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    Vol. 2 , Issue 3-4 , 2013

      Original Articles

    • Peter Liebetraut,Sebastian Petsch,Jens Liebeskind,Hans Zappe
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.54
      Abstract:Microlenses fabricated using flexible elastomers can be tuned in focal length by application of controlled strain. By varying the strain azimuthally, the lenses may be deformed asymmetrically such that aberrations may be controlled. This approach is used to tune the astigmatism of the tunable lenses, and it is shown that the generated wavefront may be accurately controlled. The lens presented here has an initial focal length of 32.6 mm and a tuning range of +2.3 mm for approximately 10% applied strain. The range of directly tunable Zernike polynomials representing astigmatism is about 3 µm, while the secondary lens errors, which cannot be tuned directly, vary only by about 0.2 µm.  
      Keywords:aberrations;active or adaptive optics;micro-optical devices;polymers   
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      Published:2024-09-30
    • Kyu Hyun Kim,Gaurav Bahl,Wonsuk Lee,Jing Liu,Matthew Tomes,Xudong Fan,Tal Carmon
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.66
      Abstract:Currently, optical or mechanical resonances are commonly used in microfluidic research. However, optomechanical oscillations by light pressure were not shown with liquids. This is because replacing the surrounding air with water inherently increases the acoustical impedance and hence, the associated acoustical radiation losses. Here, we bridge between microfluidics and optomechanics by fabricating a hollow-bubble resonator with liquid inside and optically exciting vibrations with 100 MHz rates using only mW optical-input power. This constitutes the first time that any microfluidic system is optomechanically actuated. We further prove the feasibility of microfluidic optomechanics on liquids by demonstrating vibrations on organic fluids with viscous dissipation higher than blood viscosity while measuring density changes in the liquid via the vibration frequency shift. Our device will enable using cavity optomechanics for studying non-solid phases of matter, while light is easily coupled from the outer dry side of the capillary and fluid is provided using a standard syringe pump.  
      Keywords:nonlinear optics;optical materials and devices;optomechanics   
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      Published:2024-09-30
    • Mengtao Sun,Zhenglong Zhang,Peijie Wang,Qiang Li,Fengcai Ma,Hongxing Xu
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.68
      Abstract:We experimentally investigated remotely excited Raman optical activity (ROA) using propagating surface plasmons in chiral Ag nanowires. Using chiral fmoc-glycyl-glycine-OH (FGGO) molecules, we first studied the local surface plasmon-enhanced ROA. We found that the Raman intensity can be excited by left- and right-circularly polarized lights and that the circular intensity difference (CID) can be significantly enhanced. Second, by selecting vibrational modes with large Raman and ROA intensities that are not influenced by chemical enhancements, we studied remotely excited ROA imaging and the CID of FGGO molecules by propagating a plasmonic waveguide using Ag chiral nanostructures. When laser light was radiated on one of the Ag terminals, the measured CID of the FGG at the other terminal showed little change compared to the local excited CID. Meanwhile, when the laser light was radiated on the Ag nanowires (not on the terminals) and was coupled to the nearby nanoantenna, the CID of the ROA could be manipulated by altering the coupling angle between the Ag nanowires. To directly demonstrate the propagation of ROA along the nanowire and its remote detection, we also measured the remotely excited ROA spectra. Our experimental method has the potential to remotely determine the chirality of molecular structures and the absolute configuration or conformation of a chiral live cell.  
      Keywords:Ag nanowires;chiral plasmons;plasmon propagation;Raman optical activity;remote excitation   
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      Published:2024-09-30
    • Mohammad Memarian,George V Eleftheriades
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.70
      Abstract:Focusing incident power into an area of high concentration is of significant interest for various applications. In optics, this has been traditionally achieved with lenses where a higher curvature and lens permittivity typically result in shorter focal distances (low f/D). In this work, we present designs and techniques for collecting, refracting and guiding incident light into an area of high power concentration (a hot spot) at extremely short distances. Specifically, a flat low-profile focusing mechanism is presented using a hetero-junction of anisotropic metamaterials (MTMs). The hetero-junction is formed from two cleaved finite slabs of low (near zero) permittivity anisotropic MTMs with rotated optical axes. The MTMs have near zero longitudinal permittivity while matched in the transverse direction. Such MTMs are shown to provide a unique ability to bend the transverse magnetic or p-polarized light away from the normal and along the interface, contrary to conventional dielectrics, and with minimal reflections; hence allowing for a low profile design. Realizations in the optical regime are presented using periodic bilayers of metal and dielectric. The proposed hetero-junction focusing device concentrates the normally incident plane wave and/or beam into a corresponding focal region similar to a lens via multiple refractions. The hetero-junction is capable of creating a hot spot very close to the device, much closer than dielectric lenses and it significantly outperforms the size requirements of thick high curvature lenses with low f/D ratios. The proposed designs can find applications in various scenarios including solar and thermo photovoltaics, photodetectors, concentrated photovoltaics, non-imaging optics, micro- and nano-Fresnel lenses.  
