Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy

Junghoon Jahng; Sunho Lee; Seong-Gu Hong; Chang Jun Lee; Sergey G. Menabde; Min Seok Jang; Dong-Hyun Kim; Jangyup Son; Eun Seong Lee

doi:10.1038/s41377-023-01320-1

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Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy

Original Articles

- Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy
- Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy
- LSA 2023年12卷第12期页码：2700-2710
- Affiliations：
  
  1.Hyperspectral Nano-imaging Team, Korea Research Institute of Standards and Science, Daejeon 34113, Republic of Korea
  2.Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA
  3.Multiscale Mechanical Properties Measurement Team, Korea Research Institute of Standards and Science, Daejeon 34113, Republic of Korea
  4.School of Mechanical Engineering, Chonnam National University, Gwangju 61186, Republic of Korea
  5.School of Electrical Engineering, Korea Advanced Institute of Science and Technology, Daejeon 34141, Republic of Korea
  6.Functional Composite Materials Research Center, Korea Institute of Science and Technology, Jeonbuk 55324, Republic of Korea
  7.SKKU Advanced Institute of Nanotechnology, Sungkyunkwan University, Suwon 16419, Republic of Korea
  8.Division of Nano & Information Technology, KIST School, University of Science and Technology, Seoul 02792, Republic of Korea
- Author bio：
  
  Junghoon Jahng (phyjjh@kriss.re.kr)
  Eun Seong Lee (eslee@kriss.re.kr)
- Funds：
- DOI：10.1038/s41377-023-01320-1
  中图分类号：
- 纸质出版日期：2023-12-31，
  
  网络出版日期：2023-11-24，
  
  收稿日期：2023-05-09，
  
  修回日期：2023-09-29，
  
  录用日期：2023-10-30
- Accepted：
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Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy[J]. LSA, 2023,12(12):2700-2710.

Jahng, J. et al. Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy. Light: Science & Applications, 12, 2700-2710 (2023).
Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy[J]. LSA, 2023,12(12):2700-2710. DOI： 10.1038/s41377-023-01320-1.

Jahng, J. et al. Characterizing and controlling infrared phonon anomaly of bilayer graphene in optical-electrical force nanoscopy. Light: Science & Applications, 12, 2700-2710 (2023). DOI： 10.1038/s41377-023-01320-1.

摘要

Abstract

for the first time

report the nanoscopic imaging study of anomalous infrared (IR) phonon enhancement of bilayer graphene

originated from the charge imbalance between the top and bottom layers

resulting in the enhancement of E

mode of bilayer graphene near 0.2 eV. We modified the multifrequency atomic force microscope platform to combine photo-induced force microscope with electrostatic/Kelvin probe force microscope constituting a novel hybrid nanoscale optical-electrical force imaging system. This enables to observe a correlation between the IR response

doping level

and topographic information of the graphene layers. Through the nanoscale spectroscopic image measurements

we demonstrate that the charge imbalance at the graphene interface can be controlled by chemical (doping effect via Redox mechanism) and mechanical (triboelectric effect by the doped cantilever) approaches. Moreover

we can also diagnosis the subsurface cracks on the stacked few-layer graphene at nanoscale

by monitoring the strain-induced IR phonon shift. Our approach provides new insights into the development of graphene-based electronic and photonic devices and their potential applications.

关键词

Keywords

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