films: from patterning with anion-exchange reactions to enhanced stability in air and water . ACS Nano , 2016 . 10 1224 -1230 . DOI:10.1021/acsnano.5b06536http://doi.org/10.1021/acsnano.5b06536 .

D. W. De Quilettes , 等 . Impact of microstructure on local carrier lifetime in perovskite solar cells . Science , 2015 . 348 683 -686 . DOI:10.1126/science.aaa5333http://doi.org/10.1126/science.aaa5333 .

S. F. Wu , 等 . Modulation of defects and interfaces through alkylammonium interlayer for efficient inverted perovskite solar cells . Joule , 2020 . 4 1248 -1262 . DOI:10.1016/j.joule.2020.04.001http://doi.org/10.1016/j.joule.2020.04.001 .

H. Huang , 等 . Lead halide perovskite nanocrystals in the research spotlight: stability and defect tolerance . ACS Energy Lett. , 2017 . 2 2071 -2083 . DOI:10.1021/acsenergylett.7b00547http://doi.org/10.1021/acsenergylett.7b00547 .

Q. K. Hu , 等 . Dual defect-passivation using phthalocyanine for enhanced efficiency and stability of perovskite solar cells . Small , 2021 . 17 2005216 DOI:10.1002/smll.202005216http://doi.org/10.1002/smll.202005216 .

Y. Chung , K. S. Kim , J. W. Jung . On the role of carboxylated polythiophene in defect passivation of CsPbI2Br surface for efficient and stable all-inorganic perovskite solar cells . Int. J. Energy Res. , 2022 . 46 6012 -6021 . DOI:10.1002/er.7540http://doi.org/10.1002/er.7540 .

H. Lin , 等 . Stable and efficient blue-emitting CsPbBr3 nanoplatelets with potassium bromide surface passivation . Small , 2021 . 17 2101359 DOI:10.1002/smll.202101359http://doi.org/10.1002/smll.202101359 .

L. M. Kong , 等 . Smoothing the energy transfer pathway in quasi-2D perovskite films using methanesulfonate leads to highly efficient light-emitting devices . Nat. Commun. , 2021 . 12 1246 DOI:10.1038/s41467-021-21522-8http://doi.org/10.1038/s41467-021-21522-8 .

D. X. Ma , 等 . Distribution control enables efficient reduced-dimensional perovskite LEDs . Nature , 2021 . 599 594 -598 . DOI:10.1038/s41586-021-03997-zhttp://doi.org/10.1038/s41586-021-03997-z .

S. Yang , 等 . Tailoring passivation molecular structures for extremely small open-circuit voltage loss in perovskite solar cells . J. Am. Chem. Soc. , 2019 . 141 5781 -5787 . DOI:10.1021/jacs.8b13091http://doi.org/10.1021/jacs.8b13091 .

C. Q. Ma , N. G. Park . Paradoxical approach with a hydrophilic passivation layer for moisture-stable, 23% efficient perovskite solar cells . ACS Energy Lett. , 2020 . 5 3268 -3275 . DOI:10.1021/acsenergylett.0c01848http://doi.org/10.1021/acsenergylett.0c01848 .

Q. F. Dong , 等 . Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals . Science , 2015 . 347 967 -970 . DOI:10.1126/science.aaa5760http://doi.org/10.1126/science.aaa5760 .

Z. H. Liu , 等 . Chemical reduction of intrinsic defects in thicker heterojunction planar perovskite solar cells . Adv. Mater. , 2017 . 29 1606774 DOI:10.1002/adma.201606774http://doi.org/10.1002/adma.201606774 .

M. Lu , 等 . Bright CsPbI3 perovskite quantum dot light-emitting diodes with top-emitting structure and a low efficiency roll-off realized by applying zirconium acetylacetonate surface modification . Nano Lett. , 2020 . 20 2829 -2836 . DOI:10.1021/acs.nanolett.0c00545http://doi.org/10.1021/acs.nanolett.0c00545 .

M. H. Park , 等 . Boosting efficiency in polycrystalline metal halide perovskite light-emitting diodes . ACS Energy Lett. , 2019 . 4 1134 -1149 . DOI:10.1021/acsenergylett.9b00518http://doi.org/10.1021/acsenergylett.9b00518 .

E. M. Sanehira , 等 . Enhanced mobility CsPbI3 quantum dot arrays for record-efficiency, high-voltage photovoltaic cells . Sci. Adv. , 2017 . 3 eaao4204 DOI:10.1126/sciadv.aao4204http://doi.org/10.1126/sciadv.aao4204 .

E. T. Vickers , 等 . Enhancing charge carrier delocalization in perovskite quantum dot solids with energetically aligned conjugated capping ligands . ACS Energy Lett. , 2020 . 5 817 -825 . DOI:10.1021/acsenergylett.0c00093http://doi.org/10.1021/acsenergylett.0c00093 .

M. Soreni-Harari , 等 . Tuning energetic levels in nanocrystal quantum dots through surface manipulations . Nano Lett. , 2008 . 8 678 -684 . DOI:10.1021/nl0732171http://doi.org/10.1021/nl0732171 .

X. Y. Zhang , 等 . PbS capped CsPbI3 nanocrystals for efficient and stable light-emitting devices using p–i–n structures . ACS Cent. Sci. , 2018 . 4 1352 -1359 . DOI:10.1021/acscentsci.8b00386http://doi.org/10.1021/acscentsci.8b00386 .

V. Wood , 等 . Air-stable operation of transparent, colloidal quantum dot based LEDs with a unipolar device architecture . Nano Lett. , 2010 . 10 24 -29 . DOI:10.1021/nl902425ghttp://doi.org/10.1021/nl902425g .

Q. J. Sun , 等 . Bright, multicoloured light-emitting diodes based on quantum dots . Nat. Photonics , 2007 . 1 717 -722 . DOI:10.1038/nphoton.2007.226http://doi.org/10.1038/nphoton.2007.226 .

P. O. Anikeeva , 等 . Quantum dot light-emitting devices with electroluminescence tunable over the entire visible spectrum . Nano Lett. , 2009 . 9 2532 -2536 . DOI:10.1021/nl9002969http://doi.org/10.1021/nl9002969 .

J. Senawiratne , 等 . Junction temperature analysis in green light emitting diode dies on sapphire and GaN substrates . Phys. Status Solidi C. , 2008 . 5 2247 -2249 . DOI:10.1002/pssc.200778648http://doi.org/10.1002/pssc.200778648 .

Y. F. Lu , X. A. Cao . Blue and green electroluminescence from CdSe nanocrystal quantum-dot-quantum-wells . Appl. Phys. Lett. , 2014 . 105 203101 DOI:10.1063/1.4902109http://doi.org/10.1063/1.4902109 .

T. Hasan , 等 . Photo-and electroluminescence from nitrogen-doped and nitrogen–sulfur codoped graphene quantum dots . Adv. Funct. Mater. , 2018 . 28 1804337 DOI:10.1002/adfm.201804337http://doi.org/10.1002/adfm.201804337 .

Y. L. Song , 等 . White electroluminescence from a prototypical light-emitting diode based on CdS/Si heterojunctions . Mater. Lett. , 2017 . 196 8 -11 . DOI:10.1016/j.matlet.2017.02.117http://doi.org/10.1016/j.matlet.2017.02.117 .

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