      Keywords:epsilon near zero;focusing;light concentration;metamaterials;non-imaging optics;photovoltaics   
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      Published:2024-09-30
    • Kotaro Obata,Ayman El-Tamer,Lothar Koch,Ulf Hinze,Boris N Chichkov
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.72
      Abstract:We developed a novel two-photon polymerization (2PP) configuration for fabrication of high-aspect three-dimensional (3D) structures, with an overall height larger than working distance of the microscope objective used for laser beam focusing into a photosensitive material. This method is based on a modified optical 2PP setup, where a microscope objective (100× high N.A.), immersion oil and cover glass can be moved together into the photosensitive material, resulting in an effective higher and wider objective working range (WOW-2PP). The proposed technique enables the fabrication of high-aspect structures with sub-micrometer process resolution. 3D structures with a height of 7 mm are demonstrated, which could hardly be built with the conventional 2PP set-up due to refractive index mismatch and laser beam disturbances.  
      Keywords:femtosecond laser;large-scale structuring;laser material processing;photochemistry;two-photon polymerization   
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      Published:2024-09-30
    • Quan Sun,Kosei Ueno,Han Yu,Atsushi Kubo,Yasutaka Matsuo,Hiroaki Misawa
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.74
      Abstract:Localized surface plasmon resonance (LSPR) can be supported by metallic nanoparticles and engineered nanostructures. An understanding of the spatially resolved near-field properties and dynamics of LSPR is important, but remains experimentally challenging. We report experimental studies toward this aim using photoemission electron microscopy (PEEM) with high spatial resolution of sub-10 nm. Various engineered gold nanostructure arrays (such as rods, nanodisk-like particles and dimers) are investigated via PEEM using near-infrared (NIR) femtosecond laser pulses as the excitation source. When the LSPR wavelengths overlap the spectrum of the femtosecond pulses, the LSPR is efficiently excited and promotes multiphoton photoemission, which is correlated with the local intensity of the metallic nanoparticles in the near field. Thus, the local field distribution of the LSPR on different Au nanostructures can be directly explored and discussed using the PEEM images. In addition, the dynamics of the LSPR is studied by combining interferometric time-resolved pump-probe technique and PEEM. Detailed information on the oscillation and dephasing of the LSPR field can be obtained. The results identify PEEM as a powerful tool for accessing the near-field mapping and dynamic properties of plasmonic nanostructures.  
      Keywords:femtosecond laser;local field enhancement;near-field imaging;photoemission electron microscopy;surface plasmon resonance   
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      Published:2024-09-30
    • Nikitas Papasimakis,Sukosin Thongrattanasiri,Nikolay I Zheludev,FJ García de Abajo
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.34
      Abstract:Graphene has emerged as a promising platform for THz plasmonics, allowing high confinement, long lifetimes and fast electrical tunability. Here, we predict a strong magnetic dipole response by graphene split nanorings at THz frequencies, allowing the attainment of metamaterials with a high degree of field confinement (approximately one hundredth of the excitation wavelength) that is not reachable with conventional noble metals. The magnetic response of highly doped graphene split-rings in the far-infrared is much stronger than that displayed by gold structures of similar thicknesses. We further explored stacked graphene layers as a practical way of producing high-frequency magnetism in thin, electrically tunable metamaterials. Our results support the great potential of using graphene to achieve electrically tunable magnetic metamaterials.  
      Keywords:artificial magnetism;graphene;graphene plasmons;metamaterials;plasmonics   
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      Published:2024-09-30
    • Chia Wei Hsu,Bo Zhen,Song-Liang Chua,Steven G Johnson,John D Joannopoulos,Marin Soljačić
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.40
      Abstract:From detailed numerical calculations, we demonstrate that in simple photonic crystal structures, a discrete number of Bloch surface-localized eigenstates can exist inside the continuum of free-space modes. Coupling to the free space causes the surface modes to leak, but the forward and back-reflected leakage may interfere destructively to create a perfectly bound surface state with zero leakage. We perform analytical temporal coupled-mode theory analysis to show the generality of such phenomenon and its robustness from variations of system parameters. Periodicity, time-reversal invariance, two-fold rotational symmetry and a perfectly reflecting boundary are necessary for these unique states.  
      Keywords:bound state in continuum;embedded eigenvalue;photonic crystal;surface mode   
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      Published:2024-09-30
    • Victor J Cadarso,Sylvain Chosson,Katrin Sidler,Roger D Hersch,Jürgen Brugger
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.42
      Abstract:A moiré is an interference pattern that appears when two different periodic structures are overlaid. The image created is extremely sensitive to small variations in the original layers and is thus very interesting for anti-counterfeit protection. We present a microfabricated 1D moiré enabling complex high-resolution patterns as a significantly improved security feature that cannot be reproduced using standard printing methods. Furthermore, we demonstrate, theoretically and experimentally, that a microscopic deviation from the original design results in a macroscopic variation in the moiré that is clearly visible to the naked eye. The record resolution achieved in the elements fabricated and the increased design freedom, make these high-resolution moirés excellent candidates for a variety of visually appealing security applications.  
      Keywords:anti-counterfeiting;micro-optical devices;moiré effect;optical security   
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      Published:2024-09-30
    • Marco Leonetti,Claudio Conti,Cefe Lopez
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.44
      Abstract:Random lasing is observed in optically active resonators in the presence of disorder. As the optical cavities involved are open, the modes are coupled, and energy may pour from one state to another provided that they are spatially overlapping. Although the electromagnetic modes are spatially localized, our system may be actively switched to a collective state, presenting a novel form of non-locality revealed by a high degree of spectral correlation between the light emissions collected at distant positions. In a nutshell, light may be stored in a disordered nonlinear structure in different fashions that strongly differ in their spatial properties. This effect is experimentally demonstrated and theoretically explained in titania clusters embedded in a dye, and it provides clear evidence of a transition to a multimodal collective emission involving the entire spatial extent of the disordered system. Our results can be used to develop a novel type of miniaturized, actively controlled all-optical chip.  
      Keywords:collective emission;disorder;nanophotonics;random lasing   
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      Published:2024-09-30
    • Zachary C Holman,Stefaan De Wolf,Christophe Ballif
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.62
      Abstract:Imperfect internal reflectance of near-bandgap light reduces the performance of all solar cells, and becomes increasingly detrimental as absorbers become thinner. We consider light incident on the silicon/dielectric/metal structure at the back of rear-passivated crystalline silicon solar cells with surface textures that are large enough for geometric optics. By calculating the absorbance in the metal as a function of the angle of incidence, we discover three results that are important for understanding and improving rear reflectors in many types of solar cells. First, significant parasitic absorption occurs in the metal layer in two cases: s- and p-polarized propagating modes (near-normal angles of incidence) when the dielectric thickness is adjusted to cause destructive interference of the reflected beams, and p-polarized evanescent modes (angles of incidence above the semiconductor/dielectric critical angle) that excite surface plasmon polaritons at the metal surface. Second, the latter loss dominates; a well-designed rear dielectric passivation layer must suppress the penetration of evanescent waves to the metal. Third, when used as an input in a simple analytical model, the average rear internal reflectance calculated by assuming a Lambertian angular distribution of light accurately predicts the total reflectance and absorbance of a solar cell.  
      Keywords:light trapping;photovoltaics;plasmon;silicon; solar cell   
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      Published:2024-09-30
    • Doekele G Stavenga,Hein L Leertouwer,Bodo D Wilts
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.56
      Abstract:Jamin–Lebedeff polarizing interference microscopy is a classical method for determining the refractive index and thickness of transparent tissues. Here, we extend the application of this method to pigmented, absorbing biological tissues, based on a theoretical derivation using Jones calculus. This novel method is applied to the wings of the American Rubyspot damselfly, Hetaerina americana. The membranes in the red-colored parts of the damselfly's wings, with a thickness of ~2.5 µm, contain a pigment with maximal absorption at ~490 nm and a peak absorbance coefficient of ~0.7 µm−1. The high pigment density causes a considerable and anomalous dispersion of the refractive index. This result can be quantitatively understood from the pigment absorbance spectrum by applying the Kramers–Kronig dispersion relations. Measurements of the spectral dependence of the refractive index and the absorption are valuable for gaining quantitative insight into how the material properties of animal tissues influence coloration.  
      Keywords:absorption;chitin;insect wings;Jones calculus;Kramers–Kronig relations   
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      Published:2024-09-30
    • Lin Li,Wei Guo,Yinzhou Yan,Seoungjun Lee,Tao Wang
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.60
      Abstract:Because of the small sizes of most viruses (typically 5–150 nm), standard optical microscopes, which have an optical diffraction limit of 200 nm, are not generally suitable for their direct observation. Electron microscopes usually require specimens to be placed under vacuum conditions, thus making them unsuitable for imaging live biological specimens in liquid environments. Indirect optical imaging of viruses has been made possible by the use of fluorescence optical microscopy that relies on the stimulated emission of light from the fluorescing specimens when they are excited with light of a specific wavelength, a process known as labeling or self-fluorescent emissions from certain organic materials. In this paper, we describe direct white-light optical imaging of 75-nm adenoviruses by submerged microsphere optical nanoscopy (SMON) without the use of fluorescent labeling or staining. The mechanism involved in the imaging is presented. Theoretical calculations of the imaging planes and the magnification factors have been verified by experimental results, with good agreement between theory and experiment.  
      Keywords:imaging;microscope;optical;super-resolution;virus   
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      Published:2024-09-30
    • Ricard Menchon-Enrich,Andreu Llobera,Jordi Vila-Planas,Víctor J Cadarso,Jordi Mompart,Veronica Ahufinger
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.46
      Abstract:We present the first experimental realization of a light spectral filter based on the spatial adiabatic passage technique. We demonstrate that a fully integrable CMOS-compatible system of three coupled identical total internal reflection silicon oxide waveguides with variable separation along their propagation direction can be used simultaneously as a low- and high-pass spectral filter within the visible range of wavelengths. Light is injected into the right waveguide, and after propagating along the system, long wavelengths are transferred into the left output, whereas short wavelengths propagate to the right and central outputs. The stopband reaches values up to −11 dB for the left output and approximately −20 dB for the right plus central outputs. The passband values are close to 0 dB for both cases. We also demonstrate that the filtering characteristics of the device can be controlled by modifying the parameter values, which define the geometry of the triple-waveguide system. However, the general filtering behavior of the system does not critically depend on technological variations. Thus, the spatial adiabatic passage filtering approach constitutes an alternative to other integrated filtering devices, such as interference or absorbance-based filters.  
      Keywords:CMOS-compatible technology;integrated optics devices;spatial adiabatic passage;wavelength filtering devices   
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      Published:2024-09-30
    • Xi Chen,Baohua Jia,Yinan Zhang,Min Gu
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.48
      Abstract:The solar cell market is predominantly based on textured screen-printed solar cells. Due to parasitic absorption in nanostructures, using plasmonic processes to obtain an enhancement that exceeds 2.5% of the short-circuit photocurrent density is challenging. In this paper, a 7.2% enhancement in the photocurrent density can be achieved through the integration of plasmonic Al nanoparticles and wrinkle-like graphene sheets. For the first time, we experimentally achieve Al nanoparticle-enhanced solar cells. An innovative thermal evaporation method is proposed to fabricate low-coverage Al nanoparticle arrays on solar cells. Due to the ultraviolet (UV) plasmon resonance of Al nanoparticles, the performance enhancement of the solar cells is significantly greater than that from Ag nanoparticles. Subsequently, we deposit wrinkle-like graphene sheets over the Al nanoparticle-enhanced solar cells. Compared with planar graphene sheets, the bend carbon layer also exhibits a broadband light-trapping effect. Our results exceed the limit of plasmonic light trapping in textured screen-printed silicon solar cells.  
      Keywords:Al nanoparticles;plasmonic light trapping;screen-printed solar cells;wrinkle-like graphene sheets   
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      Published:2024-09-30
    • Yasser M Sabry,Bassam Saadany,Diaa Khalil,Tarik Bourouina
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.50
      Abstract:Miniaturized optical benches process free-space light propagating in-plane with respect to the substrate and have a large variety of applications, including the coupling of light through an optical fiber. High coupling efficiency is usually obtained using assembled micro-optical parts, which considerably increase the system cost and integration effort. In this work, we report a high coupling efficiency, monolithically integrated silicon micromirror with controlled three-dimensional (3D) curvature that is capable of manipulating optical beams propagating in the plane of the silicon substrate. Based on our theoretical modeling, a spherical micromirror with a microscale radius of curvature as small as twice the Gaussian beam Rayleigh range provides a 100% coupling efficiency over a relatively long optical path range. Introducing dimensionless parameters facilitates the elucidation of the role of key design parameters, including the mirror's radii of curvature, independent of the wavelength. A micromachining method is presented for fabricating the 3D micromirror using fluorinated gas plasmas. The measured coupling efficiency was greater than 50% over a 200-μm optical path, compared to less than 10% afforded by a conventional flat micromirror, which was in good agreement with the model. Using the 3D micromirror, an optical cavity was formed with a round-trip diffraction loss of less than 0.4%, resulting in one order of magnitude enhancement in the measured quality factor. A nearly 100% coupling was also estimated when matching the sagittal and tangential radii of curvature of the presented micromirror's surface. The reported class of 3D micromirrors may be an advantageous replacement for the optical lenses usually assembled in silicon photonics and optical benches by transforming them into real 3D monolithic systems while achieving wideband high coupling efficiency over submillimeter distances.  
      Keywords:coupling efficiency;Gaussian beam coupling;micro-optics;monolithic chip;optical cavity;optical fabrication;optical benches;silicon photonics   
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      Published:2024-09-30
    • Jianfa Zhang,Kevin F MacDonald,Nikolay I Zheludev
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.52
      Abstract:We introduce a dielectric photonic metamaterial presenting a giant nonlinear optical response driven by resonant optomechanical forces. Being inherently free of Joule losses, it exhibits optical bistability at intensity levels of less than 0.2 mW μm−2 and, furthermore, manifests nonlinear asymmetric transmission with a forward∶backward optical extinction ratio of more than 30 dB.  
      Keywords:metamaterial;optical bistability;optomechanical   
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      Published:2024-09-30

      Review

    • Pan Wang,Yipei Wang,Limin Tong
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.58
      Abstract:As an organic optical fiber with a diameter comparable to or less than the wavelength of light, polymer nanofibers have been attracting increasing attention as a platform for manipulating light at the nanoscale. A variety of applications for polymer optical nanofibers, including waveguides, light sources and sensors, have been reported in recent years. In this article, the recent progress in the field of polymer optical nanofibers is reviewed in terms of their fabrication, characterization and applications. In particular, we focus on functionalized polymer nanofibers doped with functional materials, such as dye molecules, noble metal nanoparticles, quantum dots and rare earth ions, which greatly expand their capabilities of generating, propagating, converting and modulating light at the nanoscale.  
      Keywords:functionalization;polymer nanofibers;waveguides   
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    • Xiang Hao,Cuifang Kuang,Zhaotai Gu,Yifan Wang,Shuai Li,Yulong Ku,Yanghui Li,Jianhong Ge,Xu Liu
      Vol. 2, Issue 3-4, (2013) DOI: 10.1038/lsa.2013.64
      Abstract:The resolution of conventional optical equipment is always restricted by the diffraction limit, and improving on this was previously considered improbable. Optical super-resolution imaging, which has recently experienced rapid growth and attracted increasing global interest, will result in applications in many domains, benefiting fields such as biology, medicine and material research. This review discusses the contributions of different researchers who identified the diffractive barrier and attempted to realize optical super-resolution. This is followed by a personal viewpoint of the development of optical nanoscopy in recent decades and the road towards the next generation of optical nanoscopy.  
      Keywords:evanescent wave;nonlinear effect;optical nanoscopy;superoscillation;super-resolution   
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